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Альтернативная энергетика и экология (ISJAEE)

Alternative Energy and Ecology (ISJAEE)

1608-8298

Международный издательский дом научной периодики "Спейс

10.15518/isjaee.2016.09-10.025-042

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Research Article

КОНСТРУКЦИОННЫЕ МАТЕРИАЛЫ

STRUCTURAL MATERIALS

КОМПОЗИТ ГУМИНОВОЙ КИСЛОТЫ И ОКСИДА ГРАФЕНА: РЕЗУЛЬТАТЫ ВЫСОКОТЕМПЕРАТУРНОЙ ОБРАБОТКИ

COMPOSITE OF GRAPHENE OXIDE AND HUMIC ACIDS: RESULTS OF HIGH-TEMPERATURE TREATMENT

Баскаков

С. А.

Baskakov

S. A.

д. 1, пр-т Академика Семёнова, Черноголовка, Московская область, 142432

Сведения об авторе: канд. хим. наук, старший научный сотрудник Института проблем химической физики РАН.

Образование: Ивановский государственный университет, биолого- химический факультет, химик.

Область научных интересов: углеродные наноматериалы; композиционные материалы на основе графена; суперконденсаторы.

Публикации: более 30.

1 Academician Semenov ave., Chernogolovka, Moscow Region, 142432

Information about the author: Ph.D. (chemistry), Senior Research Scientist of Institute of Problems of Chemical Physics Russian Academy of Science.

Education: Ivanovo State University, Faculty of Biology and Chemistry, chemist.

Research area: carbon nanomaterials; composite materials based on grapheme; supercapacitors.

Publications: more than 30.

sabaskakov@gmail.com

Баскакова

Ю. В.

Baskakova

Y. V.

д. 1, пр-т Академика Семёнова, Черноголовка, Московская область, 142432

1 Academician Semenov ave., Chernogolovka, Moscow Region, 142432

Мартыненко

В. М.

Martynenko

V. M.

д. 1, пр-т Академика Семёнова, Черноголовка, Московская область, 142432

1 Academician Semenov ave., Chernogolovka, Moscow Region, 142432

Лобач

А. С.

Lobach

A. S.

д. 1, пр-т Академика Семёнова, Черноголовка, Московская область, 142432

Сведения об авторе: канд. хим. наук, старший научный сотрудник Института проблем химической физики РАН.

Образование: Московский химико-технологический институт им. Д.И. Менделеева, инженер-технолог.

Область научных интересов: химия углеродных наноматериалов; композиционные наноматериалы.

Публикации: более 100; индекс Хирша 18.

1 Academician Semenov ave., Chernogolovka, Moscow Region, 142432

Information about the author: Ph.D. (chemistry), Senior Research Scientist of Institute of Problems of Chemical Physics Russian Academy of Science.

Education: Moscow D. Mendeleev Institute of Chemical Technology, engineer-technologist.

Research area: chemistry of carbon nanomaterials; composite nanomaterials.

Publications: more than 100; h-index is 18.

Васильев

С. А.

Vasiliev

S. A.

д. 1, пр-т Академика Семёнова, Черноголовка, Московская область, 142432

1 Academician Semenov ave., Chernogolovka, Moscow Region, 142432

Шульга

Ю. М.

Shulga

Y. M.

д. 1, пр-т Академика Семёнова, Черноголовка, Московская область, 142432;

д. 4, Ленинский пр., Москва, 119049

1 Academician Semenov ave., Chernogolovka, Moscow Region, 142432;

4 Leninsky ave., Moscow, 119049

Арбузов

А. А.

Arbuzov

A. A.

д. 1, пр-т Академика Семёнова, Черноголовка, Московская область, 142432

Сведения об авторе: канд. хим. наук, научный сотрудник Института проблем химической физики РАН.

Образование: Ивановский государственный университет, биолого-химический факультет, химик.

Область научных интересов: химия углеродных наноструктур; углеродное материаловедение; композиционные материалы.

Публикации: более 15.

1 Academician Semenov ave., Chernogolovka, Moscow Region, 142432

Information about the author: Ph.D. (chemistry), Research Scientist of Institute of Problems of Chemical Physics Russian Academy of Science.

