alternativeАльтернативная энергетика и экология (ISJAEE)Alternative Energy and Ecology (ISJAEE)1608-8298Международный издательский дом научной периодики "Спейс10.15518/isjaee.2019.28-33.023-035alternative-1814Research ArticleВОДОРОДНАЯ ЭКОНОМИКАHYDROGEN ECONOMYВыделение водорода из водного раствора гидразин-бисборанаHydrogen Release from Aqueous Hydrazine BisboraneПетитЭ.PetitE.

Эдди Петит инженер-химик, эксперт по аналитическим методам

E. Bataillon, F-34095, Монпелье, Франция

Eddy Petit chemical engineer expert in analytic techniques, IEM, University of Montpellier, CNRS, ENSCM.

Place E. Bataillon, F-34095, Montpellier, France

ДемирчиУ. Б.DemirciU. B.

Умит Б. Демирчи д-р физ.-хим. наук., профессор в Университете Монпелье; помощник редактора International Journal of Hydrogen Energy (Elsevier)

E. Bataillon, F-34095, Монпелье, Франция

Umit B. Demirci PhD in Physical Chemistry, Professor, Assistant Editor for International Journal of Hydrogen Energy (Elsevier).

Place E. Bataillon, F-34095, Montpellier, France

umit.demirci@umontpellier.frЕвропейский институт мембран IEM, UMR 5635 (CNRS-ENSCM-UM2) Университет МонпельеФранцияIEM (Institut Europeen des Membranes), UMR 5635 (CNRS-ENSCM-UM2), Universite de MontpellierFrance201913122019028-332335Copyright © Международный издательский дом научной периодики "Спейс, 20192019Международный издательский дом научной периодики "СпейсМеждународный издательский дом научной периодики "Спейсhttps://www.isjaee.com/jour/about/submissions#copyrightNoticehttps://www.isjaee.com/jour/article/view/1814

В статье рассматривалась возможность использования водного раствора гидразин-бисборана (ГББ) H3B– N2H4–BH3 в качестве жидкого материала для химического хранения водорода (H) в условиях полного дегидрирования раствора в мягкой среде. Авторами впервые в научной литературе описан процесс дегидрирования водного раствора ГББ, проявляющего неустойчивость в воде. В щелочной среде степень устойчивости оказалась еще ниже, что обусловлено образованием неустойчивого промежуточного соединения [H3BOH] – . Установлено, что посредством металлических катализаторов гидролиз производных борана BH3 ускоряется, при этом наиболее активным оказался биметаллический катализатор на основе NiPt, способствующий, кроме того, разложению молекулы N2H4. Лучшие показатели кинетики отмечены в ходе реакции в щелочной среде при температуре 70 °C. При этом происходит неполное дегидрирование с максимальным значением конверсии 80 %, причина которого, к сожалению, пока не ясна. Несмотря на этот и ряд других вопросов, которые могут появиться в дальнейшем, авторы пришли к выводу, что раствор ГББ может быть использован в качестве жидкого материала для химического хранения водорода.

Aqueous hydrazine bisborane H3B–N2H4–BH3 (HBB) might be a possible liquid-state chemical H storage material at the conditions that the compound totally dehydrogenates in mild conditions. Herein we demonstrate such a potential. We report for the first time a work about the dehydrogenation of aqueous HBB. The compound is not stable in water. Its stability is even lower in alkaline conditions because of the likely formation of the unstable intermediate [H3BOH]– . The use of a metal-based catalyst accelerates the hydrolysis of the BH3 groups but the bimetallic NiPt catalyst is more active, being also able to decompose the N2H4 moiety. The best kinetics is observed at 70 °C and in alkaline conditions. However, the dehydrogenation is not total, reaching a limit of 80% of conversion. Unfortunately the reason of that is not understood yet. As things stand, there are some challenges ahead, but HBB has shown to be a possible liquid-state chemical H storage material.

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The authors declare that there are no conflicts of interest present.