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THE PROSPECTS OF MAGNESIUM APPLICATION IN THE METAL-AIR ELECTROCHEMICAL GENERATORS
https://doi.org/10.15518/isjaee.2018.19-21.052-061
Abstract
The paper discusses the prospects of using metal-air electrochemical current sources, in particular the advantages of using magnesium as an anode. The methods for increasing the efficiency of the anode, electrolyte and cathode are analyzed. Moreover, the paper presents the comparative electrochemical characteristics of various metals used as an anode, their effectiveness, advantages, and availability. At the same time, this research considers a number of problems that are specific to metal-air current sources and ways to overcome them. We discuss the methods for reducing the cost of magnesium production and utilization of the by-product of the reaction – magnesium hydroxide based on a new technology (ECOATOM, LLC; Republic of Armenia).
About the Authors
R. K. Kostanyan
Sci.-Ind. ECOATOM, LLC
Armenia
Armenia
Rafayel Kostanyan - Ph.D. Student, SPA “ECOATOM”, LLC.
Education: Armenian State University of Technology, Master Degree, 2010.
Research interests: chemical technology; electrochemistry.
Publications: 10.
1 Adanai St., Yerevan, 0082.
Tel.: +374 91 275751.
G. G. Karamyan
Institute of Chemical Physics of NAS of Armenia
Armenia
Armenia
Gagik Karamyan - Ph.D. in Physics and Mathematics, Senior Researcher, Institute of Chemical Physics after A.B. Nalbandyan of Nat. Acad. Sci. of Armenia.
Education: Yerevan State University, Physical Faculty, 1970.
Research interests: processing of rock concentrates; electrochemical
current sources; renewable energy; ecology.
Publications: 90.
5/2 P. Sevak St., Yerevan, 0014.
Tel.: +374 94 103647.
G. A. Martoyan
Sci.-Ind. ECOATOM, LLC
Armenia
Armenia
Gagik Martoyan - Ph.D. in Chemistry, SPA Ecoatom.
Education: Yerevan State University, Physical Faculty, 1975.
Research interests: processing of liquid radioactive waste; renewable energy; ecology.
Publications: 157.
1 Adanai St., Yerevan, 0082.
Tel.: +374 91 275751.
V. I. Sachkov
SFTI, Tomsk State University
Russian Federation
Russian Federation
Viktor Sachkov - D.Sc. in Chemistry, Head of Laboratory, Tomsk State University.
Education: Tomsk State University, 1995.
Research interests: laser technology; nanotechnology; chemical kinetics.
Publications: 120.
Novosobornaya Sq., Tomsk, 634050.
Tel.: +7 (3822) 53 35 77.
M. A. Kazaryan
P.N. Lebedev Physical Institute
Russian Federation
Russian Federation
Mishik Kazaryan - D.Sc. in Physics and Mathematics, Leading Researcher, Physical Institute named after P. N. Lebedev RAS.
Education: Moscow Institute of Physics and Technology, 1970.
Research interests: laser machining of composite materials.
Publications: 600.
53 Leninskiy Av., Moscow, 119991.
Tel.: +7 (499) 135 42 64.
References
1. Cao D.L. et al. Electrochemical behavior of Mg−Li, Mg−Li−Al and Mg−Li−Al−Ce in sodium chloride solution. Journal of Power Sources, 2008;177 (2):624−630.
2. Suresh Kannan A.R., Muralidharan S., Sarangapani K.B.,Balaramachandran V.,Kapali V. Corrosion and anodic behaviour of zinc and its ternary alloys in alkaline battery electrolytes. Journal of Power Sources, 1995;57(1):93−98.
3. Zhang T., Tao Z., Chen J. Magnesium-air batteries: from principle to application. Mater. Horiz. 2014;1:196−206.
4. Peng Z. A Reversible and Higher-Rate Li-O2 Battery. Science, 2012;337(6094):563−566.
5. Lee J.S., Kim S.T., Cao R., Choi N.‐S., Liu M., Lee K. T., Cho J. Metal–air batteries with high energy density: Li–air versus Zn–air. Adv. Energy Mat., 2011;(1):34−50.
6. Yan Y. Ionic Liquid Electrolytes in Mg-Air Batteries. Dissertation, Institute for Frontier Materials Deakin University, 2016.
7. Rahman M.A., Wang X., Wen C. High energy density metal-air batteries: a review. Journal of Electroch. Society, 2013;160(10):A1759-A1771.
8. Hamlen R.P., Jerabek E.C., Ruzzo J.C., Siwek E.G. Anodes for Refuelable Magnesium-Air Batteries. J. Electrochem. Soc., 1969;116:1588–1592.
9. Li W., Li Ch., Zhou Ch., Ma H., Chen J. Metallic Magnesium Nano/Mesoscale Structures: Their Shape‐Controlled Preparation and Mg/Air Battery Applications. Angew. Chem. Int. Ed., 2006;45(36):6009–6012.
10. Cao D., Wan K., Wang N. Electrochemical oxidation behavior of Mg−Li−Al−Ce−Zn and Mg−Li−Al−Ce−Zn−Mn in sodium chloride solution. Journal of Power Sources, 2008;183(2):799−804.
11. Ma Y. Performance of Mg-14Li-1Al-0.1Ce as anode for Mg-air battery. J. Power Sources, 2011;196(4):2346−2350.
12. Guo Y., Li N., Li D., Zhang M., Huang X. Boron-based electrolyte solutions with wide electrochemical windows for rechargeable magnesium batteries. Energy Environ. Sci., 2012;5: 9100−9106.
13. Jiang Z., Sirotina R., Iltchev. US Patent 8211578Z, IPC H01M4/58, H01M6/04. Magnesium cell with improved electrolyte, 2012.
14. Khoo T., Somers A., Torriero A.A.J., Macfarlane D.R., Howlett P., Forsyth M. Discharge behaviour and interfacial properties of a magnesium battery incorporating trihexyl (tetradecyl) phosphonium based ionic liquid electrolytes. Electrochim. Acta, 2013;87:701–708.
15. Hoge W.H. US Patent 4,906,535, IPC H01M12/06, H01M4/88, H01M4/96. Electrochemical cathode and materials therefor, 1990.
16. Hasvold O., Hasvold Ø., Lian T., Haakaas E., Størkersen N., Perelman O., Cordier S. CLIPPER: a long-range, autonomous underwater vehicle using magnesium fuel and oxygen from the sea. Journal of Power Sources, 2004;136 (2):232‒239.
17. Hahn R., Mainert J., Glaw F., Lang K.-D. Sea water magnesium fuel cell power supply. Journal of Power Sources, 2015;288:26‒35.
18. Yabe T., Suzuki Y., Satoh Y.Renewable Energy Cycle with Magnesium and Solar-Energy-Pumped Lasers. Renewable Energy & Power Quality Journal, 2014;1(12):236.
19. Yabe T., Yamaji T.The Magnesium Civilization: An Alternative New Source of Energy to Oil. Pan Stanford Publishing, 2010, Science, pp. 1−147.
20. Martoyan G.A. US Patent Application 20130233720 A1, IPC C25C5/02. Extraction of Metals, 2013.
Review
For citations:
Kostanyan R.K., Karamyan G.G., Martoyan G.A., Sachkov V.I., Kazaryan M.A. THE PROSPECTS OF MAGNESIUM APPLICATION IN THE METAL-AIR ELECTROCHEMICAL GENERATORS. Alternative Energy and Ecology (ISJAEE). 2018;(19-21):52-61. (In Russ.) https://doi.org/10.15518/isjaee.2018.19-21.052-061
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