<?xml version="1.0" encoding="UTF-8"?>
<!DOCTYPE article PUBLIC "-//NLM//DTD JATS (Z39.96) Journal Publishing DTD v1.3 20210610//EN" "JATS-journalpublishing1-3.dtd">
<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="ru"><front><journal-meta><journal-id journal-id-type="publisher-id">alternative</journal-id><journal-title-group><journal-title xml:lang="ru">Альтернативная энергетика и экология (ISJAEE)</journal-title><trans-title-group xml:lang="en"><trans-title>Alternative Energy and Ecology (ISJAEE)</trans-title></trans-title-group></journal-title-group><issn pub-type="ppub">1608-8298</issn><publisher><publisher-name>Международный издательский дом научной периодики "Спейс</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.15518/isjaee.2015.21.008</article-id><article-id custom-type="elpub" pub-id-type="custom">alternative-201</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>ВОДОРОДНАЯ ЭКОНОМИКА</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="en"><subject>HYDROGEN ECONOMY</subject></subj-group></article-categories><title-group><article-title>ЭКСТРАОРДИНАРНОЕ ПРОЯВЛЕНИЕ ЭФФЕКТОВ ТИПА ЭФФЕКТА КУРДЮМОВА И ВОДОРОДНОГО СПИЛЛОВЕР ЭФФЕКТА В СВЯЗИ С ПРОБЛЕМОЙ ЭФФЕКТИВНОГО ХРАНЕНИЯ ВОДОРОДА В ГРАФИТОВЫХ НАНОВОЛОКНАХ</article-title><trans-title-group xml:lang="en"><trans-title>EXTRAORDINARY MANIFESTATION OF THE KURDJUMOV-LIKE EFFECT AND THE SPILLOVER-LIKE ONE, RELEVANCE TO THE PROBLEM OF THE EFFICIENT HYDROGEN STORAGE IN GRAPHITE NANOFIBERS</trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Нечаев</surname><given-names>Ю. С.</given-names></name><name name-style="western" xml:lang="en"><surname>Nechaev</surname><given-names>Yu. S.</given-names></name></name-alternatives><bio xml:lang="ru"><p>д-р физ.-мат. наук, профессор, главный научный сотрудник </p></bio><bio xml:lang="en"><p>Dr. Sc., Prof., Chief researcher</p></bio><email xlink:type="simple">Yuri1939@inbox.ru</email><xref ref-type="aff" rid="aff-1"/></contrib></contrib-group><aff-alternatives id="aff-1"><aff xml:lang="ru"><institution>ЦНИИчермет им. И.П. Бардина &#13;
Институт металловедения и физики металлов им. Г.В. Курдюмова 105005 Москва, 2-я Бауманская ул., д. 9/23</institution><country>Россия</country></aff><aff xml:lang="en"><institution>I.P. Bardin Central Research Institute for Ferrous Metallurgy G.V. Kurdjumov Institute of Metals Science and Physics 9/23, 2-ya Baumanskaya str., Moscow, 105005, Russia</institution><country>Russian Federation</country></aff></aff-alternatives><pub-date pub-type="collection"><year>2015</year></pub-date><pub-date pub-type="epub"><day>05</day><month>04</month><year>2016</year></pub-date><volume>0</volume><issue>21</issue><fpage>70</fpage><lpage>75</lpage><permissions><copyright-statement>Copyright &amp;#x00A9; Международный издательский дом научной периодики "Спейс, 2016</copyright-statement><copyright-year>2016</copyright-year><copyright-holder xml:lang="ru">Международный издательский дом научной периодики "Спейс</copyright-holder><copyright-holder xml:lang="en">Международный издательский дом научной периодики "Спейс</copyright-holder><license