alternativeАльтернативная энергетика и экология (ISJAEE)Alternative Energy and Ecology (ISJAEE)1608-8298Международный издательский дом научной периодики "Спейс10.15518/isjaee.2024.10.226-246alternative-2535Research ArticleXI. ИННОВАЦИОННЫЕ РЕШЕНИЯ, ТЕХНОЛОГИИ, УСТРОЙСТВА И ИХ ВНЕДРЕНИЕ. 25. Нанотехнологии для альтернативной энергетикиXI. INNOVATION SOLUTIONS, TECHNOLOGIES, FACILITIES AND THEIR INNOVATION. 25. Nanotechnology for renewable energyТеоретическое обоснование обработки сельскохозяйственных отходов потоком плазмы радиочастотного разряда низкого давления для получения нефтесорбентаTheoretical substantiation of low-pressure radio frequency plasma flow treatment of agricultural waste for producing oil sorbentШайхиевИ. Г.ShaikhievI. G.

Шайхиев Ильдар Гильманович, заведующий кафедрой «Инженерная экология», профессор, доктор техническихнаук

420015, Республика Татарстан, Казань, ул. К. Маркса, 68

Shaikhiev Ildar Gilmanovich, Head of the Engineering Ecology Department, professor, Doctor of Technical Sciences

420015, Republic of Tatarstan, Kazan, st. K. Marx, 68

ildars@inbox.ruСтепановаС. В.StepanovaS. V.

Степанова Светлана Владимировна, профессор кафедры «Инженерная экология», доктор техническихнаук

420015, Республика Татарстан, Казань, ул. К. Маркса, 68

Stepanova Svetlana Vladimirovna, Professor of the Engineering Ecology Department, Doctor of Technical Sciences

420015, Republic of Tatarstan, Kazan, st. K. Marx, 68

 

СанатулловаЗ. Т.SanatullovaZ. T.

Санатуллова Земфира Талгатовна, доцент кафедры «Инженерная экология», кандидат техническихнаук

420015, Республика Татарстан, Казань, ул. К. Маркса, 68

Sanatullova Zemfira Talgatovna, Associate Professor of the Engineering Ecology Department, Candidate of Technical Sciences

420015, Republic of Tatarstan, Kazan, st. K. Marx, 68

КрайсманН. В.KraysmanN. V.

Крайсман Наталья Владимировна, доцент кафедры «Иностранные языки в профессиональной коммуникации», кандидат исторических наук

420015, Республика Татарстан, Казань, ул. К. Маркса, 68

Kraysman Natalia Vladimirovna, Associate Professor of the Department of Foreign Languages for Professional Communication, Candidate ofHistorical Sciences

420015, Republic of Tatarstan, Kazan, st. K. Marx, 68

ПолитаеваН. А.PolitaevaN. A.

Политаева Наталья Анатольевна, профессор Высшей школы гидротехнического и энергетического строительства

195251, г. Санкт-Петербург, ул. Политехническая, 29

Politaeva Natalia Anatolevna, professor at the Higher School of Hydraulic and Energy Construction

195251, St. Petersburg, st. Politekhnicheskaya, 29

ЧусовА. Н.ChusovA. N.

Чусов Александр Николаевич, профессор Высшей школы гидротехнического и энергетического строительства

195251, г. Санкт-Петербург, ул. Политехническая, 29 

Chusov Alexander Nikolaevich, professor at the Higher School ofHydraulic and Energy Construction

195251, St. Petersburg, st. Politekhnicheskaya, 29

ВельможинаК. А.VelmozhinaK. A.

Вельможина Ксения Алексеевна, инженер в НИЛ «Промышленная экология»

195251, г. Санкт-Петербург, ул. Политехническая, 29

Velmozhina Ksenia Alekseevna, engineer at the research Laboratory of «Industrial Ecology»

195251, St. Petersburg, st. Politekhnicheskaya, 29

ШинкевичП. С.ShinkevichP. S.

