alternativeАльтернативная энергетика и экология (ISJAEE)Alternative Energy and Ecology (ISJAEE)1608-8298Международный издательский дом научной периодики "Спейс10.15518/isjaee.2017.01-03.034-045alternative-936Research ArticleIV. ВОДОРОДНАЯ ЭКОНОМИКА 12. Водородная экономикаIV. HYDROGEN ECONOMY. 12. Hydrogen EconomyВОДОРОДСОДЕРЖАЩИЕ КОМПОЗИТЫ ГИДРИДА МАГНИЯ С ОКСИДАМИ ЛАНТАНОИДОВHYDROGEN CONTAINING COMPOSITES OF MAGNESIUM HYDRIDE WITH LANTHANIDE OXIDESФурсиковП. В.FursikovP. V.

Фурсиков Павел Владимирович - кандидат химических наук, старший научный сотрудник Института проблем химической физики РАН.

Д. 1, пр. Акад. Семенова, г. Черноголовка, Московская обл., 142432,  тел./факс: +7(496) 522-54-01; e-mail: fpv@icp.ac.ru

Pavel Fursikov - Ph.D. (chemistry), Senior Researcher of Institute of Problems of Chemical Physics of RAS.

1 Aсad. Semenov ave., Chernogolovka, 142432, tel./fax: +7(49652)2-54-01; e-mail: fpv@icp.ac.ru; 1 Leninskie Gory, Moscow, 119991, e-mail: adilya_f@mail.ru

fpv@icp.ac.ruФаттаховаА. М.FattakhovaA. M.

Фаттахова Адиля Маратовна - студент факультета фундаментальной физико-химической инженерии МГУ, инженер Института проблем химической физики РАН.

Д. 1, пр. Акад. Семенова, г. Черноголовка, Московская обл., 142432,  тел./факс: +7(496) 522-54-01; e-mail: fpv@icp.ac.ru; Д. 1, Ленинские горы, Москва, 119991, e-mail: adilya_f@mail.ru

Adilya Fattakhova - Student of Faculty of Fundamental Physical and Chemical Engineering of Moscow State University, engineer of Institute of Problems of Chemical Physics of RAS.

1 Aсad. Semenov ave., Chernogolovka, 142432, tel./fax: +7(49652)2-54-01; e-mail: fpv@icp.ac.ru; 1 Leninskie Gory, Moscow, 119991, e-mail: adilya_f@mail.ru

fpv@icp.ac.ruМожжухинС. А.MozhzhukhinS. A.

Можжухин Сергей Александрович - аспирант Ивановского государственного университета, инженер Института проблем химической физики РАН.

Д. 1, пр. Акад. Семенова, г. Черноголовка, Московская обл., 142432,  тел./факс: +7(496) 522-54-01; e-mail: fpv@icp.ac.ru; Д. 39, ул. Ермака, г. Иваново, 153025, e-mail: mozhuhin@icp.ac.ru

Sergey A. Mozhzhukhin - Postgraduate Student of Ivanovo State University, engineer of Institute of Problems of Chemical Physics of RAS.

1 Aсad. Semenov ave., Chernogolovka, 142432, tel./fax: +7(49652)2-54-01; e-mail: fpv@icp.ac.ru; 39 Ermak str., Ivanovo, 153025, tel.: +7(49552)2-16-48, e-mail: mozhuhin@icp.ac.ru

fpv@icp.ac.ruБлиноваЛ. Н.BlinovaL. N.

Блинова Лариса Николаевна - старший  специалист-исследователь ИПХФ РAH.

Д. 1, пр. Акад. Семенова, г. Черноголовка, Московская обл., 142432,  тел./факс: +7(496) 522-54-01; e-mail: fpv@icp.ac.ru

Larisa Blinova - Senior Engineer of IPCP RAS.

1 Aсad. Semenov ave., Chernogolovka, 142432, tel./fax: +7(49652)2-54-01; e-mail: fpv@icp.ac.ru

fpv@icp.ac.ruТарасовБ. П.TarasoB. P.

Тарасов Борис Петрович - кандидат химических наук, заведующий лабораторией ИПХФ РАН.

Д. 1, пр. Акад. Семенова, г. Черноголовка, Московская обл., 142432,  тел./факс: +7(496) 522-54-01; e-mail: fpv@icp.ac.ru

Boris Tarasov - Ph.D. (chemistry), Head of Laboratory of Institute of Problems of Chemical Physics of RAS.

1 Aсad. Semenov ave., Chernogolovka, 142432, tel./fax: +7(49652)2-54-01; e-mail: fpv@icp.ac.ru

fpv@icp.ac.ruИнститут проблем химической физики РАНРоссияInstitute of Problems of Chemical Physics of RASRussian FederationИнститут проблем химической физики РАН; Московский государственный университет имени М.В. ЛомоносоваРоссияInstitute of Problems of Chemical Physics of RAS; Lomonosov Moscow State UniversityRussian FederationИнститут проблем химической физики РАН; Ивановский государственный университетРоссияInstitute of Problems of Chemical Physics of RAS; Ivanovo State UniversityRussian Federation20172702201701-33445Copyright © Международный издательский дом научной периодики "Спейс, 20172017Международный издательский дом научной периодики "СпейсМеждународный издательский дом научной периодики "Спейсhttps://www.isjaee.com/jour/about/submissions#copyrightNoticehttps://www.isjaee.com/jour/article/view/936

Сформированы композиты гидрида магния с оксидами лантаноидов (лантана, церия и тербия) и изучена динамика термического разложения гидрида в композите. Установлено, что в результате помола смесей порошков MgH2 с добавками оксидов в количестве 2 мол. % под давлением водорода 10 атм образуется композит, где частицы оксидов лантаноидов равномерно распределены в объеме более крупных частиц гидрида магния. Добавки бинарных оксидов La, Ce, Tb смещают в сторону более низких температур эндоэффекты, отвечающие реакциям разложения фаз дигидрида магния в композитах, причем данное смещение максимально в случае оксида церия.

The paper studies the effect of additions of binary lanthanide oxides (lantana, ceria, and terbia) on the thermal decomposition of magnesium hydride phase. It is shown that ball-milling of powder mixtures of MgH2 with 2mol% of the oxides in 10 bar hydrogen atmosphere makes possible the formation of composites where the particles of lanthanide oxides distribute uniformly in the volume of larger particles of magnesium hydride. The additions of the oxides of lanthanum, cerium, and terbium have been found to shift towards lower values the temperatures of the endothermic thermal decomposition of the magnesium hydride phases in the composites, and the addition of ceria having strongest effect.

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The authors declare that there are no conflicts of interest present.