xlink:href="https://www.isjaee.com/jour/about/submissions#copyrightNotice" xlink:type="simple"><license-p>https://www.isjaee.com/jour/about/submissions#copyrightNotice</license-p></license></permissions><self-uri xlink:href="https://www.isjaee.com/jour/article/view/201">https://www.isjaee.com/jour/article/view/201</self-uri><abstract><p>Рассматриваются термодинамические стимулы и энергетика интеркаляции нанофазы молекулярного водорода высокой плотности в углеродные наноструктуры. Обсуждается физика экстраординарного проявления эффектов типа эффекта Курдюмова и водородного спилловер эффекта в связи с проблемой эффективного хранения водорода в графитовых нановолокнах. </p></abstract><trans-abstract xml:lang="en"><p>Thermodynamic stimuli and energetics of intercalation of H2 nanophase of a high density into carbon-based nanostructures are considered. The physics of the extraordinary manifestation of the Kurdjumov-like effect and the hydrogen spillover-like one, relevance to the problem of the efficient hydrogen storage in graphite nanofibers are discussed. </p></trans-abstract><kwd-group xml:lang="ru"><kwd>обработка атомным водородом</kwd><kwd>высоко ориентированный пиролитический графит</kwd><kwd>эпитаксиальные графены</kwd><kwd>графитовые нановолокна</kwd><kwd>интеркаляция твердого H2</kwd><kwd>эффект Курдюмова</kwd><kwd>водородный спилловер эффект</kwd><kwd>хранение водорода на борту автомобиля</kwd></kwd-group><kwd-group xml:lang="en"><kwd>atomic hydrogen treatment</kwd><kwd>HOPG</kwd><kwd>epitaxial graphenes</kwd><kwd>graphite nanofibers</kwd><kwd>solid H2 intercalation</kwd><kwd>hydrogen spillover effect</kwd><kwd>the Kurdjumov effect</kwd><kwd>hydrogen on-board storage</kwd></kwd-group></article-meta></front><back><ref-list><title>References</title><ref id="cit1"><label>1</label><citation-alternatives><mixed-citation xml:lang="ru">Juarez-Mosqueda R., Mavrandonakis A., Kuc A.B., Pettersson L.G.M., Heine T. Theoretical analysis of hydrogen spillover mechanism on carbon nanotubes. // Front Chem. 2015. Vol. 3. P. 2. Published online 2015 Feb 2. | doi: 10.3389/fchem.2015.00002. PMCID: PMC4313777.</mixed-citation><mixed-citation xml:lang="en">Juarez-Mosqueda R., Mavrandonakis A., Kuc A.B., Pettersson L.G.M., Heine T. Theoretical analysis of hydrogen spillover mechanism on carbon nanotubes. // Front Chem. 2015. Vol. 3. P. 2. Published online 2015 Feb 2. | doi: 10.3389/fchem.2015.00002. PMCID: PMC4313777.</mixed-citation></citation-alternatives></ref><ref id="cit2"><label>2</label><citation-alternatives><mixed-citation xml:lang="ru">Han S.S., Jung H., Jung D.H., Choi S.-H., Park N. (2012). Stability of hydrogenation states of graphene and conditions for hydrogen spillover. // Phys. Rev. B. 2012. Vol. 85. P. 155408. 10.1103/PhysRevB.85.155408.</mixed-citation><mixed-citation xml:lang="en">Han S.S., Jung H., Jung D.H., Choi S.-H., Park N. (2012). Stability of hydrogenation states of graphene and conditions for hydrogen spillover. // Phys. Rev. B. 2012. Vol. 85. P. 155408. 10.1103/PhysRevB.85.155408.