Шинкевич Полина Сергеевна, инженер в НИЛ «Промышленная экология»

195251, г. Санкт-Петербург, ул. Политехническая, 29

Shinkevich Polina Sergeevna, engineer at the research Laboratory of «Industrial Ecology»

195251, St. Petersburg, st. Politekhnicheskaya, 29

ФГБОУ ВО «Казанский национальный исследовательский технологический университет»РоссияKazan National Research Technological UniversityRussian FederationФГАОУ ВО «Санкт-Петербургский политехнический университет Петра Великого»РоссияPeter the Great St. Petersburg Polytechnic UniversityRussian Federation202423012025010226245Copyright © Международный издательский дом научной периодики "Спейс, 20252025Международный издательский дом научной периодики "СпейсМеждународный издательский дом научной периодики "Спейсhttps://www.isjaee.com/jour/about/submissions#copyrightNoticehttps://www.isjaee.com/jour/article/view/2535

В статье представлено глубокое исследование теоретической основы повышения сорбционной способности материалов, полученных из сельскохозяйственных отходов с помощью революционной методики 3D-обработки в среде плазмы радиочастотного разряда низкого давления. Проводится тщательный анализ, предлагающий всестороннее изложение сложных физических и математических моделей, регулирующих многоаспектные динамики взаимодействия между плазмой радиочастотного разряда низкого давления (LP-RF) и капиллярнопористыми биополимерами. Посредством использования сложных методов математического моделирования исследование детально анализирует и объясняет сложные процессы, происходящие при структурных изменениях на супрамолекулярном уровне этих материалов по всему объему во время обработки плазмой. Это исчерпывающее теоретическое исследование не только позволяет выявить и разъяснить ключевые механизмы, ответственные за индукцию структурных преобразований, но и раскрывает сложное взаимодействие различных факторов, влияющих на конечное улучшение сорбционных свойств материалов, основанных на сельскохозяйственных отходах.

The paper provides an in-depth exploration of the theoretical framework underpinning the enhancement of sorption capacity in materials derived from agricultural waste through the revolutionary technique of 3D treatment within a lowpressure radio frequency discharge plasma environment. It undertakes a rigorous examination, offering a comprehensive exposition of the intricate physical and mathematical models governing the multifaceted interaction dynamics between low-pressure radio frequency (LP-RF) plasma and capillary porous biopolymers. By employing sophisticated mathematical modeling methodologies, the study meticulously dissects and elucidates the complex processes involved in orchestrating structural modifications across the supramolecular landscape of these materials throughout their entire volume during plasma treatment. This exhaustive theoretical inquiry not only enables the discernment and elucidation of pivotal mechanisms responsible for inducing structural transformations but also unveils the intricate interplay of various factors influencing the ultimate enhancement of sorption properties in agricultural waste-based materials.

