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<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="ru"><front><journal-meta><journal-id journal-id-type="publisher-id">alternative</journal-id><journal-title-group><journal-title xml:lang="ru">Альтернативная энергетика и экология (ISJAEE)</journal-title><trans-title-group xml:lang="en"><trans-title>Alternative Energy and Ecology (ISJAEE)</trans-title></trans-title-group></journal-title-group><issn pub-type="ppub">1608-8298</issn><publisher><publisher-name>Международный издательский дом научной периодики "Спейс</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.15518/isjaee.2017.25-27.088-099</article-id><article-id custom-type="elpub" pub-id-type="custom">alternative-1186</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>КАТАЛИЗ В АЭЭ</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="en"><subject>CATALYSIS FOR AEE</subject></subj-group></article-categories><title-group><article-title>КОРРОЗИОННО-СТОЙКИЕ ЭЛЕКТРОДЫ/КОЛЛЕКТОРЫ ТОКА ДЛЯ АНОДОВ ЭЛЕКТРОЛИЗНЫХ ЯЧЕЕК С ТВЕРДЫМ ПОЛИМЕРНЫМ ЭЛЕКТРОЛИТОМ</article-title><trans-title-group xml:lang="en"><trans-title>CORROSION RESISTANT ELECTRODES / CURRENT COLLECTORS FOR ANODES OF ELECTROLYSIS CELLS WITH SOLID POLYMER ELECTROLYTE</trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Фатеев</surname><given-names>В. Н.</given-names></name><name name-style="western" xml:lang="en"><surname>Fateev</surname><given-names>V. N.</given-names></name></name-alternatives><bio xml:lang="ru"><p>д-р хим. наук, профессор НИЦ «Курчатовский институт», заместитель руководителя ККФХТ по научной работе</p></bio><email xlink:type="simple">fateev_vn@nrcki.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Алексеева</surname><given-names>О. К.</given-names></name><name name-style="western" xml:lang="en"><surname>Alekseeva</surname><given-names>O. K.</given-names></name></name-alternatives><bio xml:lang="ru"><p>канд. физ.-мат. наук, начальник отдела физикохимии и технологии новых материалов</p></bio><email xlink:type="simple">fateev_vn@nrcki.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Порембский</surname><given-names>В. И.</given-names></name><name name-style="western" xml:lang="en"><surname>Porembskiy</surname><given-names>V. I.</given-names></name></name-alternatives><bio xml:lang="ru"><p>заместитель руководителя отделения</p></bio><email xlink:type="simple">fateev_vn@nrcki.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Михалев</surname><given-names>А. И.</given-names></name><name name-style="western" xml:lang="en"><surname>Mikhalev</surname><given-names>A. I.</given-names></name></name-alternatives><bio xml:lang="ru"><p>аспирант Института прикладной механики РАН, инженер-исследователь НИЦ «Курчатовский институт»</p></bio><email xlink:type="simple">fateev_vn@nrcki.ru</email><xref ref-type="aff" rid="aff-2"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Никитин</surname><given-names>С. М.</given-names></name><name name-style="western" xml:lang="en"><surname>Nikitin</surname><given-names>S. M.</given-names></name></name-alternatives><bio xml:lang="ru"><p>канд. хим. наук, НИИЯФ МГУ, начальник лаборатории НИЦ «Курчатовский институт»</p></bio><email xlink:type="simple">fateev_vn@nrcki.ru</email><xref ref-type="aff" rid="aff-3"/></contrib></contrib-group><aff-alternatives id="aff-1"><aff xml:lang="ru"><institution>НИЦ «Курчатовский институт»</institution><country>Россия</country></aff><aff xml:lang="en"><institution>National Research Centre “Kurchatov Institute”</institution><country>Russian Federation</country></aff></aff-alternatives><aff-alternatives id="aff-2"><aff xml:lang="ru"><institution>НИЦ «Курчатовский институт»;&#13;
Институт прикладной механики (ИПРИМ РАН)</institution><country>Россия</country></aff><aff xml:lang="en"><institution>National Research Centre “Kurchatov Institute”;&#13;
