alternativeАльтернативная энергетика и экология (ISJAEE)Alternative Energy and Ecology (ISJAEE)1608-8298Международный издательский дом научной периодики "Спейс10.15518/isjaee.2016.15-18.031-053alternative-802Research ArticleI. ВОЗОБНОВЛЯЕМАЯ ЭНЕРГЕТИКА 1. Солнечная энергетикаI. RENEWABLE ENERGY 1. Solar EnergyТОНКИЕ ПЛЕНКИ Cu2ZnSn(S,Se)4 ДЛЯ ИСПОЛЬЗОВАНИЯ В СОЛНЕЧНЫХ ЭЛЕМЕНТАХ ТРЕТЬЕГО ПОКОЛЕНИЯБашкировС. А.BashkirovS. A.

Семен Александрович Башкиров: магистр химических наук, кандидат физико-математических наук, старший научный сотрудник

Simon A. Bashkirov: M.Sc. (chemistry), Ph.D. (physics), a researcher in SPA “Scientific-Practical Materials

priemnaya@physics.byКондротасР.KondrotasR.

Рокас Кондротас: доктор физических наук, научный сотрудник в Группе солнечных материалов и систем в Каталонском институте энергетических исследований

Rokas Kondrodas: D.Sc. (physics), Researcher at Solar Materials and Systems Group of Catalonia Institute for Research Energy

juskenas@ktl.mii.ltГременокВ. Ф.GremenokV. F.

Валерий Феликсович Гременок: доктор физико-математических наук, доцент, заведующий лабораторией физики твердого тела

Valery F. Gremenok: D.Sc. (physics), Assoc. Prof., Head of Laboratory of Solid State Physics

priemnaya@physics.byЮшкенасР. Л.JuskenasR.

Ремигюс Л. Юшкенас: доктор физических наук, профессор, главный научный сотрудник, заведующий отделом структурных исследований материалов

juskenas@ktl.mii.ltТюховИ. И.TyukhovI. I.

Игорь Иванович Тюхов: кандидат технических наук, доцент, заместитель заведующего кафедрой ЮНЕСКО «Возобновляемая энергетика и электрификация сельского хозяйства»

Igor I. Tyukhov: Ph.D. (engineering), Assoc. Prof., Deputy Chair Holder of the UNESCO Chair “Renewable Energy and Rural Electrification”

viesh@dol.ruНаучно-практический центр по материаловедению Национальной академии наук Беларуси, МинскБеларусьResearch Centre of the National Academy of Sciences of Belarus, MinskBelarusНаучно-исследовательский институт «Центр физических и технологических наук», ВильнюсЛитваState Research Institute Center for Physical Sciences and TechnologyLithuaniaВсероссийский научно-исследовательский институт электрификации сельского хозяйства, МоскваРоссияAll-Russian Research Institute for Electrification of Agriculture (VIESH), MoscowRussian Federation201607092016015-183153Copyright © Международный издательский дом научной периодики "Спейс, 20162016Международный издательский дом научной периодики "СпейсМеждународный издательский дом научной периодики "Спейсhttps://www.isjaee.com/jour/about/submissions#copyrightNoticehttps://www.isjaee.com/jour/article/view/802

Проведено обобщение литературных данных о методах получения тонких пленок Cu2ZnSn(S,Se)4 и разработке солнечных элементов на основе этого материала. Проанализированы сведения о фазовых состояниях в системе Cu-Zn-Sn-Se (S) и оптимальном элементном составе Cu2ZnSn(S,Se)4 для использования в фотопреобразователях. Рассмотрены механизмы протекания реакции селенизации металлических прекурсоров Cu-Zn-Sn и методы удаления побочных фаз. Особое внимание уделено вопросам использования электрохимических технологий в процессе получения данного материала.

A generalization of the literature data on the methods for Cu2ZnSn(S,Se)4 thin films deposition and the development of solar cells based on this material is presented. The information on the phase states in the Cu-Zn-Sn-Se (S) system and the optimal elemental composition of Cu2ZnSn(S,Se)4 for use in photovoltaics are analyzed. The reaction mechanisms of the metal Cu-Zn-Sn precursor selenezation process and the methods for the side phases removing are considered. A deep attention is paid to the use of electrochemical technologies in the processes of this material manufacturing.

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The authors declare that there are no conflicts of interest present.