alternativeАльтернативная энергетика и экология (ISJAEE)Alternative Energy and Ecology (ISJAEE)1608-8298Международный издательский дом научной периодики "Спейс10.15518/isjaee.2021.09.124-146alternative-2110Research ArticleВОДОРОДНАЯ ЭКОНОМИКАHYDROGEN ECONOMYСовместный пиролиз отходов сельского хозяйства и оценка применимости пиролиза в комплексной технологии получения биовозобновляемого водородаCo-pyrolysis of agricultural waste and estimation of pyrolysis applicability in the integrated technology of biorenewable hydrogen productionКараеваЮ. В.KaraevaJ. V.

Караева Юлия Викторовна, ведущий научный сотрудник лаборатории энергетических систем и технологий, кандидат технических наук

SPIN: 3126-2342

Researcher ID: F-6917-2017

Scopus Author ID: 56856782800

420111, Казань, ул. Лобачевского, 2/31, а/я 190

Julia V. Karaeva, Leading Researcher, laboratory of Energy Systems and Technolo-gies, candidate of technical sciences

420111, Kazan, st. Lobachevsky, 2/31, PO Box 190, Russia

https://orcid.org/0000-0003-4168-2442ТимофееваС. С.TimofeevaS. S.

Тимофеева Светлана Сергеевна, старший научный сотрудник лаборатории энергетических систем и технологий, кандидат технических наук

SPIN: 1926-9396

Researcher ID: AAZ-5531-2020

Scopus Author ID: 56711352400

420111, Казань, ул. Лобачевского, 2/31, а/я 190

Svetlana S. Timofeeva, Senior Researcher, la-boratory of Energy Systems and Technologies, candidate of technical sciences

420111, Kazan, st. Lobachevsky, 2/31, PO Box 190, Russia

https://orcid.org/0000-0002-1983-3454КовалевА. А.KovalevA. A.

Ковалев Андрей Александрович, старший научный сотрудник лаборатории биоэнергетических и сверхкритических технологий, кандидат технических наук

SPIN: 4267-3026

Researcher ID: F-7045-2017

Scopus Author ID: 57205285134

109428, Москва, 1-й Институтский проезд, 5

Andrey A. Kovalev, senior researcher of the laboratory of bioenergy and supercritical technologies, candidate of tech-nical sciences

109428, Moscow, 1st Institutskiy Proezd, Building 5, Russia

https://orcid.org/0000-0002-3603-3686КовалевД. А.KovalevD. A.

Ковалев Дмитрий Александрович, заведующий лабораторией биоэнергетических технологий, кандидат технических наук

SPIN: 6513-5547

Researcher ID: K-4810-2015

109428, Москва, 1-й Институтский проезд, 5

Dmitry A. Kovalev, head of the laboratory of bioenergy and supercritical technologies, candidate of technical Sciences

109428, Moscow, 1st Institutskiy Proezd, Building 5, Russia

ГильфановМ. Ф.GilfanovM. F.

Гильфанов Марат Фанильевич, инженер кафедры химической технологии древесины

SPIN: 1446-5219

Scopus Author ID: 57197763198

420015, Казань, ул. К. Маркса, 68

Marat F. Gilfanov, Engineer, Department of Chemical Technology of Wood

420015, Kazan, st. Karl Marx, 68, Russia

https://orcid.org/0000-0001-6555-1864ГригорьевВ. С.GrigorievV. S.

Григорьев Виктор Степанович, главный научный сотрудник лаборатории биоэнергетических и сверхкритических технологий, доктор технических наук, кандидат химических наук

SPIN: 7156-6667

Researcher ID: B-4331-2019

109428, Москва, 1-й Институтский проезд, 5

Victor S. Grigoriev, chief researcher of the laboratory of bioenergy and supercritical technologies, doctor of technical sciences candidate of chemical sciences

109428, Moscow, 1st Institutskiy Proezd, Building 5, Russia

ЛиттиЮ. В.LittiYu. V.

