alternativeАльтернативная энергетика и экология (ISJAEE)Alternative Energy and Ecology (ISJAEE)1608-8298Международный издательский дом научной периодики "Спейс10.15518/isjaee.2016.13-14.013-030alternative-766Research ArticleСтатьиДИЗАЙН ВЫСОКОЭФФЕКТИВНОГО КАТАЛИЗАТОРА ДЛЯ КАТАЛИТИЧЕСКОГО МЕМБРАННОГО РЕАКТОРА ДЛЯ ПРОИЗВОДСТВА ВОДОРОДАDESIGN OF HIGHLY EFFICIENT CATALYST FOR CATALYTIC MEMBRANE REACTOR OF HYDROGEN PRODUCTIONИсмагиловИ. З.IsmagilovI. Z.

канд. хим. наук, научный сотрудник Института катализа им. Г.К. Борескова СО РАН

Ph.D. (chemistry), Researcher of Boreskov Institute of Catalysis

zinfer1@mail.ruМатусЕ. В.MatusE. V.

канд. хим. наук, научный сотрудник Института катализа им. Г.К. Борескова СО РАН

Ph.D. (chemistry), Researcher of Boreskov Institute of Catalysis

КузнецовВ. В.KuznetsovV. V.

Ph.D. (chemistry), Researcher of Boreskov Institute of Catalysis

КерженцевМ. А.KerzhentsevM. A.

канд. хим. наук, старший научный сотрудник Института катализа им. Г.К. Борескова СО РАН

Ph.D. (chemistry), Senior Researcher of Boreskov Institute of Catalysis

MotaN.MotaN.

Ph.D. (chemistry), Senior Researcher of Boreskov Institute of Catalysis

NavarroR. M.NavarroR. M.FierroJ.-L. G.FierroJ.-L. G.KoekkoekA.-J. J.KoekkoekA.-J. J.GerritsenG.GerritsenG.AbbenhuisH.-C. L.AbbenhuisH.-C. L.ЗахаровЮ. А.ZaharovYu. A.

д-р хим. наук, профессор, чл.-корр. РАН, зав. кафедры КемГУ, зав. лабораторией Института углехимии и химического материаловедения Федерального исследовательского центра угля и углехимии CО РАН

 

 

D.Sc. (chemistry), Professor, Corresponding Member of RAS, Head of Chair of KemSU, Head of Laboratory of Institute of Coal Chemistry and Material Science of Federal Research Centre of Coal and Coal Chemistry SB RAS

 

 

zinfer1@mail.ruИсмагиловЗ. Р.IsmagilovZ. R.

д-р хим. наук, профессор, чл.-корр. РАН, Директор Института углехимии и химического материаловедения Федерального исследовательского ц ентра угля и углехимии CО РАН

 

D.Sc. (chemistry), Professor, Corresponding Member of RAS, Director of Institute of Coal Chemistry and Material Science of Federal Research Centre of Coal and Coal Chemistry SB RAS

