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THE PECULIARITIES OF SYNTHESIS AND CERTIFICATION OF CARBON NANOSTRUCTURED MATERIALS
https://doi.org/10.15518/isjaee.2018.19-21.072-090
Abstract
The paper considers the peculiarities of pyrolytic synthesis and attestation of carbon nanostructured materials. It is noted that the factors which influence the formation of the product during pyrolysis could be: the reactor design, the method of energy introduction, preparation and chemical composition of the gas mixture, as well as the choice and preparation of the catalyst. We have researched the nanocarbon products during their heating from room temperature to 1,400 ° C and have found out the temperature interval of their interaction with air. The features oxidation by air various carbon nanomaterials are shown to be individual for each nanostructure. The studies of soot, fullerites, nanotubes, graphite have made it possible to give a qualitative assessment of the presence in the products of synthesis (unknown composition) of various carbon structures. The temperatures of the change in mass proved to be useful for determining the composition of their mixtures.
The paper shows that analysis of the curves corresponding to the oxidation of the initial fullerene-containing soot indicates the presence of at least three phases in the sample. Moreover, pyrolysis products analysis has showed that the degree of graphitization of such structures exerts a special influence on the interaction parameters (speed and temperature) of carbon nanostructures with air oxygen. During the acetylene pyrolysis, a mirror graphite-like film forms on the walls of the quartz reactor. The nature of its oxidation curves is identical to the character of the oxidation of graphite MPG-7, but is somewhat shifted to the high-temperature region. In this paper, a complex analysis of carbon nanostructures obtained by various methods is carried out for the first time, and it is also shown that carbon nanostructures can be classified according to their thermal stability in air at normal pressure.
Keywords
graphite,
fullerite,
carbon nanostructured materials,
soot,
oxidation,
thermogravimetry,
differential-thermal analysis
Supporting agencies: The Foundation for the Development of Science under the President of the Republic of Azerbaijan
About the Authors
S. Yu. Zaginaichenko
Frantsevich Institute for Problems of Materials Science of NASU
Ukraine
Ukraine
Svetlana Zaginaichenko - D.Sc. in Physics and Mathematics, Professor, Senior Researcher at Laboratory no. 67 “Investigation of Processes andSystems of Hydrogen and Solar-Hydrogen EnergyTransformation” in Institute for Problems of Materials Science of NAS of Ukraine, Kiev.
Education: Dnepropetrovsk National University with degree of Physicist, Teacher of Physics,1979; Dnepropetrovsk Metallurgical Institute,postgraduate studies, 1982.
Research interests: physical properties of metals, ordering alloys, fullerenes on the level ofmolecular-kinetic theory; theory of phase transformations in metal-hydrogen systems and carbonmaterials; determination of hydrogen solubility inthese solids, comparison of theoretical results withexperimental data.
Publications: about 500, including 7 monographs.
3 Krzhyzhanovsky St., Kiev, 03142.
Fax: 38 (044) 424 03 81.
D. V. Schur
Frantsevich Institute for Problems of Materials Science of NASU
Ukraine
Ukraine
Dmitry Schur - Ph.D. in Chemistry, Professor, Chief of Laboratory no. 67 “Investigation of Processes and Systems of Hydrogen and Solar-Hydrogen Energy Transformation” in Institute for Problems of Materials Science of NAS of Ukraine, Kiev.
Education: Kiev Polytechnic Institute with degree in Chemical Engineering, 1980–1985; Institute for Problems of Materials Science of NAS of Ukraine, postgraduate studies, 1986–1990.
Research interests: hydrogen materials science and carbon nanostructures (synthesis, properties and application); the hydrogen and carbon plasma; the peculiarities of the hydrogenation processes of materials and carbon nanostructures; the use of materials as systems for hydrogen storage.
Publications: more than 530, 9 monographs, 4 patents.
3 Krzhyzhanovsky St., Kiev, 03142.
Fax: 38 (044) 424 03 81.
M. T. Gabdullin
Kazakh-British Technical University; National Nanotechnology Laboratory, Al-Farabi Kazakh National University
Kazakhstan
Kazakhstan
Maratbek Gabdullin - Ph.D. in Physics and Mathematics, Director of National Nanotechnological Laboratory of open type at Al-Farabi Kazakh National University.
Education: Al-Farabi Kazakh National University “Physicist”, 1999.
Research interests: nanotechnology; the thermodynamic properties of nonideal plasma.
Publications: more than 60.
71 Ali al-Farabi Av., Almaty, 050040.
Tel.: +7 (727) 221 10 00.