IAM RAS</institution><country>Russian Federation</country></aff></aff-alternatives><aff-alternatives id="aff-3"><aff xml:lang="ru"><institution>НИЦ «Курчатовский институт»;&#13;
Институт прикладной механики (ИПРИМ РАН);&#13;
Научно-исследовательский институт ядерной физики имени Д.В. Скобельцына (НИИЯФ МГУ)</institution><country>Россия</country></aff><aff xml:lang="en"><institution>National Research Centre “Kurchatov Institute”;&#13;
IAM RAS;&#13;
Lomonosov Moscow State University, Skobeltsyn Institute of Nuclear Physics (SINP MSU)</institution><country>Russian Federation</country></aff></aff-alternatives><pub-date pub-type="collection"><year>2017</year></pub-date><pub-date pub-type="epub"><day>10</day><month>12</month><year>2017</year></pub-date><volume>0</volume><issue>25-27</issue><fpage>88</fpage><lpage>99</lpage><permissions><copyright-statement>Copyright &amp;#x00A9; Международный издательский дом научной периодики "Спейс, 2017</copyright-statement><copyright-year>2017</copyright-year><copyright-holder xml:lang="ru">Международный издательский дом научной периодики "Спейс</copyright-holder><copyright-holder xml:lang="en">Международный издательский дом научной периодики "Спейс</copyright-holder><license xlink:href="https://www.isjaee.com/jour/about/submissions#copyrightNotice" xlink:type="simple"><license-p>https://www.isjaee.com/jour/about/submissions#copyrightNotice</license-p></license></permissions><self-uri xlink:href="https://www.isjaee.com/jour/article/view/1186">https://www.isjaee.com/jour/article/view/1186</self-uri><abstract><p>Рассмотрен процесс получения коррозионно-стойких электродов с помощью экологически чистого метода магнетронного распыления для кислотных электрохимических систем с твердым полимерным электролитом, в частности, топливных элементов, электролизеров, кислородных насосов. Был найден способ получения электродов с электрохимической устойчивостью, близкой к устойчивости платины, но с резко сниженным ее содержанием, что позволит уменьшить стоимость соответствующей установки. В качестве основы для электродов был выбран титан как в форме гладкой фольги, так и в пористом виде, за счёт которого был снижен вес электрода. Наносились покрытия из палладия, платины или платины с углеродом. Толщина и микроструктура покрытий исследовались методами обратного рассеяния Резерфорда и электронной микроскопии. Испытания на стабильность проводили с использованием этих покрытий в качестве анодов в 1 М серной кислоте при 25 ºC и плотности тока 50 мА/см2 . Было продемонстрировано, что покрытия, полученные при распылении с постоянным током и с отрицательным смещением напряжения на титановой подложке, имели самую плотную структуру и высокую стабильность. В импульсном режиме стабильность была ниже и уменьшалась с ростом частоты импульсов при получении более пористой структуры. Сравнение покрытий с различной композицией показало, что платина даёт более высокую стабильность, чем палладий и платина с углеродом. Доказано, что применение этих покрытий резко повышает стабильность электродов и токоприемников из титановой фольги и пористого титана. Получаемые материалы предполагается применять в топливных элементах и электрохимических кислородных насосах.</p><p> </p></abstract><trans-abstract xml:lang="en"><p>The paper deals with the corrosion resistant electrodes production by the environmentally friendly magnetron sputtering for use in the acid electrochemical systems with solid polymer electrolyte, in particular, fuel cells, electrolyzers, and oxygen pumps. A technique was found for obtaining electrodes with electrochemical stability that was close to the stability of platinum, but with a sharply reduced content, which would reduce the cost of the corresponding installation. As the basis for the electrodes, titanium was chosen. Both smooth titanium foil and porous titanium were used. Applied coatings consisted of palladium, platinum or platinum with carbon. The coatings thickness and microstructure