alternativeАльтернативная энергетика и экология (ISJAEE)Alternative Energy and Ecology (ISJAEE)1608-8298Международный издательский дом научной периодики "Спейс10.15518/isjaee.2015.21.010alternative-203Research ArticleВОДОРОДНАЯ ЭКОНОМИКАHYDROGEN ECONOMYТЕРМИЧЕСКАЯ ДЕКОМПОЗИЦИЯ ГИДРИДА ТИТАНАTHERMAL DECOMPOSITION OF TITANIUM HYDRIDEСпивакЛ. В.SpivakL. V.

д-р физ.-мат. наук, профессор кафедры физики твердого тела ПГНИУ, академик РАЕН, Засл. работник высшей школы

professor of solid state physics, Perm State National Research University, Dr. sci. sciences, Academy of Natural Sciences, Honored worker of higher school

lspivak@psu.ruЩепинаН. Е.ShchepinaN. E.

д-р хим. наук, профессор, старший научный сотрудник, зав. научно-исследовательской лабораторией радиохимии

head of the laboratory of radiochemistry of Natural Sciences Institute of Perm State University, senior scientist, Dr. sci. sciences (chemistry)

Пермский государственный национальный исследовательский университет 614990 Пермь, ул. Букирева, д. 15РоссияPerm State University 15 Bukirev str., Perm, 614990, RussiaRussian FederationЕстественнонаучный институт Пермского государственного национального исследовательского университета 614990 Пермь, ул. Генкеля, д. 4РоссияNatural Sciences Institute of Perm State University 4 Genkel str., Perm, 614990, RussiaRussian Federation2015060420160218499Copyright © Международный издательский дом научной периодики "Спейс, 20162016Международный издательский дом научной периодики "СпейсМеждународный издательский дом научной периодики "Спейсhttps://www.isjaee.com/jour/about/submissions#copyrightNoticehttps://www.isjaee.com/jour/article/view/203

Обзор посвящен ретроспективному анализу публикаций по исследованию термической диссоциации гидрида титана. Рассмотрены данные, полученные с использованием различных методик исследования: измерение кинетики выхода водорода в потоке нейтрального газа, дегазация в замкнутом объеме, дифференциальный термический анализ, дифференциальная калориметрия, термогравитационный анализ, масс-спектроскопия, рентгеноструктурный анализ и др. Обращено внимание на значительное расхождение в данных различных исследований, в том числе и проведенных с одинаковыми методиками. Предложена своя трактовка последовательности процессов, происходящих при термической диссоциации гидрида титана. Она предполагает три стадии этого процесса, завершающим этапом которых является образование твердого раствора водорода в титане как необходимого условия для выхода водорода из гидридных гранул.

The review is devoted to the retrospective analysis of publications on research of thermal dissociation of titanium hydride. The data obtained from application of various techniques of research are under consideration: measurement of kinetics of hydrogen exit in a stream of neutral gas, decontamination in the closed volume, the differential thermal analysis, a differential calorimetry, the thermogravitational analysis, masses spectroscopy, the X-ray diffraction analysis, etc. The attention to a considerable divergence in data of various researches, including carried out with the identical techniques is paid. The author’s interpretation of the sequence of the undergoing processes at thermal dissociation of titanium hydride is offered. It assumes three stages of this process which final stage is the formation of hydrogen solid solution in the titanium as a necessary condition for hydrogen exit from the hydride granules.

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The authors declare that there are no conflicts of interest present.