alternativeАльтернативная энергетика и экология (ISJAEE)Alternative Energy and Ecology (ISJAEE)1608-8298Международный издательский дом научной периодики "Спейс10.15518/isjaee.2016.01-02.004alternative-303Research ArticleКОНСТРУКЦИОННЫЕ МАТЕРИАЛЫSTRUCTURAL MATERIALSАНАЛИЗ ЗАВИСИМОСТИ КРАТНОСТИ КОВАЛЕНТНЫХ СВЯЗЕЙ ОТ КРИСТАЛЛИЧЕСКОЙ СТРУКТУРЫ НАНОРАЗМЕРНЫХ ФАЗ АЛЛОТРОПНОГО УГЛЕРОДА ДЛЯ ЧИСТЫХ ИСТОЧНИКОВ ЭНЕРГИИ И ДРУГИХ ПРИМЕНЕНИЙANALYSIS OF COVALENT BONDS MULTIPLICITY DEPENDENCE ON CRYSTAL STRUCTURES OF NANO-SCALE PHASES OF ALLOTROPIC CARBON, RELEVANCE TO THE CLEAN ENERGY AND SOME OTHER APPLICATIONSФилипповаВ. П.FilippovaV. P.

 

канд. физ.-мат. наук, вед. науч. сотр. ЦНИИчермет им. И.П. Бардина

Ph.D., Leading scientist

varia.filippova@yandex.ruНечаевЮ. С.NechaevYu. S.

д-р физ.-мат наук, профессор, главный научный сотрудник 

professor, D.Sc., Chief researcher

yuri1939@inbox.ruЦНИИчермет им. И.П. БардинаРоссияI.P.Bardin Central Research Institute for Ferrous Metallurgy 23/9-2 Radio str., Moscow, 105005 RussiaRussian Federation20162704201601-24349Copyright © Международный издательский дом научной периодики "Спейс, 20162016Международный издательский дом научной периодики "СпейсМеждународный издательский дом научной периодики "Спейсhttps://www.isjaee.com/jour/about/submissions#copyrightNoticehttps://www.isjaee.com/jour/article/view/303

The approach based on the atomic radial distribution functions (RDF) theoretical building for volume, surface, and linear atomic structures was developed, accounting the escape depth of the analyzed signal, for interpretation of electron energy loses fine structure spectroscopy (EELFS) data. Basing on the made experiments and the theoretical investigations, the covalent bonds multiplicity values were determined for two carbine modifications formed on the different metal substrates with the different methods.

The approach based on the atomic radial distribution functions (RDF) theoretical building for volume, surface, and linear atomic structures was developed, accounting the escape depth of the analyzed signal, for interpretation of electron energy loses fine structure spectroscopy (EELFS) data. Basing on the made experiments and the theoretical investigations, the covalent bonds multiplicity values were determined for two carbine modifications formed on the different metal substrates with the different methods.