</mixed-citation></citation-alternatives></ref><ref id="cit3"><label>3</label><citation-alternatives><mixed-citation xml:lang="ru">Tsao C.S., Liu Y., Chuang H.Y., Tseng H.H., Chen T.Y., Chen C.H., Yu M.S., Li Q., Lueking A.D., Chen S.H. Hydrogen Spillover effect of Pt-doped Activated Carbon Studied by Inelastic Neutron Scattering // J. Phys. Chem. Lett. 2011. Vol. 2. P. 2322– 2325.</mixed-citation><mixed-citation xml:lang="en">Tsao C.S., Liu Y., Chuang H.Y., Tseng H.H., Chen T.Y., Chen C.H., Yu M.S., Li Q., Lueking A.D., Chen S.H. Hydrogen Spillover effect of Pt-doped Activated Carbon Studied by Inelastic Neutron Scattering // J. Phys. Chem. Lett. 2011. Vol. 2. P. 2322– 2325.</mixed-citation></citation-alternatives></ref><ref id="cit4"><label>4</label><citation-alternatives><mixed-citation xml:lang="ru">Li Q., Lueking A.D. Effect of Surface Oxyen Groups and Water on Hydrogen Spillover in Pt-Doped Activated Carbon // J. Phys. Chem. C. 2011. Vol. 115. P. 4273-4282.</mixed-citation><mixed-citation xml:lang="en">Li Q., Lueking A.D. Effect of Surface Oxyen Groups and Water on Hydrogen Spillover in Pt-Doped Activated Carbon // J. Phys. Chem. C. 2011. Vol. 115. P. 4273-4282.</mixed-citation></citation-alternatives></ref><ref id="cit5"><label>5</label><citation-alternatives><mixed-citation xml:lang="ru">Bhowmick R., Rajasekaran S., Friebel D., Beasley C., Jiao L., Ogasawara H., Dai H., et al. Hydrogen spillover in pt-single-walled carbon nanotube composites: formation of stable C-H bonds. // J. Am. Chem. Soc. 2011. Vol. 133. P. 5580–5586. doi: 10.1021/ja200403m.</mixed-citation><mixed-citation xml:lang="en">Bhowmick R., Rajasekaran S., Friebel D., Beasley C., Jiao L., Ogasawara H., Dai H., et al. Hydrogen spillover in pt-single-walled carbon nanotube composites: formation of stable C-H bonds. // J. Am. Chem. Soc. 2011. Vol. 133. P. 5580–5586. doi: 10.1021/ja200403m.</mixed-citation></citation-alternatives></ref><ref id="cit6"><label>6</label><citation-alternatives><mixed-citation xml:lang="ru">Chen C.-H., Huang C.-C. Enhancement of hydrogen spillover onto carbon nanotubes with defect feature // Microporous Mesoporous Mater. 2008. Vol. 109. P. 549–559. 10.1016/j.micromeso.2007.06.003.</mixed-citation><mixed-citation xml:lang="en">Chen C.-H., Huang C.-C. Enhancement of hydrogen spillover onto carbon nanotubes with defect feature // Microporous Mesoporous Mater. 2008. Vol. 109. P. 549–559. 10.1016/j.micromeso.2007.06.003.</mixed-citation></citation-alternatives></ref><ref id="cit7"><label>7</label><citation-alternatives><mixed-citation xml:lang="ru">Chen H., Yang R.T. Catalytic effects of TiF3 on hydrogen spillover on Pt/Carbon for hydrogen storage // Langmuir. 2010. Vol. 26. P. 15394–15398. 10.1021/la100172b.</mixed-citation><mixed-citation xml:lang="en">Chen H., Yang R.T. Catalytic effects of TiF3 on hydrogen spillover on Pt/Carbon for hydrogen storage // Langmuir. 2010. Vol. 26. P. 15394–15398. 10.1021/la100172b.</mixed-citation></citation-alternatives></ref><ref id="cit8"><label>8</label><citation-alternatives><mixed-citation xml:lang="ru">Chen L., Cooper A.C., Pez G.P., Cheng H. Mechanistic study on hydrogen spillover onto graphitic carbon materials // J. Phys. Chem. C. 2007. Vol. 111. P. 18995–19000. 10.1021/jp074920g.