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<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="ru"><front><journal-meta><journal-id journal-id-type="publisher-id">alternative</journal-id><journal-title-group><journal-title xml:lang="ru">Альтернативная энергетика и экология (ISJAEE)</journal-title><trans-title-group xml:lang="en"><trans-title>Alternative Energy and Ecology (ISJAEE)</trans-title></trans-title-group></journal-title-group><issn pub-type="ppub">1608-8298</issn><publisher><publisher-name>Международный издательский дом научной периодики "Спейс</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.15518/isjaee.2015.21.025</article-id><article-id custom-type="elpub" pub-id-type="custom">alternative-218</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>ЭКОЛОГИЧЕСКИЕ АСПЕКТЫ ЭНЕРГЕТИКИ</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="en"><subject>ENVIRONMENTAL ASPECTS OF ENERGY</subject></subj-group></article-categories><title-group><article-title>ЭНЕРГИИ АКТИВАЦИИ ПЕРЕСТРОЕК КЛАСТЕРНЫХ СТРУКТУР ВОДЫ</article-title><trans-title-group xml:lang="en"><trans-title>ACTIVATION ENERGY OF REARRANGEMENTS CLUSTER STRUCTURES OF WATER</trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Холманский</surname><given-names>А. С.</given-names></name><name name-style="western" xml:lang="en"><surname>Kholmanskiy</surname><given-names>A. S.</given-names></name></name-alternatives><bio xml:lang="ru"><p>д-р хим. наук, ст. научный сотрудник ВИЭСХ</p></bio><bio xml:lang="en"><p>PhD, VIESH</p></bio><email xlink:type="simple">allexhol@yandex.ru</email><xref ref-type="aff" rid="aff-1"/></contrib></contrib-group><aff-alternatives id="aff-1"><aff xml:lang="ru">Всероссийский научно-исследовательский институт электрификации сельского хозяйства (ВИЭСХ) 109456 Москва, 1-й Вешняковский проезд, д. 2<country>Россия</country></aff><aff xml:lang="en">The All-Russian Research Institute for Electrification of Agriculture (VIESH) 2, 1st Veshnyakovskii str., Moscow, 109456, Russia<country>Russian Federation</country></aff></aff-alternatives><pub-date pub-type="collection"><year>2015</year></pub-date><pub-date pub-type="epub"><day>07</day><month>04</month><year>2016</year></pub-date><volume>0</volume><issue>21</issue><fpage>188</fpage><lpage>194</lpage><permissions><copyright-statement>Copyright &amp;#x00A9; Международный издательский дом научной периодики "Спейс, 2016</copyright-statement><copyright-year>2016</copyright-year><copyright-holder xml:lang="ru">Международный издательский дом научной периодики "Спейс</copyright-holder><copyright-holder xml:lang="en">Международный издательский дом научной периодики "Спейс</copyright-holder><license xlink:href="https://www.isjaee.com/jour/about/submissions#copyrightNotice" xlink:type="simple"><license-p>https://www.isjaee.com/jour/about/submissions#copyrightNotice</license-p></license></permissions><self-uri xlink:href="https://www.isjaee.com/jour/article/view/218">https://www.isjaee.com/jour/article/view/218</self-uri><abstract><p>Несмотря на интенсивные исследования структуры и молекулярной динамики жидкой воды, до сих пор не известен термодинамический механизм дифференцирования экстремальных точек в температурных зависимостях ряда свойств воды. В настоящей работе изучили аномалии температурных зависимостей, применив метод линейных аппроксимаций. Оценили температурный градиент и энергию активации для каждой зависимости и сопоставили их с энергией водородной связи и энергиями собственных и кооперативных движений молекул воды в кластерах. Установили, что реакция разрыва водородной связи лимитирует в основном термодинамику аномалий динамической вязкости, самодиффузии и электропроводности воды. Термодинамика кооперативных и резонансных эффектов в кластерных структурах лежит в основе аномалий плотности, адиабатической теплоемкости, скорости звука, поверхностного натяжения и сжимаемости. Практически все линейные аппроксимации имели излом в районе 25 °С. С учетом известных данных предположили, что в этой точке происходит фазовый переход между состояниями воды с различной степенью спиральности сетки водородных связей. </p></abstract><trans-abstract xml:lang="en"><p>Despite intensive research on the structure and molecular dynamics of liquid water is still not known thermodynamic mechanism of differentiation of the extreme points of the temperature dependences of the properties of water. In the present work studied the anomalous temperature dependencies, by using the method of linear approximations. Estimated temperature gradient and the activation energy for each dependency and compared them with the energy of hydrogen bonds and energies of their own and cooperative motions of water molecules in clusters. Found that the reaction rupture of hydrogen bonds limit mainly thermodynamics anomalies dynamic viscosity, self-diffusion and conductivity of water. Thermodynamics cooperative and resonance effects in the cluster structures is the basis of density anomalies, adiabatic heat capacity, speed of sound, surface tension and compressibility. Almost all linear approximation had a fracture in the area of 25 °C. Given the known data suggested that at this point, a phase transition occurs between States of water with varying degrees of helicity of hydrogen bonds. </p></trans-abstract><kwd-group xml:lang="ru"><kwd>свойства воды</kwd><kwd>зависимость от температуры</kwd><kwd>кластеры</kwd><kwd>структура</kwd><kwd>энергия активации</kwd></kwd-group><kwd-group xml:lang="en"><kwd>water properties</kwd><kwd>temperature dependence</kwd><kwd>cluster</kwd><kwd>activation energy</kwd></kwd-group></article-meta></front><back><ref-list><title>References</title><ref id="cit1"><label>1</label><citation-alternatives><mixed-citation xml:lang="ru">Захаров С.Д., Мосягина И.В. Кластерная структура воды (обзор). Препринт ФИАН. 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