alternativeАльтернативная энергетика и экология (ISJAEE)Alternative Energy and Ecology (ISJAEE)1608-8298Международный издательский дом научной периодики "Спейс10.15518/isjaee.2025.11.107-124alternative-2730Research ArticleIV. ВОДОРОДНАЯ ЭКОНОМИКА. 12. Водородная экономика. 12-5-12-0 Новые способы получения водорода. 12-5-12-0 Топливные элементыIV. HYDROGEN ECONOMY. 12. Hydrogen economy. 12-5-12-0 Hydrogen production methods. 12-5-12-0 Novel hydrogen production methodsКонцепция электрохимического кондиционирования биоводорода, получаемого в процессе темновой ферментацииConcept of electrochemical conditioning of biohydrogen produced during dark fermentation processhttps://orcid.org/0000-0002-3603-3686КовалевД. А.KovalevD. A.

Ковалев Дмитрий Александрович, кандидат технических наук, заведующий лабораторией биоэнергетических технологий,

109428, г. Москва, 1-й Институтский проезд, 5.

Researcher ID: K-4810-2015.

Kovalev Dmitry Alexandrovich, Head of the Laboratory of Bioenergy and Supercritical Technologies, Candidate of Technical Sciences,

109428, Moscow, 1-y Institutskiy proezd, 5.

Researcher ID: K-4810-2015.

https://orcid.org/0000-0002-0508-6929СафоновА. В.SafonovA. V.

Сафонов Александр Владимирович, инженер лаборатории биоэнергетических технологий,

109428, г. Москва, 1-й Институтский проезд, 5.

Researcher ID: AAE-1039-2022.

Safonov Alexander Vladimirovich, Engineer of the Laboratory of Bioenergy and Supercritical Technologies,

109428, Moscow, 1-y Institutskiy proezd, 5.

Researcher ID: AAE-1039-2022.

https://orcid.org/0000-0002-4689-843XПанченкоВ. А.PanchenkoV. A.

Панченко Владимир Анатольевич, кандидат технических наук, доцент кафедры,

127994, г. Москва, ул. Образцова, д. 9

Researcher ID: P-8127-2017; Scopus Author ID: 57201922860; Web of Science Researcher ID: AAE-1758-2019.

Panchenko Vladimir Anatolyevich, Candidate of Technical Sciences, Associate Professor of the Department,

127994, Moscow, Obraztsova str., 9.

Researcher ID: P-8127-2017; Scopus Author ID: 57201922860; Web of Science Researcher ID: AAE-1758-2019. 

https://orcid.org/0000-0002-1983-3454КовалевА. А.KovalevA. A.

Ковалев Андрей Александрович, доктор технических наук, главный научный сотрудник лаборатории биоэнергетических технологий, 

109428, г. Москва, 1-й Институтский проезд, 5.

Researcher ID: F-7045-2017; Scopus Author ID: 57205285134. https://www.researchgate.net/profile/ Andrey-Kovalev-8;

Phone:+79263477955

Kovalev Andrey Alexandrovich, Senior Researcher of the Laboratory of Bioenergy and Supercritical Technologies, Candidate of Technical Sciences,

109428, Moscow, 1-y Institutskiy proezd, 5.

Researcher ID: F-7045-2017; Scopus Author ID: 57205285134. https://www.researchgate.net/profile/Andrey-Kovalev-8.

kovalev_ana@mail.ruФедеральное государственное бюджетное научное учреждение «Федеральный научный агроинженерный центр ВИМ»РоссияFederal Scientific Agroengineering Center VIMRussian FederationРоссийский университет транспортаРоссияRussian University of TransportRussian Federation202523012026011107124Copyright © Международный издательский дом научной периодики "Спейс, 20262026Международный издательский дом научной периодики "СпейсМеждународный издательский дом научной периодики "Спейсhttps://www.isjaee.com/jour/about/submissions#copyrightNoticehttps://www.isjaee.com/jour/article/view/2730

Производство и накопление пищевых отходов ежегодно растёт, представляя угрозу человечеству и окружающей среде. При этом пищевые отходы являются потенциальным возобновляемым источником для получения зеленого водорода путем их темновой ферментации (ТФ). Последние исследования по интенсификации ТФ показали высокий потенциал процесса, сравнимый с электролизом по эффективности. Однако, несмотря на эффективность процесса ТФ, одним из препятствий для его внедрения является наличие в водородсодержащем биогазе значительного (до 94%) содержания углекислого газа. Таким образом, для дальнейшего использования биоводорода требуется его очистка от углекислого газа. В статье показано, что для очистки водородсодержащего биогаза наиболее приемлемо использование химического поглотителя, однако данный способ необходимо улучшить за счет применения принципов зеленой химии с возможностью дальнейшего использования улучшенного способа очистки в рамках циркулярной экономики. Целью данного исследования являлась разработка концепции электрохимического кондиционирования биоводорода, получаемого в процессе ТФ с использованием принципов циркулярной экономики и зеленой химии. Концепция предполагает очистку биоводорода при уменьшении выбросов углекислого газа в атмосферу на основе использования промежуточного носителя СО2 для последующей его утилизации в фотобиореакторе. На основе химизма процесса разработан материальный баланс процесса. Для экспериментального подтверждения возможности кондиционирования биогаза в соответствии с представленной концепцией разработана экспериментальная установка. В среднем степень удаления СО2 составила 68% при содержании биоводорода после электрохимического кондиционирования 84,9%. Полученные данные говорят о возможности использования разработанной системы для очистки биоводорода, полученного в процессе темновой ферментации, однако требуется модернизация и оптимизация отдельных элементов разработанной системы, что планируется в дальнейших исследованиях.

The production and accumulation of food waste is growing annually, posing a threat to humanity and the environment. Food waste is also a potential renewable source for producing green hydrogen through dark fermentation (DF). Recent studies on DF intensification have demonstrated the high potential of the process, comparable in efficiency to electrolysis. However, despite the efficiency of the DF process, one of the obstacles to its implementation is the significant (up to 94%) carbon dioxide (CO2) content in hydrogen-containing biogas. Therefore, for further use of biohydrogen, it must be purified from CO2. This article demonstrates that the use of a chemical adsorbent is most suitable for purifying hydrogen-containing biogas. However, this method needs to be improved through the application of green chemistry principles, with the possibility of further use of the improved purification method within the framework of a circular economy. The objective of this study was to develop a concept for the electrochemical conditioning of biohydrogen obtained through DF using the principles of a circular economy and green chemistry. The concept involves purifying biohydrogen while reducing CO2 emissions into the atmosphere using an intermediate carrier of carbon dioxide for subsequent utilization in a photobioreactor. A material balance was developed based on the process chemistry. A pilot plant was designed to experimentally validate the feasibility of biogas conditioning according to the presented concept. The average CO2 removal rate was 68%, with a biohydrogen content of 84.9% after electrochemical conditioning. The obtained data indicate the feasibility of using the developed system for purifying biohydrogen obtained during dark fermentation. However, modernization and optimization of individual system components is required, which is planned for future research.

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The authors declare that there are no conflicts of interest present.