alternativeАльтернативная энергетика и экология (ISJAEE)Alternative Energy and Ecology (ISJAEE)1608-8298Международный издательский дом научной периодики "Спейс10.15518/isjaee.2017.10-12.063-074alternative-1022Research ArticleВОДОРОДНАЯ ЭКОНОМИКАHYDROGEN ECONOMYИССЛЕДОВАНИЕ ПРОЦЕССА ГЕНЕРАЦИИ ВОДОРОДА ПРИ ОКИСЛЕНИИ МАГНИЯ В СОЛЕВЫХ ВОДНЫХ РАСТВОРАХ В ДИАПАЗОНЕ ТЕМПЕРАТУР ОТ –40 ºC ДО +20 ºCTHE STUDY OF THE HYDROGEN PRODUCTION DURING THE MAGNESIUM OXIDATION IN AQUEOUS SALT SOLUTIONS AT TEMPERATURES RANGING FROM –40 ºC TO +20 ºCБуряковскаяО. А.BuryakovskayaO. A.

младший научный струдник 

Junior Researcher

svetlana_ryzhkova_1993@mail.ruРыжковаС. С.RyzhkovaS. S.

магистр, стажер исследователь

Intern Researcher

svetlana_ryzhkova_1993@mail.ruВласкинМ. С.VlaskinM. S.

канд. тех. наук, заведующий лабораторией 3.2.2 (энергоаккумулирующих веществ)

Ph.D. (engineering), Head of the Energy Accumulating Materials Laboratory

svetlana_ryzhkova_1993@mail.ruФГБУН «Объединенный институт высоких температур РАН»РоссияJoint Institute for High Temperatures of the Russian Academy of SciencesRussian Federation201717052017010-126374Copyright © Международный издательский дом научной периодики "Спейс, 20172017Международный издательский дом научной периодики "СпейсМеждународный издательский дом научной периодики "Спейсhttps://www.isjaee.com/jour/about/submissions#copyrightNoticehttps://www.isjaee.com/jour/article/view/1022

Статья посвящена исследованию процесса генерации водорода при окислении магния в солевых водных растворах в условиях низких температур. Определен состав водных растворов, которые обеспечивают окисление магния при низких температурах с выделением водорода, а также температурная зависимость скорости протекания данной реакции для создания водородогенерирующей установки. Для этого был проведен ряд экспериментов по окислению магния в различных водных растворах. Эксперименты показали, что при 0 ºC степень превращения магния для раствора MgCl2 составляет 94,5 %, для AlCl3 – 84,5 %; при –20 ºC для раствора MgCl2 степень превращения – 32,5 %, для AlCl3 – 65,1 %; при –40 ºC для раствора AlCl3 – 85,2 %. В работе показано, что применение порошка магния при низких отрицательных температурах позволяет получать водород с высокой степенью превращения. Полученные результаты могут лечь в основу создания энергетических установок для использования в арктических условиях, а также для энергообеспечения беспилотных летательных аппаратов (на высоте 6 000 м, Tвоздуха = –24 ºC).

 

 

 

 

The paper is devoted to the investigation of hydrogen production from magnesium oxidation in aqueous salt solutions under low temperature conditions. This study determines the solution compositions suitable for effective low-temperature magnesium oxidation with hydrogen production, and the reaction rate dependence on temperature. A number of experiments were conducted using various solution compositions. The obtained experimental results can be very useful when developing a hydrogen production system. The experimental data obtained demonstrate that at temperature of 0ºC magnesium conversion for MgCl2 solution is equal to 94,5%, for AlCl3 – 84,5%; at –20 ºC for MgCl2 – 32,5%, for AlCl3 – 65,1%; at –40ºC for AlCl3 – 85,2%. Moreover the paper demonstrates that oxidation of magnesium powder in some aqueous solutions provides hydrogen production with high hydrogen yields even at low temperatures. The results of this study can be used for designing power supply systems which can operate in Arctic regions and provide electricity supply to drones (at 6,000 m above the sea level, Tambient = –24 ºC).

 

 

 

 

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The authors declare that there are no conflicts of interest present.