сельскохозяйственные отходыобработка плазмойматематическая модельфизическая модельagricultural wasteplasma treatmentmathematical modelphysical modelReferences. Penkov O. V., Khadem M., Lim W. S., Kim D. E. A review of recent applications of atmospheric pressure plasma jets for materials processing. Journal of Coatings Technology and Research. 2015, 12, 225-235. DOI: 10.1007/s11998-014-9638-z.. Penkov O. V., Khadem M., Lim W. S., Kim D. E. A review of recent applications of atmospheric pressure plasma jets for materials processing. Journal of Coatings Technology and Research. 2015, 12, 225-235. DOI: 10.1007/s11998-014-9638-z.. Nisar A., Zhang C., Boesl B., Agarwal A. Unconventional materials processing using spark plasma sintering. Ceramic. 2021, 4(1), 20-39. DOI: 10.3390/ceramics4010003.. Nisar A., Zhang C., Boesl B., Agarwal A. Unconventional materials processing using spark plasma sintering. Ceramic. 2021, 4(1), 20-39. DOI: 10.3390/ceramics4010003.. Cheruthazhekatt S., Černák M., Slavíček P. & Havel J. Gas plasmas and plasma modified materials in medicine // Journal of Applied Biomedicine. 2010, 8(2), 55-66. DOI 10.2478/v10136-009-0013-9. Cheruthazhekatt S., Černák M., Slavíček P. & Havel J. Gas plasmas and plasma modified materials in medicine // Journal of Applied Biomedicine. 2010, 8(2), 55-66. DOI 10.2478/v10136-009-0013-9. Pavlatová M., Horáková M., Hladík J., Špatenka P. Plasma surface treatment of powder materials – Process and application // Acta Polytechnica. – 2012, 52(3). DOI: 10.14311/1562.. Pavlatová M., Horáková M., Hladík J., Špatenka P. Plasma surface treatment of powder materials – Process and application // Acta Polytechnica. – 2012, 52(3). DOI: 10.14311/1562.. Kaseem M., Fatimah S., Nashrah N., Ko Y. G. Recent progress in surface modification of metals coated by plasma electrolytic oxidation: Principle, structure, and performance // Progress in Materials Science. – 2021, 117, 100735. DOI: 10.1016/j.pmatsci.2020.100735.. Kaseem M., Fatimah S., Nashrah N., Ko Y. G. Recent progress in surface modification of metals coated by plasma electrolytic oxidation: Principle, structure, and performance // Progress in Materials Science. – 2021, 117, 100735. DOI: 10.1016/j.pmatsci.2020.100735.. Keidar M., Yan D., Sherman J. H. Plasma as a fourth state of matter. In Cold Plasma Cancer Therapy // Morgan & Claypool Publishers. – 2019, 1-3. DOI: 10.1088/2053-257/aafb9ccn1. Keidar M., Yan D., Sherman J. H. Plasma as a fourth state of matter. In Cold Plasma Cancer Therapy // Morgan & Claypool Publishers. – 2019, 1-3. DOI: 10.1088/2053-257/aafb9ccn1. Conrads H., Schmidt M. Plasma generation and plasma sources // Plasma Sources Science and Technology. – 2000, 9(4), 441-454.. Conrads H., Schmidt M. Plasma generation and plasma sources // Plasma Sources Science and Technology. – 2000, 9(4), 441-454.. Laroussi M., Akan T. Arc-free atmospheric pressure cold plasma jets: a review // Plasma Processes and Polymers. – 2007, 4(9), 777-788. DOI: 10.1002/ppap.200700066.. Laroussi M., Akan T. Arc-free atmospheric pressure cold plasma jets: a review // Plasma Processes and Polymers. – 2007, 4(9), 777-788. DOI: 10.1002/ppap.200700066.. Zhou R., Zhou R., Wang P., Xian Y., Mai-Prochnow A., Lu X., Bazaka K. Plasma-activated water: Generation, origin of reactive species and biological applications // Journal of Physics D: Applied Physics. – 2020, 53(30), 303001. DOI 10.1088/1361-6463/ab81cf.. Zhou R., Zhou R., Wang P., Xian Y., Mai-Prochnow A., Lu X., Bazaka K. Plasma-activated water: Generation, origin of reactive species and biological applications // Journal of Physics D: Applied Physics. – 2020, 53(30), 303001. DOI 10.1088/1361-6463/ab81cf.. George A., Shen B., Craven M., Wang Y., Kang D., Wu C., Tu X. A Review of Non-Thermal Plasma Technology: A novel solution for CO2 conversion and utilization // Renewable and Sustainable Energy Reviews. 2021, 135, 109702. DOI: 10.1016/j.rser.2020.109702.. George A., Shen B., Craven M., Wang Y., Kang D., Wu C., Tu X. A Review of Non-Thermal Plasma Technology: A novel solution for CO2 conversion and utilization // Renewable and Sustainable Energy Reviews. 