alternativeАльтернативная энергетика и экология (ISJAEE)Alternative Energy and Ecology (ISJAEE)1608-8298Международный издательский дом научной периодики "Спейс10.15518/isjaee.2019.07-09.062-072alternative-1642Research ArticleIV. ВОДОРОДНАЯ ЭКОНОМИКА 12. Водородная экономикаIV. HYDROGEN ECONOMY. 12. Hydrogen EconomyПолучение водорода низкотемпературным окислительным водно-паровым реформингом этанола на катализаторе Ni/ZnOHydrogen Production by Low-Temperature Oxidative Water-Steam Reforming of Ethanol on Ni/ZnO Catalysthttps://orcid.org/0000-0001-6609-399XЛапинН. В.LapinN. V.

Николай Васильевич Лапин - кандидат технических наук, старший научный сотрудник ИПТМ РАН.

Д. 6, ул. Академика Осипьяна, Черноголовка, Московская обл., 142432, тел.: +7(496)524-40-15; факс: 8(496)524-42-25

Nikolai Lapin - PhD. in Engineering, Senior Researcher at IMT RAS.

6 Academician Osipyan Str., Chernogolovka, Moscow Reg., 142432, tel.: +7 (496) 524 40 15; fax: +7 (496) 524 42 25

lapin@iptm.ruhttps://orcid.org/0000-0001-9717-8865ГринькоВ. В.GrinkoV. V.

Валерий Васильевич Гринько - кандидат химических наук, младший научный сотрудник ИПТМ РАН.

Д. 6, ул. Академика Осипьяна, Черноголовка, Московская обл., 142432, тел.: +7(496)524-40-15; факс: 8(496)524-42-25

h-index 3

Valerij Grinko - Ph.D. in Chemistry, Junior Researcher at IMT RAS.

6 Academician Osipyan Str., Chernogolovka, Moscow Reg., 142432, tel.: +7 (496) 524 40 15; fax: +7 (496) 524 42 25

https://orcid.org/0000-0002-9289-6435БежокВ. С.BezhokV. S.

Владимир Сергеевич Бежок - младший научный сотрудник ИПТМ РАН.

Д. 6, ул. Академика Осипьяна, Черноголовка, Московская обл., 142432, тел.: +7(496)524-40-15; факс: 8(496)524-42-25

h-index 3

Vladimir Bezhok - Junior Researcher at IMT RAS.

6 Academician Osipyan Str., Chernogolovka, Moscow Reg., 142432, tel.: +7 (496) 524 40 15; fax: +7 (496) 524 42 25

ВяткинА. Ф.VyatkinA. F.

Анатолий Федорович Вяткин - доктор физико-математических наук, профессор, заместитель директора ИПТМ РАН.

Д. 6, ул. Академика Осипьяна, Черноголовка, Московская обл., 142432, тел.: +7(496)524-40-15; факс: 8(496)524-42-25

A-index 9

Anatolij Vyatkin - D.Sc. in Physics and Mathematics, Professor, Deputy Director of IMT RAS.

6 Academician Osipyan Str., Chernogolovka, Moscow Reg., 142432, tel.: +7 (496) 524 40 15; fax: +7 (496) 524 42 25

ФГБУН Институт проблем технологии микроэлектроники и особочистых материалов Российской академии наук (ИПТМ РАН)РоссияInstitute of Microelectronics Technology and High Purity Materials (IMT RAS)Russian Federation20191004201907-96272Copyright © Международный издательский дом научной периодики "Спейс, 20192019Международный издательский дом научной периодики "СпейсМеждународный издательский дом научной периодики "Спейсhttps://www.isjaee.com/jour/about/submissions#copyrightNoticehttps://www.isjaee.com/jour/article/view/1642

Исследован процесс окислительного низкотемпературного водно-парового реформинга этанола в проточном трубчатом кварцевом реакторе при атмосферном давлении в интервале температур 300-450 °С для получения водорода с минимальным содержанием монооксида углерода на ранее разработанном катализаторе Ni/ZnO (20 мас.% никеля). Катализатор готовили пропиткой промышленного порошка оксида цинка нитратом никеля с последующим прокаливанием и восстановлением оксида никеля. Использовались водно-этанольные смеси с молярным отношением «этанол - вода» от 1:2 до 1:13. Поток жидкой смеси составлял 0,45-1,55 г/час. Вместе со смесью в реакционную зону подавался воздух с таким расчетом, чтобы молярное отношение «кислород - этанол» изменялось в интервале 0,5-1,2. Анализ газовой фазы осуществлялся на газовом хроматографе «Цвет-500». В качестве детектора применялся катарометр.

Показана довольно высокая эффективность катализатора Ni/ZnO при получении водорода в процессе окислительного водно-парового реформинга этанола при относительно низких температурах. Основными продуктами реформинга этанола являлись водород, метан и двуокись углерода. Конверсия этанола происходила уже при 300 °С, а при 450 °С протекала практически полностью (99 %). Содержание водорода в продуктах реформинга во всех исследованных случаях находилось в интервале 45-60 об.%, выход водорода составлял при температуре 450 °С 1,6 моля на 1 моль этанола. При этом наблюдалось более высокое содержание двуокиси углерода, достигающее 45 об.%, и более низкое содержание метана, в 4-10 раз меньше водорода, в отличие от водно-парового реформинга этанола, где содержание двуокиси углерода составляло 15-20 об.%, а метана - всего в 2-2,5 раза меньше водорода.

Во всей исследованной области температур при малом времени контакта (0,5-0,6 сек) реакционной смеси с катализатором и при повышенном молярном отношении «кислород - этанол» в газовой фазе практически полностью отсутствовал монооксид углерода, что позволяет использовать полученную богатую водородом смесь для питания топливных элементов на протонообменных мембранах.

The paper investigates the process of oxidative low-temperature water-steam reforming of ethanol in the flow tube of a quartz reactor at atmospheric pressure over a temperature range 300-450 °C in order to obtain hydrogen with a minimum content of carbon monoxide on the previously developed Ni/ZnO catalyst (20 wt.% nickel). The catalyst was prepared by impregnating industrial zinc oxide powder with nickel nitrate followed by calcination and reduction of nickel oxide. Water-ethanol mixtures with the ethanol-water molar ratios from 1: 2 to 1:13 were used. The flow of the liquid mixture was 0.45-1.55 g / h. Air with the mixture was supplied to the reaction zone so that the oxy-gen/ethanol molar ratio varied in the range of 0.5-1.2. A gas phase analysis was carried out on a gas chromatograph “Tsvet-500”. A catarometer was used as a detector.

The research has shown a rather high efficiency of the Ni/ZnO catalyst in the hydrogen production in the process of oxidizing water-steam reforming of ethanol at relatively low temperatures. Hydrogen, methane and carbon dioxide are the main products of ethanol reforming. The conversion of ethanol takes place already at 300 °C and is almost completely at 450 °C (99%). The hydrogen content in the reforming products in all the studied cases is over the range of 45-60 vol% and constitutes the yield of 1.6 mole of hydrogen per 1 mole of ethanol at a temperature of 450 °C. At the same time, a higher content of carbon dioxide reaching 45 vol% and a lower content of methane, 4-10 times less than hydrogen, are observed in contrast to water-steam reforming of ethanol, where the content of carbon dioxide is 15-20 vol%, and methane is only 2-2.5 times less than hydrogen.

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The authors declare that there are no conflicts of interest present.