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Альтернативная энергетика и экология (ISJAEE)

Alternative Energy and Ecology (ISJAEE)

1608-8298

Международный издательский дом научной периодики "Спейс

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Research Article

ВОДОРОДНАЯ ЭКОНОМИКА

HYDROGEN ECONOMY

О некоторых теоретических и экспериментальных (STM, STS, HREELS/LEED, PES, ARPS, Raman spectroscopy) данных по сорбции водорода графеновыми наноматериалами в связи с проблемами чистой энергетики

On some theoretical and experimental (STM, STS, HREELS/LEED, PES, ARPS & Raman spectroscopy) data on hydrogen sorption with graphene-layers nanomaterials, relevance to the clean energy applications

Нечаев

Ю. С.

Nechaev

Yu. S.

Yuri1939@inbox.ru

ЦНИИчермет им. И.П. Бардина; Институт металловедения и физики металлов им. Г.В. КурдюмоваРоссияBardin Institute for Ferrous Metallurgy; Kurdumov Institute of Metals Science and PhysicsRussian Federation

2014

23062016

173356

2016

Международный издательский дом научной периодики "Спейс

https://www.isjaee.com/jour/about/submissions#copyrightNotice

https://www.isjaee.com/jour/article/view/591

Представлены результаты термодинамического анализа ряда теоретических и экспериментальных (TDS, STM, STS, HREELS/LEED, PES, ARPS, Raman spectroscopy и др.) данных по «обратимому» гидрированию и дегидрированию некоторых графеновых (моно- и полислойных) наноструктур. В рамках приближения формальной кинетики для реакций первого порядка определены термодинамические характеристики процессов сорбции водорода этими наноструктурами (константы скорости, энергии активации, предэкспоненциальные факторы констант скорости). При интерпретации полученных термодинамических характеристик использованы некоторые модели и характеристики химической сорбции водорода на базальной и краевых поверхностях графита с целью раскрытия атомных механизмов гидрирования и дегидрированию различных графеновых (моно- и полислойных) наноструктур. Рассмотрена кинетика как сорбционных процессов, в которых не лимитирует диффузионный массоперенос водорода в сорбенте, так и процессов с лимитирующей диффузионной стадией. Рассматриваются также некоторые «открытые вопросы» и перспективы решения актуальной проблемы эффективного хранения водорода «на борту» экоавтомобиля и ряда других проблем чистой энергетики на основе использования графитовых нановолокон.

Herein, results of thermodynamic analysis of some theoretical and experimental (TDS, STM, STS, HREELS/LEED, PES, ARPS, Raman spectroscopy and others) data on “reversible” hydrogenation and dehydrogenation of some graphene-layer-nanostructures are presented. In the framework of the formal kinetics approximation of the first order rate reaction, some thermodynamic quantities for the reaction of hydrogen sorption (the reaction rate constant, the reaction activation energy, the per-exponential factor of the reaction rate constant) have been determined. Some models and characteristics of hydrogen chemisorption on graphite (on the basal and edge planes) have been used for interpretation of the obtained quantities, with the aim of revealing the atomic mechanisms of hydrogenation and dehydrogenation of different graphene-layer-systems. The cases of both a non-diffusion rate limiting kinetics, and a diffusion rate limiting kinetics are considered. Some open questions and perspectives of solving of the actual problem of the effective hydrogen on-board storage and other clean energy applications, with using the graphite nanofibers, are also considered.

эпитаксиальные и мембранные графеныслоистые графеновые системыгидрирование-дегидрированиетермодинамические характеристикиатомные механизмыпроблема эффективного хранения водорода «на борту» экоавтомобиляepitaxial and membrane graphenesother graphene-layer-systemshydrogenation-dehydrogenationthermodynamic characteristicsatomic mechanismsthe hydrogen on-board efficient storage problem

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The authors declare that there are no conflicts of interest present.