carboncarbinecrystal structurecovalent bondselectron energy loses spectroscopyradial distribution functionscarboncarbinecrystal structurecovalent bondselectron energy loses spectroscopyradial distribution functionsReferencesKovalev A.I., Mishina V.P. (Filippova V.P.), Stsherbedinsky G.V., Wainstein D.L. EELFS method for investigation of equilibrium segregations on surfaces in steels and alloys. Vacuum, 1990, vol. 41, no. 7–9, pp. 1794–1795.Kovalev A.I., Mishina V.P. (Filippova V.P.), Stsherbedinsky G.V., Wainstein D.L. EELFS method for investigation of equilibrium segregations on surfaces in steels and alloys. Vacuum, 1990, vol. 41, no. 7–9, pp. 1794–1795.Wainstein D.L., Kovalev A.I. Fine determination of interatomic distances on surface using extended energy-loss fine structure (EELFS) data: peculiarities of the technique. SurFace and InterFace Analysis, 2002, vol. 34, pp. 230–233.Wainstein D.L., Kovalev A.I. Fine determination of interatomic distances on surface using extended energy-loss fine structure (EELFS) data: peculiarities of the technique. SurFace and InterFace Analysis, 2002, vol. 34, pp. 230–233.Glatter O., Kratky O. Small-Angle X-ray Scatterinbg. Academic Press Inc. (London) Ltd, 1982, 515 p.Glatter O., Kratky O. Small-Angle X-ray Scatterinbg. Academic Press Inc. (London) Ltd, 1982, 515 p.Wainstein B.K. Diffraction of X-rays on molecule chains. Publishing House the Academy of Science of the USSR (Moscow), 1963, 372 pp. (in Russ.).Wainstein B.K. Diffraction of X-rays on molecule chains. Publishing House the Academy of Science of the USSR (Moscow), 1963, 372 pp. (in Russ.).Svergun D.I., Feygin L.A. X-ray and neutron Small-Angle Scattering. Nauka Publ. (Moscow), 1986, 279 p. (in Russ.)Svergun D.I., Feygin L.A. X-ray and neutron Small-Angle Scattering. Nauka Publ. (Moscow), 1986, 279 p. (in Russ.)Emsley J. The Elements. Clarendon Press (Oxford), 1991, 256 p. (ISBN 0-19-855568-7).Emsley J. The Elements. Clarendon Press (Oxford), 1991, 256 p. (ISBN 0-19-855568-7).Penkala T. Progress in crystal chemistry. Publishing House “Chemistry” (Leningrad, USSR), 1974, 496 p. (in Russian translated from Polish, 1972).Penkala T. Progress in crystal chemistry. Publishing House “Chemistry” (Leningrad, USSR), 1974, 496 p. (in Russian translated from Polish, 1972).Pearson W.B. The Crystal Chemistry and Physics of Metals and Alloys. Willey-Iterscience (New York), 1972, vol. 1, 419 p.; vol. 2, 471p.Pearson W.B. The Crystal Chemistry and Physics of Metals and Alloys. Willey-Iterscience (New York), 1972, vol. 1, 419 p.; vol. 2, 471p.Eletskiy A.V., Smirnov B.M. Fullerenes and Carbon Structures. Physics-Uspehi, 1995, vol. 165, no. 9, pp. 977–1009 (in Russ.)Eletskiy A.V., Smirnov B.M. Fullerenes and Carbon Structures. Physics-Uspehi, 1995, vol. 165, no. 9, pp. 977–1009 (in Russ.)Sladkov A.M., Kudriavtcev Yu.P. Diamond, graphite, carbine – allotropic forms of carbon. Priroda, 1969, no. 5, pp. 37–44 (in Russ., ISBN: 978-5-458-66294-9).Sladkov A.M., Kudriavtcev Yu.P. Diamond, graphite, carbine – allotropic forms of carbon. Priroda, 1969, no. 5, pp. 37–44 (in Russ., ISBN: 978-5-458-66294-9).Nechaev Yu.S. and T. Nejat Veziroglu. Thermodynamic aspects of the stability of the graphene/graphane/hydrogen systems, relevance to the hydrogen on-board storage problem. Advances in Materials Physics and Chemistry, 2013, vol. 3, pp. 255–280.Nechaev Yu.S. and T. Nejat Veziroglu. Thermodynamic aspects of the stability of the graphene/graphane/hydrogen systems, relevance to the hydrogen on-board storage problem. Advances in Materials Physics and Chemistry, 2013, vol. 3, pp. 255–280.Gijzeman O.L.J. Surface composition of binary metal alloys; Applicability of bulk parameters to surfaces. SurFace Sci., 1985, vol. 150, no. 1, pp.1–13.Gijzeman O.L.J. Surface composition of binary metal alloys; Applicability of bulk parameters to surfaces. SurFace Sci., 1985, vol. 150, no. 1, pp.1–13.Seach M.P., Briggs D. Practical Surface Analysis de Auger and X-Ray Phitoelectron spectroscopy: Edited by D. Briggs and M.P. Seach. John Wiley & Sons Ltd (London, New-York), 1983, 800 p.Seach M.P., Briggs D. Practical Surface Analysis de Auger and X-Ray Phitoelectron spectroscopy: Edited by D. Briggs and M.P. Seach. John Wiley & Sons Ltd (London, New-York), 1983, 800 p.

The authors declare that there are no conflicts of interest present.