alternativeАльтернативная энергетика и экология (ISJAEE)Alternative Energy and Ecology (ISJAEE)1608-8298Международный издательский дом научной периодики "Спейсalternative-27Research ArticleВОДОРОДНАЯ ЭКОНОМИКАHYDROGEN ECONOMYОБ ИНТЕРКАЛЯЦИИ H2 НАНОФАЗЫ В ГРАФЕНОВЫЕ СЛОИСТЫЕ СТРУКТУРЫ В СВЯЗИ СО СПИЛЛОВЕР ЭФФЕКТОМON THE H2 NANOPHASE INTERCALATION INTO GRAPHENE-LAYERS STRUCTURES: RELEVANCE TO THE SPILLOVER EFFECTНечаевЮ. С.NechaevYu. S.

д-р  ф.-мат  наук,  профессор,  главный  научный  сотрудник

Dr. Sc., Prof., Chief researcher

Yuri1939@inbox.ruЦНИИчермет им. И.П. Бардина, Институт металловедения и физики металлов им. Г.В. КурдюмоваРоссияI.P. Bardin Central Research Institute for Ferrous Metallurgy, G.V. Kurdjumov Institute of Metals Science and PhysicsRussian Federation201507112015063740Copyright © Международный издательский дом научной периодики "Спейс, 20152015Международный издательский дом научной периодики "СпейсМеждународный издательский дом научной периодики "Спейсhttps://www.isjaee.com/jour/about/submissions#copyrightNoticehttps://www.isjaee.com/jour/article/view/27

Рассматриваются  экспериментальные  данные,  демонстрирующие  проявление  спилловер  эффекта при интеркаляции твердого водорода в графитовые нановолокна.

Experimental data on manifestation of the spillover effect, when intercalation of the solid hydrogen into graphite nanofibers, are considered.

