alternativeАльтернативная энергетика и экология (ISJAEE)Alternative Energy and Ecology (ISJAEE)1608-8298Международный издательский дом научной периодики "Спейс10.15518/isjaee.2023.01.077-105alternative-2186Research ArticleXII. ТРАНСПОРТНЫЕ ЭКОЛОГИЧЕСКИЕ СРЕДСТВА 29. Бортовые аккумуляторыXII. ENVIRONMENTAL VEHICLES 29. On-Board Energy AccumulatorsМетодологические основы оценки эффективности теплового аккумулятора, работающего на фазопереходных теплоаккумулирующих материалахThe salts hydrate phase change materials heat accumulator efficiency evaluating methodologyhttps://orcid.org/0000-0002-9735-3835ТестовД. С.TestovD. S.

Тестов Дмитрий Сергеевич - Ассистент, аспирант  кафедры химии, новых технологий и материалов

Университетская ул., д.19, г. Дубна,141980

Testov Dmitry Sergeevich - Ph.D. student, Senior Lecturer of the Chemistry Department

Universitetskaya str., 19, Dubna, 141980

dima13-1994@yandex.ruhttps://orcid.org/0000-0001-8395-136XМоржухинаС. В.MorzhukhinaS. V.

Моржухина Светлана Владимировна - канд. хим. наук, доцент, заведующий кафедрой химии, новых технологий и материалов

Университетская ул., д.19, г. Дубна,141980

Morzhukhina Svetlana  Vladimirovna - Ph.D. in Chemistry, Assistant Professor at the Heat of the Chemistry Department

Universitetskaya str., 19, Dubna, 141980

https://orcid.org/0000-0002-4584-347XМоржухинА. М.MorzhukhinA. M.

Моржухин Артём Маркович - аспирант, старшийпреподаватель кафедры химии, новых технологий и материалов

Университетская ул., д.19, г. Дубна,141980

Morzhykhin Artem Markovich - Ph.D. student, Senior Lecturer of the Chemistry Department

Universitetskaya str., 19, Dubna, 141980

https://orcid.org/0000-0002-8617-6650ГашимоваВ. Р.GashimovaV. R.

Гашимова Валерия Руслановна - Ассистент, аспирант кафедры химии, новых технологий и материалов

Университетская ул., д.19, г. Дубна,141980

Gashimova Valeriia Ruslanovna - Postgraduatestudent, assistant, of the Department of Chemistry,New Technologies and Materials

Universitetskaya str., 19, Dubna, 141980

https://orcid.org/0000-0002-7036-8594ГасиевА. Л.GasievA. L.

Гасиев Азамат Львович - студент кафедры химии, новых технологий и материалов

Университетская ул., д.19, г. Дубна,141980

Gasiev Azamat Lvovich - Student of the Department of Chemistry, New Technologies and Materials

Universitetskaya str., 19, Dubna, 141980

Государственный университет «Дубна»РоссияDubna State UniversityRussian Federation2023150320230177105Copyright © Международный издательский дом научной периодики "Спейс, 20232023Международный издательский дом научной периодики "СпейсМеждународный издательский дом научной периодики "Спейсhttps://www.isjaee.com/jour/about/submissions#copyrightNoticehttps://www.isjaee.com/jour/article/view/2186

