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THE STUDY OF THE HYDROGEN PRODUCTION DURING THE MAGNESIUM OXIDATION IN AQUEOUS SALT SOLUTIONS AT TEMPERATURES RANGING FROM –40 ºC TO +20 ºC
https://doi.org/10.15518/isjaee.2017.10-12.063-074
Abstract
The paper is devoted to the investigation of hydrogen production from magnesium oxidation in aqueous salt solutions under low temperature conditions. This study determines the solution compositions suitable for effective low-temperature magnesium oxidation with hydrogen production, and the reaction rate dependence on temperature. A number of experiments were conducted using various solution compositions. The obtained experimental results can be very useful when developing a hydrogen production system. The experimental data obtained demonstrate that at temperature of 0ºC magnesium conversion for MgCl2 solution is equal to 94,5%, for AlCl3 – 84,5%; at –20 ºC for MgCl2 – 32,5%, for AlCl3 – 65,1%; at –40ºC for AlCl3 – 85,2%. Moreover the paper demonstrates that oxidation of magnesium powder in some aqueous solutions provides hydrogen production with high hydrogen yields even at low temperatures. The results of this study can be used for designing power supply systems which can operate in Arctic regions and provide electricity supply to drones (at 6,000 m above the sea level, Tambient = –24 ºC).
About the Authors
O. A. Buryakovskaya
Joint Institute for High Temperatures of the Russian Academy of Sciences
Russian Federation
Russian Federation
Junior Researcher
S. S. Ryzhkova
Joint Institute for High Temperatures of the Russian Academy of Sciences
Russian Federation
Intern Researcher
Russian Federation
Intern Researcher
M. S. Vlaskin
Joint Institute for High Temperatures of the Russian Academy of Sciences
Russian Federation
Ph.D. (engineering), Head of the Energy Accumulating Materials Laboratory
Russian Federation
Ph.D. (engineering), Head of the Energy Accumulating Materials Laboratory
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Review
For citations:
Buryakovskaya O.A., Ryzhkova S.S., Vlaskin M.S. THE STUDY OF THE HYDROGEN PRODUCTION DURING THE MAGNESIUM OXIDATION IN AQUEOUS SALT SOLUTIONS AT TEMPERATURES RANGING FROM –40 ºC TO +20 ºC. Alternative Energy and Ecology (ISJAEE). 2017;(10-12):63-74. (In Russ.) https://doi.org/10.15518/isjaee.2017.10-12.063-074
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