</mixed-citation><mixed-citation xml:lang="en">Chen L., Cooper A.C., Pez G.P., Cheng H. Mechanistic study on hydrogen spillover onto graphitic carbon materials // J. Phys. Chem. C. 2007. Vol. 111. P. 18995–19000. 10.1021/jp074920g.</mixed-citation></citation-alternatives></ref><ref id="cit9"><label>9</label><citation-alternatives><mixed-citation xml:lang="ru">Chen L., Cooper A.C., Pez G.P., Cheng H. Density functional study of sequential H2 dissociative chemisorption on a Pt6 cluster // J. Phys. Chem. C. 2007. Vol. 111. P. 5514–5519. 10.1021/jp070181s.</mixed-citation><mixed-citation xml:lang="en">Chen L., Cooper A.C., Pez G.P., Cheng H. Density functional study of sequential H2 dissociative chemisorption on a Pt6 cluster // J. Phys. Chem. C. 2007. Vol. 111. P. 5514–5519. 10.1021/jp070181s.</mixed-citation></citation-alternatives></ref><ref id="cit10"><label>10</label><citation-alternatives><mixed-citation xml:lang="ru">Chen L., Zhou C.-G., Wu J.-P., Cheng H.-S. Hydrogen adsorption and desorption on the Pt and Pd subnano clusters – a review // Front. Phys. China. 2009. Vol. 4. P. 356–366. 10.1007/s11467-009-0050-6.</mixed-citation><mixed-citation xml:lang="en">Chen L., Zhou C.-G., Wu J.-P., Cheng H.-S. Hydrogen adsorption and desorption on the Pt and Pd subnano clusters – a review // Front. Phys. China. 2009. Vol. 4. P. 356–366. 10.1007/s11467-009-0050-6.</mixed-citation></citation-alternatives></ref><ref id="cit11"><label>11</label><citation-alternatives><mixed-citation xml:lang="ru">Cheng H., Chen L., Cooper A.C., Sha X., Pez G.P. Hydrogen spillover in the context of hydrogen storage using solid-state materials // Energy Environ. Sci. 2008. Vol. 1. P. 338–354. 10.1039/B807618A.</mixed-citation><mixed-citation xml:lang="en">Cheng H., Chen L., Cooper A.C., Sha X., Pez G.P. Hydrogen spillover in the context of hydrogen storage using solid-state materials // Energy Environ. Sci. 2008. Vol. 1. P. 338–354. 10.1039/B807618A.</mixed-citation></citation-alternatives></ref><ref id="cit12"><label>12</label><citation-alternatives><mixed-citation xml:lang="ru">Lachawiec A.J., Qi G., Yang R.T. Hydrogen storage in nanostructured carbons by spillover: bridge-building enhancement // Langmuir. 2005. Vol. 21. P. 11418–11424. 10.1021/la051659r.</mixed-citation><mixed-citation xml:lang="en">Lachawiec A.J., Qi G., Yang R.T. Hydrogen storage in nanostructured carbons by spillover: bridge-building enhancement // Langmuir. 2005. Vol. 21. P. 11418–11424. 10.1021/la051659r.</mixed-citation></citation-alternatives></ref><ref id="cit13"><label>13</label><citation-alternatives><mixed-citation xml:lang="ru">Li Y., Yang R.T. Hydrogen storage in metal-organic frameworks by bridged hydrogen spillover // J. Am. Chem. Soc. 2006. Vol. 128. P. 8136–8137. 10.1021/ja061681m.</mixed-citation><mixed-citation xml:lang="en">Li Y., Yang R.T. Hydrogen storage in metal-organic frameworks by bridged hydrogen spillover // J. Am. Chem. Soc. 2006. Vol. 128. P. 8136–8137. 10.1021/ja061681m.</mixed-citation></citation-alternatives></ref><ref id="cit14"><label>14</label><citation-alternatives><mixed-citation xml:lang="ru">Li Y., Yang R.T. Significantly enhanced hydrogen storage in metal-organic frameworks via spillover // J. Am. Chem. Soc. 2006. Vol. 128. P. 726– 727. 