were tested using Rutherford backscattering and electron microscopy. The stability tests were carried out in 1 M sulphuric acid at 25oC and current density of 50 mA/cm2 . The application of these coatings is shown to increase sharply the stability of electrodes and current collectors of titanium foils and porous titanium. The coatings obtained at a direct current sputtering and a negative bias voltage on the titanium substrate have the most dense structure and high stability. In the pulsed mode, the stability was worse and decreased with increasing pulse frequency when obtaining a more porous structure. Comparison of the coatings with different compositions shows that stability of the coating with platinum is higher than stability of the coating with palladium and platinum with carbon. The resulting materials are expected to be used in fuel cells and electrochemical oxygen pumps.</p><p> </p></trans-abstract><kwd-group xml:lang="ru"><kwd>магнетронное напыление</kwd><kwd>электрокатализ</kwd><kwd>электрокатализаторы</kwd><kwd>защита от коррозии</kwd><kwd>окисление</kwd><kwd>электро- химические датчики</kwd><kwd>водородные концентраторы</kwd></kwd-group><kwd-group xml:lang="en"><kwd>magnetron sputtering</kwd><kwd>electrocatalysis</kwd><kwd>electrocatalysts</kwd><kwd>protection against corrosion</kwd><kwd>oxidation</kwd><kwd>electrochemical sensors</kwd><kwd>hydrogen concentrators</kwd></kwd-group></article-meta></front><back><ref-list><title>References</title><ref id="cit1"><label>1</label><citation-alternatives><mixed-citation xml:lang="ru">Eladeb, B. Electrochemical extraction of oxygen using PEM electrolysis technologies technologies [Text] / B. Eladeb [et al.] // J. Electrochem. Sci. Eng. – 2012. – Vol. 2. – No. 4. – P. 211–221.</mixed-citation><mixed-citation xml:lang="en">Eladeb B. Electrochemical extraction of oxygen using PEM electrolysis technologies technologies. J. Electrochem. Sci. Eng., 2012;2(4):211−221.</mixed-citation></citation-alternatives></ref><ref id="cit2"><label>2</label><citation-alternatives><mixed-citation xml:lang="ru">Discovery research group, 4 октября 2017 Объем рынка кислорода в России в 2016 г. составил 17 288,3 тыс. т, что эквивалентно $2 373,2 млн [Электронный ресурс]. – Режим доступа: https://marketing.rbc.ru/articles/9925 – (Дата обращения: 25.08.2017).</mixed-citation><mixed-citation xml:lang="en">Discovery research group, The volume of the oxygen market in Russia in 2016 amounted to 17,288.3 thousand tons, which is equivalent to $ 2,373.2 million (Ob"em rynka kisloroda v Rossii v 2016 g. sostavil 17 288,3 tys. t, chto ekvivalentno $2 373,2 mln) Available on: https://marketing.rbc.ru/articles/9925/ (in Russ.).</mixed-citation></citation-alternatives></ref><ref id="cit3"><label>3</label><citation-alternatives><mixed-citation xml:lang="ru">ГРАСИС Продукция. Кислородные установки и станции [Электронный ресурс]. – Режим доступа: http://www.grasys.ru/products/gas/kislorodnyeustanovki – (Дата обращения: 25.08.2017).</mixed-citation><mixed-citation xml:lang="en">GRASYS Production. Oxygen plants and stations (GRASIS Produktsiya. Kislorodnye ustanovki i stantsii) Available on: http://www.grasys.ru/products/gas/kislorodnye-ustanovki/ (in Russ.).</mixed-citation></citation-alternatives></ref><ref id="cit4"><label>4</label><citation-alternatives><mixed-citation xml:lang="ru">Пат. 133653 Российская Федерация, МПК7 H01M8/00 H01M8/12 Электрохимический модуль для твердоэлектролитного кислородного насоса / Волощенко Г.Н..; заявитель и патентообладатель Федеральное государственное бюджетное учреждение Национальный исследовательский центр «Курчатовский институт». – № 2013130274/07; заявл. 03.07.2013; опубл. 20.10.2013. Бюл. № 29.</mixed-citation><mixed-citation xml:lang="en">Voloshchenko G.N. Electrochemical module for solid electrolyte oxygen pump (Elektrokhimicheskii modul' dlya tverdoelektrolitnogo kislorodnogo nasosa) Patent RU 133653 U1 H01M8/00 H01M8/12 20.10.2013 (in Russ.).