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<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="ru"><front><journal-meta><journal-id journal-id-type="publisher-id">alternative</journal-id><journal-title-group><journal-title xml:lang="ru">Альтернативная энергетика и экология (ISJAEE)</journal-title><trans-title-group xml:lang="en"><trans-title>Alternative Energy and Ecology (ISJAEE)</trans-title></trans-title-group></journal-title-group><issn pub-type="ppub">1608-8298</issn><publisher><publisher-name>Международный издательский дом научной периодики "Спейс</publisher-name></publisher></journal-meta><article-meta><article-id custom-type="elpub" pub-id-type="custom">alternative-397</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>ЛИТИЙ-ИОННЫЕ ИСТОЧНИКИ ТОКА И СУПЕРКОНДЕНСАТОРЫ</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="en"><subject>LITHIUM-ION CURRENT SOURCES AND SUPERCAPACITOR</subject></subj-group></article-categories><title-group><article-title>КОМПОЗИТЫ НА ОСНОВЕ ВОССТАНОВЛЕННОГО ОКСИДА ГРАФЕНА И ГИДРОКСИДА НИКЕЛЯ КАК ПЕРСПЕКТИВНЫЕ МАТЕРИАЛЫ ДЛЯ ГИБРИДНЫХ СУПЕРКОНДЕНСАТОРОВ</article-title><trans-title-group xml:lang="en"><trans-title>COMPOSITES BASED ON REDUCED GRAPHENE OXIDE AND NICKEL HYDROXIDE AS A PROMISING MATERIAL FOR HYBRID SUPERCAPACITORS</trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Баскаков</surname><given-names>С. А.</given-names></name><name name-style="western" xml:lang="en"><surname>Baskakov</surname><given-names>S. A.</given-names></name></name-alternatives><email xlink:type="simple">baskakov@icp.ac.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Баскакова</surname><given-names>Ю. В.</given-names></name><name name-style="western" xml:lang="en"><surname>Baskakova</surname><given-names>Y. V.</given-names></name></name-alternatives><email xlink:type="simple">noemail@neicon.ru</email><xref ref-type="aff" rid="aff-2"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Золотаренко</surname><given-names>А. Д.</given-names></name><name name-style="western" xml:lang="en"><surname>Zolotarenko</surname><given-names>A. D.</given-names></name></name-alternatives><email xlink:type="simple">noemail@neicon.ru</email><xref ref-type="aff" rid="aff-3"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Шульга</surname><given-names>Ю. М.</given-names></name><name name-style="western" xml:lang="en"><surname>Shulga</surname><given-names>Y. M.</given-names></name></name-alternatives><email xlink:type="simple">noemail@neicon.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Ефимов</surname><given-names>О. Н.</given-names></name><name name-style="western" xml:lang="en"><surname>Efimov</surname><given-names>O. N.</given-names></name></name-alternatives><email xlink:type="simple">noemail@neicon.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Гусев</surname><given-names>А. Л.</given-names></name><name name-style="western" xml:lang="en"><surname>Gusev</surname><given-names>A. L.</given-names></name></name-alternatives><email xlink:type="simple">noemail@neicon.ru</email><xref ref-type="aff" rid="aff-4"/></contrib></contrib-group><aff-alternatives id="aff-1"><aff xml:lang="ru"><institution>Федеральное государственное бюджетное учреждение науки Институт проблем химической физики РАН</institution></aff><aff xml:lang="en"><institution>Federal State Budget Scientific Agency Institute of Problems of Chemical Physics RAS</institution></aff></aff-alternatives><aff-alternatives id="aff-2"><aff xml:lang="ru"><institution>Федеральное государственное бюджетное учреждение науки Институт проблем химической физики РАН</institution></aff><aff xml:lang="en"><institution>Institute of Materials Science. IM Frantsevich NAS</institution></aff></aff-alternatives><aff-alternatives id="aff-3"><aff xml:lang="ru"><institution>Институт проблем материаловедения им. И.