10.1021/ja056831s.</mixed-citation><mixed-citation xml:lang="en">Li Y., Yang R.T. Significantly enhanced hydrogen storage in metal-organic frameworks via spillover // J. Am. Chem. Soc. 2006. Vol. 128. P. 726– 727. 10.1021/ja056831s.</mixed-citation></citation-alternatives></ref><ref id="cit15"><label>15</label><citation-alternatives><mixed-citation xml:lang="ru">Liu Y.-Y., Zeng J.-L., Zhang J., Xu F., Sun L.-X. Improved hydrogen storage in the modified metal-organic frameworks by hydrogen spillover effect // Int. J. Hydrogen Energy. 2007. Vol. 32. P. 4005–4010. 10.1016/j.ijhydene.2007.04.029.</mixed-citation><mixed-citation xml:lang="en">Liu Y.-Y., Zeng J.-L., Zhang J., Xu F., Sun L.-X. Improved hydrogen storage in the modified metal-organic frameworks by hydrogen spillover effect // Int. J. Hydrogen Energy. 2007. Vol. 32. P. 4005–4010. 10.1016/j.ijhydene.2007.04.029.</mixed-citation></citation-alternatives></ref><ref id="cit16"><label>16</label><citation-alternatives><mixed-citation xml:lang="ru">Lueking A.D., Yang R.T. Hydrogen spillover to enhance hydrogen storage study of the effect of carbon physicochemical properties // Appl. Catal. A. 2004. Vol. 265. P. 259–268. 10.1016/j.apcata.2004.01.019.</mixed-citation><mixed-citation xml:lang="en">Lueking A.D., Yang R.T. Hydrogen spillover to enhance hydrogen storage study of the effect of carbon physicochemical properties // Appl. Catal. A. 2004. Vol. 265. P. 259–268. 10.1016/j.apcata.2004.01.019.</mixed-citation></citation-alternatives></ref><ref id="cit17"><label>17</label><citation-alternatives><mixed-citation xml:lang="ru">Mitchell P.C.H., Ramirez-Cuesta A.J., Parker S.F., Tomkinson J. Inelastic neutron scattering in spectroscopic studies of hydrogen on carbon-supported catalysts-experimental spectra and computed spectra of model systems // J. Mol. Struct. 2003. Vols. 651–653. P. 781–785. 10.1016/S0022-2860(03)00124-8.</mixed-citation><mixed-citation xml:lang="en">Mitchell P.C.H., Ramirez-Cuesta A.J., Parker S.F., Tomkinson J. Inelastic neutron scattering in spectroscopic studies of hydrogen on carbon-supported catalysts-experimental spectra and computed spectra of model systems // J. Mol. Struct. 2003. Vols. 651–653. P. 781–785. 10.1016/S0022-2860(03)00124-8.</mixed-citation></citation-alternatives></ref><ref id="cit18"><label>18</label><citation-alternatives><mixed-citation xml:lang="ru">Mitchell P.C.H., Ramirez-Cuesta A.J., Parker S.F., Tomkinson J., Thompsett D. Hydrogen spillover on carbon-supported metal catalysts studied by inelastic neutron scattering. Surface vibrational states and hydrogen riding modes // J. Phys. Chem. B. 2003. Vol. 107(28). P. 6838–6845. 10.1021/jp0277356.</mixed-citation><mixed-citation xml:lang="en">Mitchell P.C.H., Ramirez-Cuesta A.J., Parker S.F., Tomkinson J., Thompsett D. Hydrogen spillover on carbon-supported metal catalysts studied by inelastic neutron scattering. Surface vibrational states and hydrogen riding modes // J. Phys. Chem. B. 2003. Vol. 107(28). P. 6838–6845. 10.1021/jp0277356.