References

alternative

Альтернативная энергетика и экология (ISJAEE)

Alternative Energy and Ecology (ISJAEE)

1608-8298

Международный издательский дом научной периодики "Спейс

10.15518/isjaee.2024.01.133-152

alternative-2372

Research Article

IV. ВОДОРОДНАЯ ЭКОНОМИКА 12. Водородная экономика

IV. HYDROGEN ECONOMY. 12. Hydrogen Economy

Характеристика электрода из активированного угля, полученного из прекурсора кокосовой скорлупы для использования в системах хранения водорода

Characterization of an activated carbon electrode made from coconut shell precursor for hydrogen storage applications

Маниш

Кумар Сингла

Manish

Kumar Singla

Маниш Кумар Сингла - доцент кафедры междисциплинарных инженерных курсов,

Пенджаб

Manish Kumar Singla - Assistant Professor in the Department of Interdisciplinary Courses in Engineering,

Rajpura, Punjab

Джиоти

Гуптаа

Jyoti

Guptaa

Джиоти Гупта - доцент кафедры школьного образования и инженерного дела, факультет компьютерных наук,

Гуруграм, Харьяна

Jyoti Gupta - Assistant Professor in the Department of School and Engineering, Department of Computer Science,

Gurugram, Haryana

Сафаралиев

Муродбек

Safaraliev

Murodbek

Сафаралиев Муродбек - к.т.н., старший научный сотрудник кафедры "Автоматизированных электрических систем", Уральский энергетический институт,

620002 Екатеринбург

Safaraliev M.Kh. - PhD, Senior Researcher, Department of «Automated Electrical Systems», Ural Power Engineering Institute,

620002 Yekaterinburg

Параг

Ниджхаван

Parag

Nijhawan

Параг Ниджхаван - доцент кафедры электротехники и приборостроения, Отдел электротехники и приборостроения

Parag Nijhawan - Associate Professor in the Department of Electrical and InstrumentationEngineering

Амандип

Сингх Оберой

Amandeep

Singh Oberoi

Амандип Сингх Оберой - доцент кафедры машиностроения, Факультет машиностроения

Amandeep Singh Oberoi - Associate Professor in the Department of Mechanical Engineering

Амир

Абдель Менаем

Amir

Abdel Menaem

Амир Абдель Менем - кандидат технических наук, научный сотрудник кафедры «Автоматизированные электрические системы», Уральский энергетический институт, 620002 Екатеринбург;

Факультет электротехники, 35516 Мансура

Amir Abdel Menaem - PhD, Researcher, Department of «Automated Electrical Systems», Ural Power Engineering Institute, 620002 Yekaterinburg;

Electrical Engineering Department, 35516 Mansoura

Инженерно-технологический институт Университета ЧиткараИндияChitkara University Institute of Engineering & Technology Chitkara UniversityIndia

Университет К. Р. МангаламаИндияK.R Mangalam UniversityIndia

Уральский федеральный университетРоссияUral Federal UniversityRussian Federation

Тапарский инженерно-технологический институт ПатиалыИндияThaparInstitue of Engineering and Technology PatialaIndia

Тапарский инженерно-технологический институт ПатиалыИндияThapar Institue of Engineering and Technology PatialaIndia

Уральский федеральный университет; Университет МансураЕгипетUral Federal University, Mansoura UniversityEgypt

2024

20052024

01133152

2023

Международный издательский дом научной периодики "Спейс

https://www.isjaee.com/jour/about/submissions#copyrightNotice

https://www.isjaee.com/jour/article/view/2372

Электрохимическое хранение водорода считается наиболее безопасным способом по сравнению с другими формами хранения, поэтому в последнее десятилетие оно привлекло значительное внимание исследователей. Пористые среды на основе углерода обладают множеством преимуществ, способствующих адсорбции в них водорода. В представленной работе исследуется возможность использования активированного угля, полученного из скорлупы кокосового ореха, для адсорбции водорода путем установления его физических и химических характеристик. Раскрыта процедура, используемая для характеристики. Площадь поверхности Брунауэра-Эммета-Теллера (БЭТ), средний размер кристаллов активированного угля составил 51,7 м2 /г, а средний размер кристаллов с помощью рентгеновской дифракции (XRD) составил 10,69 нм соответственно, что сопоставимо с опубликованными данными в литературе. На иллюстрации автоэмиссионной сканирующей электронной микроскопии обнаружено наличие хорошо развитых пор на поверхности образца активированного угля. Спектр инфракрасного анализа с преобразованием Фурье (FTIR) использовался для определения существования основных функциональных групп. Ультрафиолетово-видимая спектроскопия (УФ-В) используется для подтверждения наличия перехода π- π* внутри активированного угля. Работая в том же направлении, представленная работа представляет собой экспериментальное исследование по хранению ионного водорода в электроде из активированного угля, интегрированном в топливный элемент с модифицированным обратимым полимерным электролитом (PEMFC) для транспортных применений. Вход и выход водорода в разработанном PEMFC активной площадью 6,25 см2 успешно сохраняет 559,65 мАч/г во время зарядки и выдает 510,51 мАч/г при разрядке. Анализ результатов показал, что активированный уголь на основе скорлупы кокосового ореха может стать подходящим кандидатом для хранения водорода.

Electrochemical hydrogen storage is considered as the safest mode compared to the other storage forms, which is why it has attracted a significant research attention in the past decade. Carbon-based porous mediums offer many benefits that favor hydrogen adsorption in it. The presented work investigates the feasibility of coconut shell derived activated carbon for hydrogen adsorption by ascertaining its physical and chemical characteristics. The procedure employed for characterization is disclosed. Brunauer-Emmett-Teller (BET) surface area, average crystalline size of the activated carbon was found to be 51,7 m2 /g and average crystalline size using X-Ray Diffraction (XRD) to be 10,69 nm, respectively, which is comparable with the published data in literature. The scanning electron microscopy illustration of the field emission revealed the presence of well-developed pores on the surface of the sample activated carbon. The Fourier Transform Infrared Analysis (FTIR) spectrum was employed to determine the existence of essential functional groups. The ultraviolet-visible spectroscopy (UV-V) is used to confirm the presence of π- π* transition within the activated carbon. Working in the similar direction, the presented work is an experimental investigation on ionic hydrogen storage in an activated carbon electrode integrated in a modified reversible polymer electrolyte fuel cell (PEMFC) for transport applications that is carried out. The ingress and egress of hydrogen within the developed PEMFC of 6,25 cm2 active area successfully stored 559,65 mAh/g during charging and give out 510,51 mAh/g while discharging. The result analysis revealed the feasibility of the coconut shell based activated carbon to be a suitable candidate for hydrogen storage applications.

хранение водородарезервуар для водородаскорлупа кокосового орехахимическая активацияфизическая активациядревесный угольактивированный угольхарактеристика

hydrogen storagehydrogen tankcoconut shellchemical activationphysical activationcharcoalactivated carboncharacterization

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The authors declare that there are no conflicts of interest present.