</mixed-citation></citation-alternatives></ref><ref id="cit5"><label>5</label><citation-alternatives><mixed-citation xml:lang="ru">Grigoriev, S.A. Evaluation of carbon-supported Pt and Pd nanoparticles for the hydrogen evolution reaction in PEM water electrolysers [Text] / S.A.Grigoriev, P. Millet, V.N. Fateev // Journal of Power Sources. – 2008. – Vol. 177. – Iss. 2. – P. 281–285.</mixed-citation><mixed-citation xml:lang="en">Grigoriev S.A. , Millet P., Fateev V.N. Evaluation of carbon-supported Pt and Pd nanoparticles for the hydrogen evolution reaction in PEM water electrolysers. Journal of Power Sources, 2008;177(2):281–285.</mixed-citation></citation-alternatives></ref><ref id="cit6"><label>6</label><citation-alternatives><mixed-citation xml:lang="ru">Patent RU 2016613524 20.04.2016 Программа для ЭВМ: Модель системы кондиционирования атмосферы мобильного аппарата / Волощенко Г. Н.</mixed-citation><mixed-citation xml:lang="en">Voloshchenko G.N. Computer program: Model of the atmosphere conditioning system of the mobile device (Programma dlya EVM: Model' sistemy konditsionirovaniya atmosfery mobil'nogo apparata). Patent RU 2016613524 20.04.2016 (in Russ.).</mixed-citation></citation-alternatives></ref><ref id="cit7"><label>7</label><citation-alternatives><mixed-citation xml:lang="ru">Пат. EP 0682379 США, IPC1-7 B01D53/32; C25B1/02; C25B9/00; C25B9/06; C25B9/08; C25B9/18; G01N27/41; G01N27/419; H01M8/02; H01M8/06; H01M8/12; H01M8/24; Series planar construction for solid electrolyte oxygen pump. Carolan M.F., Dyer P.N., E. Minford, Russek S. L., Wilson M. A., Taylor D. M., Henderson B.T. заявитель и патентообладатель Air products and chemicals, inc – № 19950106935; заявл. 08.05.95; опубл. 15.11.95, Бюл. № 95/46.</mixed-citation><mixed-citation xml:lang="en">Carolan M.F., Dyer P.N., E. Minford, Russek S. L., Wilson M. A., Taylor D. M., Henderson B.T. Series planar construction for solid electrolyte oxygen pump. Patent EP 0682379 USA, IPC1-7 B01D53/32; C25B1/02; C25B9/00; C25B9/06; C25B9/08; C25B9/18; G01N27/41; G01N27/419; H01M8/02; H01M8/06; H01M8/12; H01M8/24; заявитель и патентообладатель Air products and chemicals, inc – № 19950106935; опубл. 15.11.95. Бюл. № 95/46.</mixed-citation></citation-alternatives></ref><ref id="cit8"><label>8</label><citation-alternatives><mixed-citation xml:lang="ru">Grigoriev S.A., Optimization of porous current collectors for PEM water electrolysers. / S.A.Grigoriev et al. // International journal of hydrogen energy. − 2009. − Vol. 34. − P. 4968−4973</mixed-citation><mixed-citation xml:lang="en">Grigoriev S.A., I. Baranov, P. Millet, Z. Li, V. Fateev. Optimization of porous current collectors for PEM water electrolysers. International journal of hydrogen energy, 2009;34:4968−4973.</mixed-citation></citation-alternatives></ref><ref id="cit9"><label>9</label><citation-alternatives><mixed-citation xml:lang="ru">Grigoriev, S.A. Mathematical modeling and experimental study of the performance of PEM water electrolysis cell with different loadings of platinum metals in electrocatalytic layers [Text] / S.A. Grigoriev, A.A. Kalinnikov // International journal of hydrogen energy. − 2017. − Vol. 42. – P.1590 −1597</mixed-citation><mixed-citation xml:lang="en">Grigoriev S.A., Kalinnikov A.A. Mathematical modeling and experimental study of the performance of PEM water electrolysis cell with different loadings of platinum metals in electrocatalytic layers. International journal of hydrogen energy, 2017;42:1590−1597.</mixed-citation></citation-alternatives></ref><ref id="cit10"><label>10</label><citation-alternatives><mixed-citation xml:lang="ru">Huth, A. A proton pump concept for the investigation of proton transport and anode kinetics in proton exchange membrane fuel cells [Text] / A. Huth, B. Schaar, T. Oekermann // Electrochim Acta. – 2009. – Vol. 54. – P. 2774–2780.