</mixed-citation></citation-alternatives></ref><ref id="cit19"><label>19</label><citation-alternatives><mixed-citation xml:lang="ru">Psofogiannakis G.M., Froudakis G.E. DFT study of the hydrogen spillover mechanism on Pt-Doped graphite // J. Phys. Chem. C. 2009. Vol. 113. P. 14908– 14915. 10.1021/jp902987s.</mixed-citation><mixed-citation xml:lang="en">Psofogiannakis G.M., Froudakis G.E. DFT study of the hydrogen spillover mechanism on Pt-Doped graphite // J. Phys. Chem. C. 2009. Vol. 113. P. 14908– 14915. 10.1021/jp902987s.</mixed-citation></citation-alternatives></ref><ref id="cit20"><label>20</label><citation-alternatives><mixed-citation xml:lang="ru">Wu H.-Y., Fan X., Kuo J.-L., Deng W.-Q. DFT study of hydrogen storage by spillover on graphene with boron substitution // J. Phys. Chem. C. 2011. Vol. 115. P. 9241–9249. 10.1021/jp200038b.</mixed-citation><mixed-citation xml:lang="en">Wu H.-Y., Fan X., Kuo J.-L., Deng W.-Q. DFT study of hydrogen storage by spillover on graphene with boron substitution // J. Phys. Chem. C. 2011. Vol. 115. P. 9241–9249. 10.1021/jp200038b.</mixed-citation></citation-alternatives></ref><ref id="cit21"><label>21</label><citation-alternatives><mixed-citation xml:lang="ru">Yang F.H., Lachawiec A.J., Yang R.T. Adsorption of spillover hydrogen atoms on single-wall carbon nanotubes // J. Phys. Chem. B. 2006. Vol. 110. P. 6236–6244. 10.1021/jp056461u.</mixed-citation><mixed-citation xml:lang="en">Yang F.H., Lachawiec A.J., Yang R.T. Adsorption of spillover hydrogen atoms on single-wall carbon nanotubes // J. Phys. Chem. B. 2006. Vol. 110. P. 6236–6244. 10.1021/jp056461u.</mixed-citation></citation-alternatives></ref><ref id="cit22"><label>22</label><citation-alternatives><mixed-citation xml:lang="ru">Yang R.T., Wang Y. Catalyzed hydrogen spillover for hydrogen storage // J. Am. Chem. Soc. 2009. Vol. 131. P. 4224–4226. 10.1021/ja808864r.</mixed-citation><mixed-citation xml:lang="en">Yang R.T., Wang Y. Catalyzed hydrogen spillover for hydrogen storage // J. Am. Chem. Soc. 2009. Vol. 131. P. 4224–4226. 10.1021/ja808864r.</mixed-citation></citation-alternatives></ref><ref id="cit23"><label>23</label><citation-alternatives><mixed-citation xml:lang="ru">Zacharia R., Rather S., Hwang S.W., Nahm K.S. Spillover of physisorbed hydrogen from sputter-deposited arrays of platinum nanoparticles to multi-walled carbon nanotubes // Chem. Phys. Lett. 2007. Vol. 434. P. 286–291. 10.1016/j.cplett.2006.12.022.</mixed-citation><mixed-citation xml:lang="en">Zacharia R., Rather S., Hwang S.W., Nahm K.S. Spillover of physisorbed hydrogen from sputter-deposited arrays of platinum nanoparticles to multi-walled carbon nanotubes // Chem. Phys. Lett. 2007. Vol. 434. P. 286–291. 10.1016/j.cplett.2006.12.022.</mixed-citation></citation-alternatives></ref><ref id="cit24"><label>24</label><citation-alternatives><mixed-citation xml:lang="ru">Zhou C., Wu J., Nie A., Forrey R.C., Tachibana A., Cheng H. On the sequential hydrogen dissociative chemisorption on small platinum clusters: a density functional theory study // J. Phys. Chem. C. 2007. Vol. 111. P. 12773–12778. 10.1021/jp073597e.