2021, 135, 109702. DOI: 10.1016/j.rser.2020.109702.. Chen G., Raja L. L. Fluid modeling of electron heating in low-pressure, high-frequency capacitively coupled plasma discharges // Journal of Applied Physics. – 2004, 96(11), 6073-6081.. Chen G., Raja L. L. Fluid modeling of electron heating in low-pressure, high-frequency capacitively coupled plasma discharges // Journal of Applied Physics. – 2004, 96(11), 6073-6081.. Laroussi M. Cold plasma in medicine and healthcare: The new frontier in low temperature plasma applications // Frontiers in Physics. – 2020, 8, 74. DOI: 10.3389/fphy.2020.00074.. Laroussi M. Cold plasma in medicine and healthcare: The new frontier in low temperature plasma applications // Frontiers in Physics. – 2020, 8, 74. DOI: 10.3389/fphy.2020.00074.. Chen H., Yuan D., Wu A., Lin X., Li X. Review of low-temperature plasma nitrogen fixation technology // Waste Disposal & Sustainable Energy. – 2021, 3, 201-217. DOI: 10.1007/s42768-021-00074-z.. Chen H., Yuan D., Wu A., Lin X., Li X. Review of low-temperature plasma nitrogen fixation technology // Waste Disposal & Sustainable Energy. – 2021, 3, 201-217. DOI: 10.1007/s42768-021-00074-z.. Jelil R. A. A review of low-temperature plasma treatment of textile materials // Journal of Materials Science. – 2015, 50(18), 5913-5943. DOI: 10.1007/s10853015-9152-4.. Jelil R. A. A review of low-temperature plasma treatment of textile materials // Journal of Materials Science. – 2015, 50(18), 5913-5943. DOI: 10.1007/s10853015-9152-4.. Bhattacharjee S., Dutta T. An overview of oil pollution and oil-spilling incidents. Advances in Oil-Water Separation. – 2022, 3-15. DOI: 10.1016/B978-0-32389978-9.00014-8.. Bhattacharjee S., Dutta T. An overview of oil pollution and oil-spilling incidents. Advances in Oil-Water Separation. – 2022, 3-15. DOI: 10.1016/B978-0-32389978-9.00014-8.. Hassanshahian M., Amirinejad N., Askarinejad Behzadi M. Crude oil pollution and biodegradation at the Persian Gulf: A comprehensive and review study // Journal of Environmental Health Science and Engineering. – 2020, 18, 1415-1435. DOI: 10.1007/s40201-02000557-x.. Hassanshahian M., Amirinejad N., Askarinejad Behzadi M. Crude oil pollution and biodegradation at the Persian Gulf: A comprehensive and review study // Journal of Environmental Health Science and Engineering. – 2020, 18, 1415-1435. DOI: 10.1007/s40201-02000557-x.. Koundinya K. K., Mondal S., Bose A. An overview of worldwide regulations on oil pollution control // Advances in Oil-Water Separation. – 2022, 65-82. DOI: 10.1016/B978-0-323-89978-9.00001-X.. Koundinya K. K., Mondal S., Bose A. An overview of worldwide regulations on oil pollution control // Advances in Oil-Water Separation. – 2022, 65-82. DOI: 10.1016/B978-0-323-89978-9.00001-X.. Kalter V., Passow U. Quantitative review summarizing the effects of oil pollution on subarctic and arctic marine invertebrates // Environmental Pollution. – 2022, 120960. DOI: 10.1016/j.envpol.2022.120960.. Kalter V., Passow U. Quantitative review summarizing the effects of oil pollution on subarctic and arctic marine invertebrates // Environmental Pollution. – 2022, 120960. DOI: 10.1016/j.envpol.2022.120960.. Al-Jammal N., Juzsakova T. Review on the effectiveness of adsorbent materials in oil spills clean up. Sea. – 2017, 25, 36, 131-138. Al-Jammal N., Juzsakova T. Review on the effectiveness of adsorbent materials in oil spills clean up. Sea. – 2017, 25, 36, 131-138. Husseien M., Amer A. A., El-Maghraby A., Taha N. A. Availability of barley straw application on oil spill clean up // International Journal of Environmental Science & Technology. – 2009, 6, 123-130. DOI: 10.1007/BF03326066.. Husseien M., Amer A. A., El-Maghraby A., Taha N. A. Availability of barley straw application on oil spill clean up // International Journal of Environmental Science & Technology. – 2009, 6, 123-130. DOI: 10.1007/BF03326066.. Zhou Y., Zhang L., Cheng Z. Removal of organic pollutants from aqueous solution using agricultural wastes: a review // Journal of Molecular Liquids. – 2015, 212, 739-762. DOI: 10.1016/j.molliq.2015.10.023.. Zhou Y., Zhang L., Cheng Z. Removal of organic pollutants from aqueous solution using agricultural wastes: a review // Journal of Molecular Liquids. – 2015, 212, 739-762. DOI: 