</mixed-citation><mixed-citation xml:lang="en">Huth A., Schaar B., Oekermann T. A proton pump concept for the investigation of proton transport and anode kinetics in proton exchange membrane fuel cells. Electrochim Acta, 2009;54:P.2774–2780.</mixed-citation></citation-alternatives></ref><ref id="cit11"><label>11</label><citation-alternatives><mixed-citation xml:lang="ru">Barbir, F. Electrochemical hydrogen pump for recirculation of hydrogen in a fuel cell stack [Text] / F. Barbir, H. Görgün // Journal of Applied Electrochemistry. – 2007. – Vol. 37. – Iss. 3. – P. 359–365.</mixed-citation><mixed-citation xml:lang="en">Barbir F., Görgün H. Electrochemical hydrogen pump for recirculation of hydrogen in a fuel cell stack. Journal of Applied Electrochemistry, 2007;37(3):359–365.</mixed-citation></citation-alternatives></ref><ref id="cit12"><label>12</label><citation-alternatives><mixed-citation xml:lang="ru">Sarakinos, K. High power pulsed magnetron sputtering: A review on scientific and engineering state of the art [Text] / K. Sarakinos, J. Alami, S. Konstantinidis // Surface &amp; Coatings Technology. – 2010. – Vol. 204. – P. 1661–1684.</mixed-citation><mixed-citation xml:lang="en">Sarakinos K., Alami J., Konstantinidis S. High power pulsed magnetron sputtering: A review on scientific and engineering state of the art. Surface &amp; Coatings Technology, 2010;204:1661–1684.</mixed-citation></citation-alternatives></ref><ref id="cit13"><label>13</label><citation-alternatives><mixed-citation xml:lang="ru">Xie, L. Molecular dynamics simulations of clusters and thin film growth in the context of plasma sputtering deposition [Text] / L.Xie, et al. // J. Phys. D: Appl. Phys. – 2014. – Vol. 47. – P. 224004.</mixed-citation><mixed-citation xml:lang="en">Xie L., Brault P., Bauchire J.-M., Thomann A.-L., Bedra L. Molecular dynamics simulations of clusters and thin film growth in the context of plasma sputtering deposition. J. Phys. D: Appl. Phys., 2014;47:224004.</mixed-citation></citation-alternatives></ref><ref id="cit14"><label>14</label><citation-alternatives><mixed-citation xml:lang="ru">Kelly, P.J. Magnetron sputtering: a review of recent developments and applications [Text] / P.J. Kelly, R.D. Arnell // Vacuum. – 2000. – Vol. 56. – P. 159–172.</mixed-citation><mixed-citation xml:lang="en">Kelly P.J., Arnell R.D. Magnetron sputtering: a review of recent developments and applications. Vacuum, 2000;56:159–172.</mixed-citation></citation-alternatives></ref><ref id="cit15"><label>15</label><citation-alternatives><mixed-citation xml:lang="ru">Radev, I. Optimization of platinum/iridium ratio in thin sputtered films for PEMFC cathodes / Radev I. [et al.] // Int. J. Hydrogen Energy. – 2012. – Vol. 37. – P. 7730–7735.</mixed-citation><mixed-citation xml:lang="en">Radev I., Topalov G., Lefterova E.D., Slavcheva E. Optimization of platinum/iridium ratio in thin sputtered films for PEMFC cathodes. Int. J. Hydrogen Energy, 2012;37:7730–7735.</mixed-citation></citation-alternatives></ref><ref id="cit16"><label>16</label><citation-alternatives><mixed-citation xml:lang="ru">Hirano, S. High performance proton exchange membrane fuel cells with sputter-deposited Pt layer electrodes [Text] / S. Hirano, J. Kim, S. Srinivasan // Electrochim. Acta. – 1997. – Vol. 42. – P. 1587–1593.</mixed-citation><mixed-citation xml:lang="en">Hirano S., Kim J., Srinivasan S. High performance proton exchange membrane fuel cells with sputter-deposited Pt layer electrodes. Electrochim. Acta, 1997;42:1587–1593.</mixed-citation></citation-alternatives></ref><ref id="cit17"><label>17</label><citation-alternatives><mixed-citation xml:lang="ru">Kim, H.-T. Platinum-sputtered electrode based on blend of carbon nanotubes and carbon black for polymer electrolyte fuel cell [Text] / Kim H.-T., Lee J.-K., Kim J. // J. of Power Sources. – 2008. – Vol. 180. – P. 191–194.</mixed-citation><mixed-citation xml:lang="en">Kim H.