</mixed-citation><mixed-citation xml:lang="en">Zhou C., Wu J., Nie A., Forrey R.C., Tachibana A., Cheng H. On the sequential hydrogen dissociative chemisorption on small platinum clusters: a density functional theory study // J. Phys. Chem. C. 2007. Vol. 111. P. 12773–12778. 10.1021/jp073597e.</mixed-citation></citation-alternatives></ref><ref id="cit25"><label>25</label><citation-alternatives><mixed-citation xml:lang="ru">Zieliñski M., Wojcieszak R., Monteverdi S., Mercy M., Bettahar M.M. Hydrogen storage in nickel catalysts supported on activated carbon // Int. J. Hydrogen Energy. 2007. Vol. 32. P. 1024–1032. 10.1016/j.ijhydene.2006.07.004.</mixed-citation><mixed-citation xml:lang="en">Zieliñski M., Wojcieszak R., Monteverdi S., Mercy M., Bettahar M.M. Hydrogen storage in nickel catalysts supported on activated carbon // Int. J. Hydrogen Energy. 2007. Vol. 32. P. 1024–1032. 10.1016/j.ijhydene.2006.07.004.</mixed-citation></citation-alternatives></ref><ref id="cit26"><label>26</label><citation-alternatives><mixed-citation xml:lang="ru">Nechaev Yu.S. On the H2 nanophase intercalation into graphene-layers structures: Relevence to the spillover effect // Int. Scientific Journal for Alternative Energy and Ecology. 2015. # 06 (170). P. 37-40.</mixed-citation><mixed-citation xml:lang="en">Nechaev Yu.S. On the H2 nanophase intercalation into graphene-layers structures: Relevence to the spillover effect // Int. Scientific Journal for Alternative Energy and Ecology. 2015. # 06 (170). P. 37-40.</mixed-citation></citation-alternatives></ref><ref id="cit27"><label>27</label><citation-alternatives><mixed-citation xml:lang="ru">Nechaev Yu.S., Veziroglu T.N. On the hydrogenation-dehydrogenation of graphene-layer-nanostructures: Relevance to the hydrogen on-board storage problem // Int. Journal of Physical Sciences. 2015. Vol. 10, Iss. 2. P. 54-89 (an “open access” Journal).</mixed-citation><mixed-citation xml:lang="en">Nechaev Yu.S., Veziroglu T.N. On the hydrogenation-dehydrogenation of graphene-layer-nanostructures: Relevance to the hydrogen on-board storage problem // Int. Journal of Physical Sciences. 2015. Vol. 10, Iss. 2. P. 54-89 (an “open access” Journal).</mixed-citation></citation-alternatives></ref><ref id="cit28"><label>28</label><citation-alternatives><mixed-citation xml:lang="ru">Lobodjuk V.A., Estrin E.I. Martensite Transformation. Moscow: Fizmatlit, 2009, in Russian.</mixed-citation><mixed-citation xml:lang="en">Lobodjuk V.A., Estrin E.I. Martensite Transformation. Moscow: Fizmatlit, 2009, in Russian.</mixed-citation></citation-alternatives></ref><ref id="cit29"><label>29</label><citation-alternatives><mixed-citation xml:lang="ru">Koval Yu.N. Peculiarities of relaxation processes during martensite transformation // Usp. Fiz. Met. 2005. Vol. 6. P. 169-196.</mixed-citation><mixed-citation xml:lang="en">Koval Yu.N. Peculiarities of relaxation processes during martensite transformation // Usp. Fiz. Met. 2005. Vol. 6. P. 169-196.