высоко ориентированный пиролитический графит (ВОПГ)эпитаксиальные графеныграфитовые нановолокнагидрированиетвердый водородинтеркаляцияхранение H2спилловер эффектHOPGepitaxial graphenesgraphite nanofibershydrogenationsolid hydrogenintercalationH2 storagespillover effectReferencesNechaev Yu.S., Filippova V.P., Alp Yurum, Yuda Yurum, Veziroglu N.T. The Reversible hydrogenation-dehydrogenation of membrane and epitaxial graphenes // Journal of Chemical Engineering and Chemical Research, Vol. 2, # 1 (2015) p.p. 421-457.Nechaev Yu.S., Filippova V.P., Alp Yurum, Yuda Yurum, Veziroglu N.T. The Reversible hydrogenation-dehydrogenation of membrane and epitaxial graphenes // Journal of Chemical Engineering and Chemical Research, Vol. 2, # 1 (2015) p.p. 421-457.Nechaev Yu.S. and Nejat Veziroglu T. On the hydrogenation-dehydrogenation of graphene-layer-nanostructures: Relevance to the hydrogen on-board storage problem // Int. Journal of Physical Sciences, Vol. 10, Iss. 2 (2015) P. 54-89.Nechaev Yu.S. and Nejat Veziroglu T. On the hydrogenation-dehydrogenation of graphene-layer-nanostructures: Relevance to the hydrogen on-board storage problem // Int. Journal of Physical Sciences, Vol. 10, Iss. 2 (2015) P. 54-89.Nechaev Yu.S., Alp Yurum, Adem Tekin, Nilgun Karatepe Yavuz, Yuda Yurum, Veziroglu N.T. Fundamental open questions on engineering of super hydrogen sorption in graphite nanofibers: Relevance for clean energy applications // American Journal of Analytical Chemistry, Vol. 5, # 16 (2014) P. 1151-1165.Nechaev Yu.S., Alp Yurum, Adem Tekin, Nilgun Karatepe Yavuz, Yuda Yurum, Veziroglu N.T. Fundamental open questions on engineering of super hydrogen sorption in graphite nanofibers: Relevance for clean energy applications // American Journal of Analytical Chemistry, Vol. 5, # 16 (2014) P. 1151-1165.Nechaev Yu.S. and Veziroglu N.T. On thermodynamic characteristics of the thermal desorption of hydrogen from hydrogenated graphene layers. Chapter 4, in: Handbook of Carbon Nanomaterials, Vol. 5, Graphene – Fundamental Properties. Eds. F. D’Souza, K.M. Kadish. World Scientific Publ. Co Pte. Ltd., Singapore, (20014) P. 219-258.Nechaev Yu.S. and Veziroglu N.T. On thermodynamic characteristics of the thermal desorption of hydrogen from hydrogenated graphene layers. Chapter 4, in: Handbook of Carbon Nanomaterials, Vol. 5, Graphene – Fundamental Properties. Eds. F. D’Souza, K.M. Kadish. World Scientific Publ. Co Pte. Ltd., Singapore, (20014) P. 219-258.Nechaev Yu.S. and Veziroglu N.T. Thermodynamic aspects of the stability of the graphene/graphane/hydrogen systems, relevance to the hydrogen on-board storage problem // Advances in Materials Physics and Chemistry. Vol. 3 (2013) P. 255-280.Nechaev Yu.S. and Veziroglu N.T. Thermodynamic aspects of the stability of the graphene/graphane/hydrogen systems, relevance to the hydrogen on-board storage problem // Advances in Materials Physics and Chemistry. Vol. 3 (2013) P. 255-280.Nechaev Yu.S., Veziroglu T.N. On thermodynamic stability of hydrogenated graphene layers, relevance to the hydrogen on-board storage // The Open Fuel Cells Journal. Vol. 6 (2013) P. 21–39.Nechaev Yu.S., Veziroglu T.N. On thermodynamic stability of hydrogenated graphene layers, relevance to the hydrogen on-board storage // The Open Fuel Cells Journal. Vol. 6 (2013) P. 21–39.Nechaev Yu.S. Physical and chemical interactions of hydrogen with carbonaceous nanostructures (An analytical study – indirect experiment). Chapter 2, in: Carbon Nanomaterials for Gas Adsorption. Eds. M.L. Teranova, S. Orlanducci, M. Rossi. Pan Stanford Publ. Pte. Ltd., Singapore (2013) P. 39-130.Nechaev Yu.S. Physical and chemical interactions of hydrogen with carbonaceous nanostructures (An analytical study – indirect experiment). Chapter 2, in: Carbon Nanomaterials for Gas Adsorption. Eds. M.L. Teranova, S. Orlanducci, M. Rossi. Pan Stanford Publ. Pte. Ltd., Singapore (2013) P. 39-130.Nechaev Yu.S. Solid hydrogen intercalation in closed graphane-hydride-like nanostructures, Relevance to the storage applications. Chapter 5, in: Nanotechnology, Vol. 6, Energy and Environment. Eds. S. Sinha, N.K. Navani, G.N. Govil. Stadium Press LLS, U.S.A. (2013) P. 111-136.Nechaev Yu.S. Solid hydrogen intercalation in closed graphane-hydride-like nanostructures, Relevance to the storage applications. Chapter 5, in: Nanotechnology, Vol. 6, Energy and Environment. Eds. S. Sinha, N.K. Navani, G.N. Govil. Stadium Press LLS, U.S.A. (2013) P. 111-136.Nechaev Yu.S. On the solid hydrogen intercalation in multilayer carbohydride-like graphane nanostructures, relevance to storage applications // Journal of Nano Research, Vol. 15 (2011) P. 75-93.Nechaev Yu.S. On the solid hydrogen intercalation in multilayer carbohydride-like graphane nanostructures, relevance to storage applications // Journal of Nano Research, Vol. 15 (2011) P. 75-93.Nechaev Yu.S. The high-density hydrogen carrier intercalation in graphane-like nanostructures, relevance to its on-board storage in fuel-cell-powered vehicles // The Open Fuel Cells Journal, Vol. 4 (2011) P.p. 16-29.Nechaev Yu.S. The high-density hydrogen carrier intercalation in graphane-like nanostructures, relevance to its on-board storage in fuel-cell-powered vehicles // The Open Fuel Cells Journal, Vol. 4 (2011) P.p. 16-29.Nechaev Yu.S. On the solid hydrogen carrier intercalation in graphane-like regions in carbon-based nanostructures // Int. Journal of Hydrogen Energy, Vol. 36, # 15 (2011) P. 9023-9031.Nechaev Yu.S. On the solid hydrogen carrier intercalation in graphane-like regions in carbon-based nanostructures // Int. Journal of Hydrogen Energy, Vol. 36, # 15 (2011) P. 9023-9031.Nechaev Yu.S. Carbon nanomaterials, relevance to solving the hydrogen storage problem // Journal of Nano Research, Vol. 12 (2010) P. 1-44.Nechaev Yu.S. Carbon nanomaterials, relevance to solving the hydrogen storage problem // Journal of Nano Research, Vol. 12 (2010) P. 1-44.

The authors declare that there are no conflicts of interest present.