-T., Lee J.-K., Kim J. Platinumsputtered electrode based on blend of carbon nanotubes and carbon black for polymer electrolyte fuel cell. J. of Power Sources, 2008;180:191–194.</mixed-citation></citation-alternatives></ref><ref id="cit18"><label>18</label><citation-alternatives><mixed-citation xml:lang="ru">Plasma-assisted Pt and Pt-Pd nano-particles deposition on carbon carriers for application in PEM electrochemical cells [Text] / A.A. Fedotov [et al.] // Int. J. Hydrogen Energy. – 2013. – Vol. 38. – P. 8568–8574.</mixed-citation><mixed-citation xml:lang="en">Fedotov A.A., Grigoriev S.A., Millet P., Fateev V.N. Plasma-assisted Pt and Pt-Pd nanoparticles deposition on carbon carriers for application in PEM electrochemical cells. Int. J. Hydrogen Energy, 2013;38:8568–8574.</mixed-citation></citation-alternatives></ref><ref id="cit19"><label>19</label><citation-alternatives><mixed-citation xml:lang="ru">Fedotov, A.A. Characterization of carbonsupported platinum nano-particles synthesized using magnetron sputtering for application in PEM electrochemical systems [Text] / A.A Fedotov [et al.] // Int. J. Hydrogen Energy. – 2013. – Vol. 38. – P. 426–430.</mixed-citation><mixed-citation xml:lang="en">Fedotov A.A., Grigoriev S.A., Lyutikova E.K., Millet P., Fateev V.N. Characterization of carbonsupported platinum nano-particles synthesized using magnetron sputtering for application in PEM electrochemical systems. Int. J. Hydrogen Energy, 2013;38:426–430.</mixed-citation></citation-alternatives></ref><ref id="cit20"><label>20</label><citation-alternatives><mixed-citation xml:lang="ru">Федотов, А.А. Метод синтеза наноструктурных электрокатализаторов, основанный на магнетронно-ионном распылении [Текст] / А.А. Федотов [и др.] // Кинетика и катализ. – 2012. – Т. 53. – С. 803–809.</mixed-citation><mixed-citation xml:lang="en">Fedotov A.A. The method of synthesis of nanostructured electrocatalysts, based on magnetron-ion sputtering (Metod sinteza nanostrukturnykh elektrokatalizatorov, osnovannyi na magnetronno-ionnom raspylenii). Kinetika i kataliz, 2012;53:803–809 (in Russ.).</mixed-citation></citation-alternatives></ref><ref id="cit21"><label>21</label><citation-alternatives><mixed-citation xml:lang="ru">Alexeeva, O.K. Application of the magnetron sputtering for nanostructured electrocatalysts synthesis [Text] / O.K. Alexeeva, V.N. Fateev // Int. J. Hydrogen Energy. – 2016. – Vol. 41. – P. 3373–3386.</mixed-citation><mixed-citation xml:lang="en">Alexeeva O.K., Fateev V.N. Application of the magnetron sputtering for nanostructured electrocatalysts synthesis. Int. J. Hydrogen Energy, 2016;41:3373–3386.</mixed-citation></citation-alternatives></ref><ref id="cit22"><label>22</label><citation-alternatives><mixed-citation xml:lang="ru">Alexeeva, O. Preparation of hydride-forming intermetallic films [Text] / O. Alexeeva, A. Chistov, V. Sumarokov // Int. J. Hydrogen Energy. – 1995. – Vol. 20. – P. 397–399.</mixed-citation><mixed-citation xml:lang="en">Alexeeva O., Chistov A., Sumarokov V. Preparation of hydride-forming intermetallic films. Int. J. Hydrogen Energy, 1995;20:397–399.</mixed-citation></citation-alternatives></ref><ref id="cit23"><label>23</label><citation-alternatives><mixed-citation xml:lang="ru">Alexeeva, O.K. Interaction of magnetron sputtered PrNi5 films with hydrogen [Text] / O. Alexeeva, A. Chistov, V. Sumarokov // Int. J. Hydrogen Energy. – 1996. – Vol. 21. – P. 1001–1003.</mixed-citation><mixed-citation xml:lang="en">Alexeeva O.K., Chistov A., Sumarokov V.Interaction of magnetron sputtered PrNi5 films with hydrogen. Int. J. Hydrogen Energy, 1996;21:1001–1003.</mixed-citation></citation-alternatives></ref><ref id="cit24"><label>24</label><citation-alternatives><mixed-citation xml:lang="ru">Alexeeva, O.K. Interaction of hydrogen sulfide with Ni-Al protective coatings prepared by vacuum deposition [Text] / O.K. Alexeeva [et al.] // Int. J. Hydrogen Energy. – 1999. – Vol. 24. – P. 235–239.