Целью теплосберегающей энергетики в настоящее время является повышение эффективности потребляемых энерго и топливных ресурсов за счет создания и модернизации технологий, способных к эффективному сбору и длительному хранению тепловой энергии. Более рациональное потребление тепловой энергии, контролируемо используемой по мере необходимости, позволит перейти к энергосберегающей политике расхода ресурсов. Однако, одним из основных факторов, определяющих конкурентоспособность разрабатываемых энергосберегающих технологий остается финансовая составляющая. Ядром теплоаккумулирующей системы, вносящим до 80 % в стоимость систем хранения тепла, являются теплоаккумулирующие материалы. Это поднимает вопросы об оптимизации разрабатываемых технологий накопления и использования тепловой энергии в необходимом объеме, что сопровождается необходимостью отработки создаваемых теплоаккумулирующих материалов в условиях практической эксплуатации. В работе предлагается пошаговый подход к оптимизации свойств теплоаккумулирующих составов для повышения их эффективной работы в тепловом аккумуляторе. Это обуславливает необходимость рассмотрения параметров, обеспечивающих эффективную и безопасную работу теплового аккумулятора с использованием перспективных фазопереходных теплоаккумулирующих материалов на основе кристаллогидратов. Предлагаемый алгоритм, состоящий из методологии выбора кристаллогидратов и методологии исследования теплоаккумулирующих материалов апробирован при создании теплоаккумулирующего материала на основе CH3COONa·3H2O и показаны отличия представленных результатов в лабораторных и опытных условиях работы теплоаккумулирующего материала. В ходе синтеза смеси CH3COONa·3H2O и Na4P2O7·10H2O была существенно увеличена теплоемкость в жидкой фазе с 2.37 у CH3COONa·3H2O до 5.64 у фазопереходных теплоаккумулирующих материалов, энтальпия плавления с 226 до 259.8 кДж/кг. Переохлаждение ΔT снизилось с 90 до 1.45 °C, а температура плавления осталась на уровне 58 °C. При этом стоимость фазопереходных теплоаккумулирующих материалов увеличилась в 1.5 раза по сравнению с исходным ацетатом и составила 340 руб/кг. Это показывает значимость достигнутых результатов при проверке работоспособности теплоаккумулирующих материалов в условиях опытного образца теплового аккумулятора с целью их дальнейшей оптимизации. Разработанная методология полезна для исследователей, планирующих промышленный синтез полученных теплоаккумулирующих материалов, во избежание низкой эффективности опытного образца.

Currently the aim of heat-saving energy sector is to increase the efficiency of consuming energy and fuel resources through the creation and modernization of technologies capable of efficient collection and long-term storage of heat energy. A more rational consumption of heat energy, being in use under supervision when needed, will make it possible to pass on to energy storage policy of resource consumption. However, one of the main factors determining the competitiveness of the developing low-energy technologies is the financial component. The core of thermal energy storage system, contributing up to 80 % to the cost of heat storage systems, are heat-accumulating materials. This raises the issues o f the optimization o f the developed storage technologies a nd of the use of heat energy in the required volume, which is accompanied by the need to test the created heat storage materials in practical exploitation. The article proposes a step-by-step approach to optimizing the properties of heat storage compositions to improve their efficient operation in a heat accumulator. This necessitates the consideration of the parameters that ensure the efficient and safe operation of heat accumulator due to the use of advanced phase change materials based on hydrate salts. The provided algorithm, consisting of a methodology for the selection of hydrate salts and a methodology for investigating heat storage materials, was tested in creating the heat storage material based on CH3COONa·3H2O, and there were shown the differences between the results presented in laboratory conditions and results presented in experimental conditions of the heat storage material. During the synthesis of a mixture of CH3COONa·3H2O and Na4P2O7·10H2O, the heat capacity in the liquid phase increased significantly from 2.37 for CH3COONa·3H2O to 5.64 for phase change heat storage materials, and the enthalpy of melting from 226 to 259.8 kJ/kg. Subcooling ΔT decreased from 90 to 1.45 °C, while the melting point remained at 58 °C. In these circumstances, the cost of phase change heat storage materials increased by 1.5 times compared to the starting acetate and amounted to 340 rubles/kg. This shows the significance of the results achieved during the testing of the efficiency of phase change heat storage materials under the conditions of the developmental prototype of the heat accumulator with the purpose of further optimization. The developed methodology is useful for researchers planning the industrial synthesis of derived phase change heat storage materials in order to avoid the low efficiency of the prototype

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The authors declare that there are no conflicts of interest present.