</mixed-citation></citation-alternatives></ref><ref id="cit30"><label>30</label><citation-alternatives><mixed-citation xml:lang="ru">Hu S., Lozada-Hidalgo M., Wang F.C., Mishchenko A., Schedin F., Nair R.R., Hill E.W., Boukhvalov D.W., Katsnelson M.I., Dryfe R.A.W., Grigorieva I.V., Wu H.A., Geim A.K. Proton transport through one atom thick crystals // Materials Science (cond-mat.mtrl-sci); Mesoscale and Nanoscale Physics (cond-mat.mes-hall), (Submitted on 31 Oct 2014), 10.1038/nature14015, arXiv:1410.8724 cond-mat.mtrl-sci. (or arXiv:1410.8724v1 cond-mat.mtrl-sci.).</mixed-citation><mixed-citation xml:lang="en">Hu S., Lozada-Hidalgo M., Wang F.C., Mishchenko A., Schedin F., Nair R.R., Hill E.W., Boukhvalov D.W., Katsnelson M.I., Dryfe R.A.W., Grigorieva I.V., Wu H.A., Geim A.K. Proton transport through one atom thick crystals // Materials Science (cond-mat.mtrl-sci); Mesoscale and Nanoscale Physics (cond-mat.mes-hall), (Submitted on 31 Oct 2014), 10.1038/nature14015, arXiv:1410.8724 cond-mat.mtrl-sci. (or arXiv:1410.8724v1 cond-mat.mtrl-sci.).</mixed-citation></citation-alternatives></ref><ref id="cit31"><label>31</label><citation-alternatives><mixed-citation xml:lang="ru">Naumov I.I., Hemley R.J. Aromaticity, Closed-Shell Effects, and Metallization of Hydrogen // Acc. Chem. Res. 2014. Vol. 47. P. 3551−3559.</mixed-citation><mixed-citation xml:lang="en">Naumov I.I., Hemley R.J. Aromaticity, Closed-Shell Effects, and Metallization of Hydrogen // Acc. Chem. Res. 2014. Vol. 47. P. 3551−3559.</mixed-citation></citation-alternatives></ref><ref id="cit32"><label>32</label><citation-alternatives><mixed-citation xml:lang="ru">Ting V.P., Ramirez-Cuesta A.J., Bimbo N., Sharpe J.E., Noguera-Diaz A., Presser V., Rudic S., Mays T.J. Direct Evidence for Solid-like Hydrogen in a Nanoporous Carbon Hydrogen Storage Material at Supercritical Temperatures // ACS Nano, Just Accepted Manuscript (2015). DOI: 10.1021/acsnano.5b02623, www.acsnano.org.</mixed-citation><mixed-citation xml:lang="en">Ting V.P., Ramirez-Cuesta A.J., Bimbo N., Sharpe J.E., Noguera-Diaz A., Presser V., Rudic S., Mays T.J. Direct Evidence for Solid-like Hydrogen in a Nanoporous Carbon Hydrogen Storage Material at Supercritical Temperatures // ACS Nano, Just Accepted Manuscript (2015). DOI: 10.1021/acsnano.5b02623, www.acsnano.org.</mixed-citation></citation-alternatives></ref><ref id="cit33"><label>33</label><citation-alternatives><mixed-citation xml:lang="ru">Nechaev Yu.S., Yurum A., Tekin A., Yavuz N.K., Yurum Yu., Veziroglu T.N. Fundamental open questions on engineering of super hydrogen sorption in graphite nanofibers: Relevance for clean energy applications // American Journal of Analytical Chemistry. 2014. Vol. 5, # 16. P. 1151-1165 (an “open access” Journal).</mixed-citation><mixed-citation xml:lang="en">Nechaev Yu.S., Yurum A., Tekin A., Yavuz N.K., Yurum Yu., Veziroglu T.N. Fundamental open questions on engineering of super hydrogen sorption in graphite nanofibers: Relevance for clean energy applications // American Journal of Analytical Chemistry. 2014. Vol. 5, # 16. P. 1151-1165 (an “open access” Journal).</mixed-citation></citation-alternatives></ref></ref-list><fn-group><fn fn-type="conflict"><p>The authors declare that there are no conflicts of interest present.</p></fn></fn-group></back></article>