Education: Ivanovo State University, Faculty of Biology and Chemistry, chemist.

Research area: chemistry of carbon nanostructures; carbon material science; composite material.

Publications: more than 15.

Володин

А. А.

Volodin

A. A.

д. 1, пр-т Академика Семёнова, Черноголовка, Московская область, 142432

Сведения об авторе: канд. хим. наук, старший научный сотрудник Института проблем химической физики РАН.

Образование: Ивановский государственный университет, химик (2002).

Область научных интересов: углеродные наноматериалы; нанотрубки; графен; каталитический пиролиз; композиты на основе графена.

Публикации: более 20.

1 Academician Semenov ave., Chernogolovka, Moscow Region, 142432

Information about the author: Ph.D. (chemistry), Senior Researcher, Institute of Problems of Chemical Physics of the RAS.

Education: Ivanovo State University, chemist, 2002.

Research area: carbon nanomaterials; nanotubes; grapheme; catalytic pyrolysis; composites based on graphene.

Publications: more than 20.

Вольфкович

Ю. М.

Volfkovich

Y. M.

д. 31, Ленинский пр., Москва 119071

31 Leninsky ave., Moscow, 119071

Сосенкин

В. Е.

Sosenkin

V. E.

д. 31, Ленинский пр., Москва 119071

31 Leninsky ave., Moscow, 119071

Шульга

Н. Ю.

Shulga

N. Y.

д. 4, Ленинский пр., Москва, 119049

Сведения об авторе: аспирант НИТУ «МИСиС».

Образование: Национальный исследовательский технологический университет «МИСиС», инженер по специальности «Наноматериалы».

Область научных интересов: углеродные наноматериалы; рентгеновская фотоэлектронная спектроскопия; суперконденсаторы.

Публикации: более 15.

4 Leninsky ave., Moscow, 119049

Information about the author: postgraduate of NUST MISIS.

Education: National University of Science and Technology, engineer.

Research area: carbon nanomaterials; x-ray photoelectron spectroscopy; supercapacitors.

Publications: more than 15.

Пархоменко

Ю. Н.

Parkhomenko

Y. N.

д. 4, Ленинский пр., Москва, 119049

Сведения об авторе: д-р физ.-мат. наук, профессор, заведующий кафедрой, директор центра коллективного пользования «Материаловедение и металлургия».

Образование: Национальный исследовательский технологический университет «МИСиС» по специальности «Физика полупроводников и диэлектриков».

Область научных интересов: физика полупроводников и диэлектриков; спектральные методы анализа.

Публикации: более 100.

4 Leninsky ave., Moscow, 119049

Information about the author: D.Sc., professor, the head of department at the MISIS, director of the center of collective use “Material science and metallurgy”.

Education: National University of Science and Technology «MISIS»; in physics of semiconductor and dielectric materials.

Research area: physics of semiconductors and dielectric; spectroscopic methods.

Publications: more than 100.

Мищенко

А.

Michtchenko

Мехико, C.P. 07738

Сведения об авторе: канд. физ.-мат. наук, доцент Мексиканского технологического университета, г. Мехико.

Образование: Московский физико-технический институт, инженер-физик.

Область научных интересов: физика лазеров; углеродные наноматериалы.

Публикации: более 50.

Ed. 5, 3-r piso, Mexico D.F., C.P. 07738

Information about the author: PhD (physics), Associate Professor at the University of Technology of Mexico, Mexico City.

Education: Moscow Institute of Physics and Technology, engineerphysicist.

Research area: physics of lasers; carbon nanomaterials.

Publications: more than 50.

Кумар

Йогеш

Kumar

Yogesh

Дели-110027

Сведения об авторе: работает в ARSD, Университет Дели; работал по программе постдоков в Евросоюзе, в Польше.

Образование: Университет Дели, кафедра физики и астрофизики.

Область научных интересов: углеродные материалы; полимерные электролиты; суперконденсаторы и аккумуляторы.

Публикации: более 30.