Институт катализа им. Г.К. Борескова СО РАН д. 5, пр. Акад. Лаврентьева, Новосибирск, 630090, Россия тeл.: +7(383)330-62-19; факс: +7(383)330-62-19РоссияBoreskov Institute of Catalysis SB RAS 5 Akademik Lavrentiev, Novosibirsk, 630090, Russia tel.: +7(383)330-62-19; fax: +7(383)330-62-19Russian FederationInstituto de Catálisis y Petroleoquímica, CSIC д. 2, ул. М арии Кюри, М адрид, 28049, ИспанияРоссияInstituto de Catálisis y Petroleoquímica, CSIC 2 Marie Curie, Madrid, 28049, SpainRussian FederationHybrid Catalysis B.V д. 2, ул. Den Dolech, Эйндховен, 5612, AZ, НидерландыРоссияHybrid Catalysis B.V. Den Dolech 2, Eindhoven 5612, AZ, the NetherlandsRussian FederationИнститут углехимии и химического материаловедения Федерального исследовательского центра угля и углехимии СО РАН д. 18, пр. Советский, Кемерово, 650000, Россия тeл.: +7(3842)36-55-86; факс: +7(3842)36-55-86 Кемеровский государственный университет д. 6, ул. Красная, Кемерово, 650043, Россия тел.: +7(3842)58-05-91РоссияInstitute of Coal Chemistry and Material Science of Federal Research Centre of Coal and Coal Chemistry SB RAS 18 Sovetskiy ave., Kemerovo, 650000, Russia tel.: +7(3842)36-55-86; fax: +7(3842)36-55-86 Kemerovo State University 6 Krasnaya str., Kemerovo, 650043, Russia tel.: +7 (3842) 58-05-91Russian FederationИнститут катализа им. Г.К. Борескова СО РАН д. 5, пр. Акад. Лаврентьева, Новосибирск, 630090, Россия тeл.: +7(383)330-62-19; факс: +7(383)330-62-19 Институт углехимии и химического материаловедения Федерального исследовательского центра угля и углехимии СО РАН д. 18, пр. Советский, Кемерово, 650000, Россия тeл.: +7(3842)36-55-86; факс: +7(3842)36-55-86РоссияBoreskov Institute of Catalysis SB RAS 5 Akademik Lavrentiev, Novosibirsk, 630090, Russia tel.: +7(383)330-62-19; fax: +7(383)330-62-19 Institute of Coal Chemistry and Material Science of Federal Research Centre of Coal and Coal Chemistry SB RAS 18 Sovetskiy ave., Kemerovo, 650000, Russia tel.: +7(3842)36-55-86; fax: +7(3842)36-55-86Russian Federation201616082016013-141330Copyright © Международный издательский дом научной периодики "Спейс, 20162016Международный издательский дом научной периодики "СпейсМеждународный издательский дом научной периодики "Спейсhttps://www.isjaee.com/jour/about/submissions#copyrightNoticehttps://www.isjaee.com/jour/article/view/766

В работе представлены данные по разработке каталитических материалов с улучшенными характеристиками для каталитическо го мембранного реактора (КМР) авто термического риформинга метана (АТР СH4), полученные в рамках международного проекта DEMCAMER (ДИПКАМЕР) – Дизайн и производство каталитических мембранных реакторов путем разработки новых наноструктурированных каталитических и селективных мембранных материалов. Синтезированы Ni и Ni-Me (Me = Pt, Pd, Re, Mo, Sn) катализаторы на основе различных носителей (La2O3, Ce1-xZrxOy, Ce1-xGdxOy, CeZrO2/Al2O3, La2O3-CeZrO2/Al2O3) и исследована их активность в реакции АТР СH4. Показана возможность целенаправленного регулирования состава Ni-содержащей фазы (NiO, La-Ni-O, Al-Ni-O), среднего размер частиц NiO (6 ÷ 50 нм) и окислительно -восстановительных свойств ионов никеля пу тем варьирования состава носителя. Определены оптимальный состав катализатора 10Ni0,5Pd/10CeZrO2/Al2O3, метод его приго товления и условия реакции, обеспечивающие при 850 ºС выход водорода ~60 % и стабильную работу в условиях реакции АТР СH4, что указывает на перспективность его использования для рациональной переработки метана в водородсодержащий газ.

The paper presents data on the development of catalytic materials with improved characteristics for catalytic membrane reactors of autothermal reforming of methane (ATR of CH4) obtained in the frame of the International collaborative project DEMCAMER – Design and Manufacturing of Catalytic Membrane Reactors by developing new nano-architectured catalytic and selective membrane materials. The Ni and Ni-Me (Me = Pt, Pd, Re, Mo, Sn) catalysts were synthesized based on different supports (La2O3, Ce1-xZrxOy, Ce1-xGdxOy, CeZrO2/Al2O3, La2O3-CeZrO2/Al2O3). Their activity was studied in the reaction of autothermal reforming of methane. The purposeful regulation of composition of Ni-containing phase (NiO, La-Ni-O, Al-Ni-O), average particle size of NiO (6-50 nm), and redox properties of Ni cations is realized by variation of support composition. The optimal composition and preparation mode of catalyst 10Ni0.5Pd/10CeZrO2/Al2O3 as well as reaction conditions were established. The catalyst provides at 850 ºС the H2 yield of ~60% and is characterized by stable work in condition of АТР of СH4 that indicates the availability of its application for rational methane conversion to hydrogen-containing gas.

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The authors declare that there are no conflicts of interest present.