М. Францевича НАН Украины</institution></aff><aff xml:lang="en"><institution>Federal State Budget Scientific Agency Institute of Problems of Chemical Physics RAS</institution></aff></aff-alternatives><aff-alternatives id="aff-4"><aff xml:lang="ru"><institution>ООО «Научно-технический центр «ТАТА»</institution></aff><aff xml:lang="en"><institution>LLC "Scientific and Technical Center" TATA ""</institution></aff></aff-alternatives><pub-date pub-type="collection"><year>2014</year></pub-date><pub-date pub-type="epub"><day>23</day><month>06</month><year>2016</year></pub-date><issue>2</issue><fpage>146</fpage><lpage>156</lpage><permissions><copyright-statement>Copyright &amp;#x00A9; Международный издательский дом научной периодики "Спейс, 2016</copyright-statement><copyright-year>2016</copyright-year><copyright-holder xml:lang="ru">Международный издательский дом научной периодики "Спейс</copyright-holder><copyright-holder xml:lang="en">Международный издательский дом научной периодики "Спейс</copyright-holder><license xlink:href="https://www.isjaee.com/jour/about/submissions#copyrightNotice" xlink:type="simple"><license-p>https://www.isjaee.com/jour/about/submissions#copyrightNotice</license-p></license></permissions><self-uri xlink:href="https://www.isjaee.com/jour/article/view/397">https://www.isjaee.com/jour/article/view/397</self-uri><abstract><p>На основе восстановленного СВЧ-облучением оксида графена (RGO) и гидроксида никеля (Ni-RGO) были получены композиты переменного состава двумя способами: осаждением Ni(OH)2 на RGO in situ, и смешением суспензий RGO и Ni(OH)2. Установлено, что композиты Ni-RGO обладают высокой удельной емкостью при испытании их в качестве электродов суперконденсаторов в 1М КОН (от 150 до 330 F/g). Показано, что RGO обладает высокой стабильностью при циклировании в режиме заряд-разряд, но низкими показателями емкости (~25 F/g). Чистый Ni(OH)2, наоборот, имеет высокую удельную емкость в пределах 450-500 Ф/г, но недостаточную устойчивость при циклировании. Емкостные показатели и стабильность композитов Ni-RGO при гальваностатических испытаниях занимают промежуточные значения по сравнению с составляющими их компонентами, в зависимости от процентного содержания Ni(OH)2. После первых 100 циклов заряда/разряда видно, что введение RGO усиливает устойчивость электродной массы при циклировании. Таким образом, RGO может служить стабилизирующей добавкой, которая позволит увеличить срок службы и расширить диапазон рабочего тока суперконденсаторов на основе Ni(OH)2.</p></abstract><trans-abstract xml:lang="en"><p>Using microwave irradiation reduced graphene oxide (RGO) and nickel hydroxide as precursors the composites (Ni-RGO) of variable composition were prepared in two ways : by precipitation of Ni(OH)2 on RGO in situ, and mixing the suspensions RGO and Ni(OH)2. It was established that the Ni-RGO composites have a high specific capacity when tested as a super-capacitor electrode in 1M KOH (150 to 330 F/g). It was shown that RGO has high stability during cycling mode of the charge-discharge capacity but a low (~ 25 F/g). Pure Ni(OH)2, on the contrary, has a high specific capacity in the range of 450-500 F/g, but lack the stability during cycling. Capacitive and stability galvanostatic tests of composites Ni-RGO take intermediate values compared with their components, depending on the percentage of Ni(OH)2. The introduction of RGO enhanced the resistance of electrode mass during cycling during the first 100 charge/discharge cycles. Thus, RGO can serve as a stabilizing additive which increase the life and the range of the operating current of super-capacitors based on Ni(OH)2.</p></trans-abstract><kwd-group xml:lang="ru"><kwd>восстановленный оксид графена</kwd><kwd>гидроксид никеля</kwd><kwd>нанокомпозиты</kwd><kwd>суперконденсатор</kwd><kwd>Reduced graphene oxide</kwd><kwd>nickel hydroxide</kwd><kwd>supercapacitor</kwd><kwd>nanocomposites</kwd></kwd-group></article-meta></front><back><ref-list><title>References</title><ref id="cit1"><label>1</label><citation-alternatives><mixed-citation xml:lang="ru">Полякова А.Л., Васильев, Б.М., Купенко И.Н. и др. 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