Delhi-110027

Information about the author: Dr. Yogesh Kumar is currently working in ARSD College, University of Delhi; he worked as postdoctoral fellow in a European Union project in Poland.

Education: University of Delhi, department of Physics and Astrophysics.

Research area: carbon materials; polymer electrolytes; supercapacitor and batteries.

Publications: more than 30.

Гусев

А. Л.

Gusev

A. L.

а/я 687, г.Саров, Нижегородская обл., 607183

Post Box Office 687, Sarov, Nizhny Novgorod region, 607183

Институт проблем химической физики РАНРоссияInstitute of Problems of Chemical Physics, Russian Academy of SciencesRussian Federation

Институт проблем химической физики РАН; Национальный университет науки и техники МИСиСРоссияInstitute of Problems of Chemical Physics, Russian Academy of Sciences; National University of Science and Technology MISISRussian Federation

Институт физической химии и электрохимии России РАНРоссияA.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of SciencesRussian Federation

Национальный университет науки и техники МИСиСРоссияNational University of Science and Technology MISISRussian Federation

Национальный политехнический институтМексикаInstituto Politecnico Nacional, SEPI-ESIME-ZacatencoMexico

Департамент физики, Шиваджи колледж, университет ДелиИндияDepartment of Physics, Shivaji College, University of DelhiIndia

ООО Научно-технический центр «ТАТА»РоссияScientific Technical Centre «TATA» LimitedRussian Federation

2016

14062016

09-102542

2016

Международный издательский дом научной периодики "Спейс

https://www.isjaee.com/jour/about/submissions#copyrightNotice

https://www.isjaee.com/jour/article/view/348

Гуминовые кислоты (ГК) и углеродный наноматериал, полученный путем нагрева ГК при 900 °С в инертной атмосфере (УНГК), были изучены методами твердотельного ядерного магнитного резонанса (ЯМР), дифференциальной сканирующей калориметрии (ДСК), термогравиметрического анализа (ТГА), спектроскопии комбинационного рассеяния света и стандартной контактной порометрии (СКП). Масс-спектрометрия была также использована для анализа газов, выделяющихся при нагревании образцов. Были также получены композит ГК с оксидом графена (ГК-ОГ) и углеродный наноматериал, образующийся при карбонизации композита (ГК-ОГ) в инертной атмосфере при температуре 900 °С. Установлено, что при карбонизации образуются небольшие агломераты углерода с четко определенными краями, тогда как при карбонизации композита при тех же условиях образуются крупные агрегаты. Значения удельной поверхности для УНГК и УН (ГК-ОГ) составили 173 и 474 м2 /г соответственно. Удельная поверхность, соответствующая площади всех пор (Spore), равна только 3 м2 /г в случае УНГК, в случае УН (ГК-ОГ) Spore = 237 м2 /г.

Humic acids (HA) and HA derived carbon (HADC), obtained by heating HA at 900 oC in inert atmosphere, has been studied by solid-state nuclear magnetic resonance (NMR), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), Raman spectroscopy and the method of standard contact porosimetry (SCP). Mass spectrometry was also used for analysis of gases released upon heating of the samples. The composite of HA with graphene oxide (HA+GO) derived carbon has been prepared using carbonization of HA+GO in an inert atmosphere at 900 °C. Small agglomerates of carbon with sharply defined edges have been obtained because of carbonization of HA, and the composite of HA+GO forms only large aggregates at the same condition. The values of specific surface area of HADC and (HA+GO)DC are 173 and 474 m2 /g, respectively. The value of specific surface correspond to the area of all pores (Spore) is equal to only 3 m2 /g in the case of HADC. In the case of the (HA+GO)DC, Spore is equal to 237 m2 /g.

гуминовые кислотыоксид графенакомпозиттермическая обработкапористость

humic acidsgraphene oxidecompositeheat treatmentporosity

Presidium of the Russian Academy of Sciences, RF Ministry of Education and Science, Joint Research Center “Material Science and Metallurgy” at the National University of Science and Technology “MISIS”, Dr. Shashi Nijhawan of the Shivaji College, University of Delhi

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The authors declare that there are no conflicts of interest present.