</mixed-citation><mixed-citation xml:lang="en">Alexeeva O.K., Shapir B.L., Sumarokov V.N., Vinogradova E.A. Interaction of hydrogen sulfide with Ni-Al protective coatings prepared by vacuum deposition. Int. J. Hydrogen Energy, 1999;24:235–239.</mixed-citation></citation-alternatives></ref><ref id="cit25"><label>25</label><citation-alternatives><mixed-citation xml:lang="ru">Alexeeva, O.K. Creation of hydrogen - selective tubular composite membranes based on Pd-alloys: I. Improvement of ceramic support with Ni layer deposition // Hydrogen Materials Science and Chemistry of Carbon Nanomaterials, T.N. Veziroglu et al. (eds.), New York, Springer, 2007, pp. 95–103.</mixed-citation><mixed-citation xml:lang="en">Alexeeva O.K. Creation of hydrogen–selective tubular composite membranes based on Pd-alloys: I. Improvement of ceramic support with Ni layer deposition. Hydrogen Materials Science and Chemistry of Carbon Nanomaterials, T.N. Veziroglu et al. (eds.), New York, Springer, 2007, pp. 95–103.</mixed-citation></citation-alternatives></ref><ref id="cit26"><label>26</label><citation-alternatives><mixed-citation xml:lang="ru">Алексеева, О.К. Характеристики нанесенного ленточного катализатора с активным слоем никеля Ренея [Текст] / О.К.Алексеева и [др.] // Кинетика и катализ. – 1987. – Т. 28. – С. 240–243.</mixed-citation><mixed-citation xml:lang="en">Alekseeva O.K. Characteristics of the deposited tape catalyst with an active layer of Raney nickel (Kharakteristiki nanesennogo lentochnogo katalizatora s aktivnym sloem nikelya Reneya. Kinetika i kataliz, 1987;28:240–243 (in Russ.).</mixed-citation></citation-alternatives></ref><ref id="cit27"><label>27</label><citation-alternatives><mixed-citation xml:lang="ru">Alexeeva О.K., Modified hydrogen sulfide adsorbents-catalysts [Text] / О.K. Alexeeva // Int. J. Hydrogen Energy. – 1994. – Vol. 19. – P. 693–696.</mixed-citation><mixed-citation xml:lang="en">Alexeeva О.K. Modified hydrogen sulfide adsorbents-catalysts. Int. J. Hydrogen Energy, 1994;19:693–696.</mixed-citation></citation-alternatives></ref><ref id="cit28"><label>28</label><citation-alternatives><mixed-citation xml:lang="ru">Giannuzzi, L.A. Introduction to Focused Ion Beams: Instrumentation, Theory, Techniques and Practice [Text] / L.A.Giannuzzi, F.A. Stevie. − Springer Press., 2005. − 357 p.</mixed-citation><mixed-citation xml:lang="en">Giannuzzi L.A., Stevie F.A. Introduction to Focused Ion Beams: Instrumentation, Theory, Techniques and Practice. Springer Press. 2005.</mixed-citation></citation-alternatives></ref><ref id="cit29"><label>29</label><citation-alternatives><mixed-citation xml:lang="ru">Shemukhin, A.A. Investigation of transmission of 1.7-MeV He+ beams through porous alumina membranes [Text] / A.A.Shemukhin, E.N. Muratova // Technical Physics Letters. − 2014. − Vol. 40. – Iss. 3. − P. 219−221.</mixed-citation><mixed-citation xml:lang="en">Shemukhin A.A., Muratova E.N. Investigation of transmission of 1.7-MeV He+ beams through porous alumina membranes. Technical Physics Letters, 2014;40(3):219−221.</mixed-citation></citation-alternatives></ref><ref id="cit30"><label>30</label><citation-alternatives><mixed-citation xml:lang="ru">Shemukhin, A.A. Defect formation and recrystallization in the silicon on sapphire films under Si+ irradiation [Text] /A.A. Shemukhin [et al.] // Nucl. Instrum. Methods Phys. Res. Sect B. − 2015. − Vol. 354. − P. 274−276.</mixed-citation><mixed-citation xml:lang="en">Shemukhin A.A., Nazarov A.V., Balakshin Yu.V., Chernysh V.S. Defect formation and recrystallization in the silicon on sapphire films under Si+ irradiation. Nucl. Instrum. Methods Phys. Res. Sect. B, 2015;354:274−276.</mixed-citation></citation-alternatives></ref></ref-list><fn-group><fn fn-type="conflict"><p>The authors declare that there are no conflicts of interest present.</p></fn></fn-group></back></article>