Литти Юрий Владимирович, заведующий лабораторией микробиологии антропогенных мест обитания, кандидат биологических наук

SPIN: 1487-7611

Researcher ID: C-4945-2014

119071, Москва, Ленинский проспект, 33, строение 2

Yuriy V. Litti, Russian Academy of Sciences, Head of Laboratory of Microbiology of Anthropogenic Habitats, Candidate of Biological Sciences

119071, Moscow, Leninsky prospect, 33, building 2, Russia

Институт энергетики и перспективных технологий – структурное подразделение Федерального исследовательского центра «Казанский научный центр Российской академии наук»РоссияInstitute of Power Engineering and Advanced Technologies, FRC Kazan Scientific Center, Russian Academy of SciencesRussian FederationФедеральное государственное бюджетное научное учреждение “Федеральный научный агроинженерный центр ВИМ”РоссияFederal Government Budgetary Institution of Science “Federal Scientific Agroengeneering Сenter VIM”Russian FederationФедеральное государственное бюджетное образовательное учреждение высшего образования «Казанский национальный исследовательский технологический университет»РоссияKazan National Research Technological UniversityRussian FederationФИЦ Биотехнологии РАНРоссияResearch Center of Biotechnology of the Russian Academy of SciencesRussian Federation202102042022025-27124146Copyright © Международный издательский дом научной периодики "Спейс, 20222022Международный издательский дом научной периодики "СпейсМеждународный издательский дом научной периодики "Спейсhttps://www.isjaee.com/jour/about/submissions#copyrightNoticehttps://www.isjaee.com/jour/article/view/2110

Для производства биовозобновляемого водорода в работе исследовалась возможность применения пиролиза сельскохозяйственных отходов, а именно коровьего навоза и стеблей сорного растения Amaranthus retroflexus L. (AR), а также их смеси в соотношении 1:1, 2:1 и 4:1. Термогравиметрический анализ проводился при скорости нагрева 10°С/мин в интервале температур от 40°С до 1000°С. Показано, что для термического разложения сельскохозяйственных отходов в инертной среде характерны три основные стадии, наиболее значимая из которых находится в интервале температур от 145 до 410 С, при которой происходит максимальный выход летучих компонентов. Пиролиз проводили при температуре 550°С и скорости нагрева 10°С / мин. При пиролизе смеси сельскохозяйственных отходов материальный баланс имел в среднем следующий вид: 36,95 % пиролизной жидкости, 24,99 % газа и 38,06 % углистого остатка, а максимальная концентрация водорода в получаемом пиролизном газе составила 21,17% при соотношении коровьего навоза и AR 4:1. Такое соотношение позволило получить на 12,1 % водорода больше, чем при использовании смеси с соотношением 1:1. Увеличение доли AR обогащало пиролизную жидкость фенольными соединениями. Высокое содержание фиксированного углерода (в среднем 47,52%) в твердом углистом остатке привлекательно для его использования в качестве почвенных добавок. Для дальнейших исследований по увеличению выхода газообразного водорода из биомассы предложена схема биотермохимической переработки, предполагающей сочетание темновой ферментации и пиролиза.

For the production of biorenewable hydrogen, the possibility of using pyrolysis of agricultural waste, namely cow dung and stems of weeds Amaranthus retroflexus L. (AR), as well as their mixtures in a ratio of 1:1, 2: 1 and 4:1, was investigated. Thermogravimetric analysis was carried out at a heating rate of 10°C / min in the temperature range from 40°C to 1000°C. It was shown that the thermal decomposition of agricultural waste in an inert environment is characterized by three main stages, the most significant of which is in the temperature range from 145 to 410 C, at which the maximum yield of volatile components occurs. Pyrolysis was carried out at a temperature of 550°C and a heating rate of 10°C / min. During the pyrolysis of a mixture of agricultural waste, the material balance was on aver-age as follows: 36.95% pyrolysis liquid, 24.99% syngas and 38.06% biochar, and the maximum hydrogen concentra-tion in the resulting pyrolysis gas was 21.17% with cow dung to AR ratio of 4:1. With this ratio, the hydrogen yield was 12.1% higher than when using a mixture with a 1: 1 ratio. An increase in the AR fraction enriched the pyrolysis liquid with phenolic compounds. The high content of fixed carbon (47.52%) in biochar is attractive for its use as soil additives. For further research on increasing the yield of gaseous hydrogen from biomass, a scheme of bio-thermochemical processing was proposed, involving a combination of dark fermentation and pyrolysis.

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The authors declare that there are no conflicts of interest present.