10.1016/j.molliq.2015.10.023.. Galblaub O. A., Shaykhiev I. G., Stepanova S. V., Timirbaeva G. R. Oil spill cleanup of water surface by plant-based sorbents: Russian practices. Process Safety and Environmental Protection. – 2016, 101, 88-92. DOI: 10.1016/j.psep.2015.11.002.. Galblaub O. A., Shaykhiev I. G., Stepanova S. V., Timirbaeva G. R. Oil spill cleanup of water surface by plant-based sorbents: Russian practices. Process Safety and Environmental Protection. – 2016, 101, 88-92. DOI: 10.1016/j.psep.2015.11.002.. Ifelebuegu A. O., Johnson A. Nonconventional low-cost cellulose-and keratin-based biopolymeric sorbents for oil/water separation and spill cleanup: A review. Critical Reviews in Environmental Science and Technology. – 2017, 47(11), 964-1001. DOI: 10.1080/10643389.2017.1318620.. Ifelebuegu A. O., Johnson A. Nonconventional low-cost cellulose-and keratin-based biopolymeric sorbents for oil/water separation and spill cleanup: A review. Critical Reviews in Environmental Science and Technology. – 2017, 47(11), 964-1001. DOI: 10.1080/10643389.2017.1318620.. Dai Y., Sun Q., Wang W., Lu L., Liu M., Li J., Zhang Y. Utilizations of agricultural waste as adsorbent for the removal of contaminants: A review. Chemosphere. – 2018, 211, 235-253. DOI: 10.1016/j.chemosphere.2018.06.179.. Dai Y., Sun Q., Wang W., Lu L., Liu M., Li J., Zhang Y. Utilizations of agricultural waste as adsorbent for the removal of contaminants: A review. Chemosphere. – 2018, 211, 235-253. DOI: 10.1016/j.chemosphere.2018.06.179.. Noor A., Khan S. A. Agricultural Wastes as Renewable Biomass to Remediate Water Pollution. Sustainability. – 2023, 15(5), 4246. DOI: 10.3390/su15054246.. Noor A., Khan S. A. Agricultural Wastes as Renewable Biomass to Remediate Water Pollution. Sustainability. – 2023, 15(5), 4246. DOI: 10.3390/su15054246.. Wolok E., Barafi J., Joshi N., Girimonte R., Chakraborty S. Study of bio-materials for removal of the oil spill // Arabian Journal of Geosciences. – 2020, 13, 1-11. DOI: 10.1007/s12517-020-06244-3.. Wolok E., Barafi J., Joshi N., Girimonte R., Chakraborty S. Study of bio-materials for removal of the oil spill // Arabian Journal of Geosciences. – 2020, 13, 1-11. DOI: 10.1007/s12517-020-06244-3.. Doshi B., Sillanpää M., Kalliola S. A review of bio-based materials for oil spill treatment. Water Research. (2018, 135, 262-277. DOI: 10.1016/j.watres.2018.02.034.. Doshi B., Sillanpää M., Kalliola S. A review of bio-based materials for oil spill treatment. Water Research. (2018, 135, 262-277. DOI: 10.1016/j.watres.2018.02.034.. Alekseeva A. A., Stepanova S. V. Effect of plasma surface modification of mixed leaf litter on the mechanism of oil film removal from water bodies // Russian Journal of General Chemistry. – 2019, 89, 763–2768. DOI: 10.1134/s107036321913005x. Alekseeva A. A., Stepanova S. V. Effect of plasma surface modification of mixed leaf litter on the mechanism of oil film removal from water bodies // Russian Journal of General Chemistry. – 2019, 89, 763–2768. DOI: 10.1134/s107036321913005x. Shaikhiev I. G. Ecological and technological bases of modification and application of waste processing of wool and flax for the purification of polluted waters. Dissertation for the degree of Doctor of Sciences, Kazan National Research Technological University, Kazan, 2011, 357 p. (in Russian). Shaikhiev I. G. Ecological and technological bases of modification and application of waste processing of wool and flax for the purification of polluted waters. Dissertation for the degree of Doctor of Sciences, Kazan National Research Technological University, Kazan, 2011, 357 p. (in Russian). Sanatullova Z. T. Removal of oils from the water surface of plasma by modified felting and felt production waste. Dissertation for the degree of Candidate of Sciences, Kazan National Research Technological University, Kazan, 2017, 136 p. (in Russian). Sanatullova Z. T. Removal of oils from the water surface of plasma by modified felting and felt production waste. Dissertation for the degree of Candidate of Sciences, Kazan National Research Technological University, Kazan, 2017, 136 p. (in Russian)

The authors declare that there are no conflicts of interest present.