N. F. Javadov
National Aviation Academy of Azerbaijan
Azerbaijan
Azerbaijan
Nariman F. Javadov - Employee of the Department of Chemistry and Materials Science, National Academy of Aviation in Azerbaijan.
Education: Azerbaijan Oil and Chemistry Institute in specialty Engineer and Economist for the Organization and the Economics of Chemical Industry.
Research interests: synthesis of polymers, polymer compositions and composite materials; chemistry of carbon nanomaterials and their application.
Publications: more than 40, including chapters in monographs and 12 patents.
Mardakyan Drive, Bina Khazarsky village, Baku, AZ1045.
Tel.: (+99412) 556 51 13.
Al. D. Zolotarenko
Frantsevich Institute for Problems of Materials Science of NASU
Ukraine
Ukraine
Alexander Zolotarenko - Ph.D. in Chemistry, Senior Researcher at Institute for Problems of Materials Science of National Academy of Sciences (IMPS NASU).
Education: National Technical University of Ukraine “Kiev Polytechnic Institute” (NTUU“KPI”, 2008), The Faculty of Chemistry and Chemical Engineering; Ph.D. in Physical Chemistry at Institute for Problems of Materials Science NASU (IMPS NASU), Laboratory “Hydrogen Materials Science and Chemistry of Carbon Nanomaterials” of Ukraine.
Research interests: synthesis of metal-carbon Nanocomposites in the gaseous and liquid media, the study of their structure and magneticproperties; the synthesis of carbon-containing compounds by pyrolytic method; physicochemical features of the synthesis of carbon-containing materials.
Publications: 57.
3 Krzhyzhanovsky St., Kiev, 03142.
Fax: 38 (044) 424 03 81.
An. D. Zolotarenko
Frantsevich Institute for Problems of Materials Science of NASU
Ukraine
Ukraine
Anatoliy Zolotarenko - Ph.D. in Chemistry, Senior Researcher at Institute for Problems of Materials Science of National Academy of Sciences (IMPS NASU).
Education: National Technical University of Ukraine “Kiev Polytechnic Institute” (NTUU “KPI”, 2008), The Faculty of Chemistry and Chemical Engineering; Ph.D. in Physical Chemistry, Institute for Problems of Materials Science NASU (IMPS NASU), Laboratory “Hydrogen Materials Science and Chemistry of Carbon Nanomaterials” of Ukraine.
Research interests: synthesis of metalcarbon nanocomposites in the gaseous and liquid media, the study of their structure and magnetic properties; the synthesis of carbon-containing compounds by pyrolytic method; physicochemical features of the synthesis of carbon-containing materials.
Publications: 59.
3 Krzhyzhanovsky St., Kiev, 03142.
Fax: 38 (044) 424 03 81.
A. D. Zolotarenko
Frantsevich Institute for Problems of Materials Science of NASU
Ukraine
Ukraine
Aleksey Zolotarenko - Ph.D. In Chemistry, Senior Researcher, Laboratory No 67 “Investigation of Processes and Systems of Hydrogen and Solar-Hydrogen Energy Transformation” in Institute for Problems of Materials Science of NAS of Ukraine.
Education: Kiev Polytechnic Institute with degree in Chemical Engineering, 2004; Institute for Problems of Materials Science of NAS of Ukraine, Postgraduate Studies, 2008.
Research interests: chemistry of carbon nanomaterials and materials science hydrogen; carbon and hydrogen plasma; the features of the processes of formation of carbon nanostructures; hydrogen materials science; the use of materials as hydrogen storage systems.
Publications: 96, including the chapters in monographs and 4 patents.
3 Krzhyzhanovsky St., Kiev, 03142.
Fax: 38 (044) 424 03 81.
S. Kh. Mamedova
National Aviation Academy of Azerbaijan
Azerbaijan
Azerbaijan
Sevda K. Mammadova - Ph.D. in Chemistry, Associate Professor, Head of the Department of Chemistry and Materials Science, National Aviation Academy of Azerbaijan.
Education: Azerbaijan State University, Chemical Faculty, specialist in Chemistry, 1964–1969; Institute of Petrochemical Processes of Academy of Sciences of Azerbaijan, post-graduate studies, 1970–1974.
Research interests: material science and synthesis of heterogeneous catalysts; study of the features of hydrogenation, dehydrogenation, dehydrocyclization, isomerization and dehydrodisproportionation of hydrocarbons.
Publications: more than 50, including 4 author’s certificates and 1 patent.
Mardakyan Drive, Bina Khazarsky village, Baku, AZ1045.
Tel.: (+99412) 556 51 13.
G. D. Omarova
National Aviation Academy of Azerbaijan
Azerbaijan
Azerbaijan
Gulnara J. Omarova - Ph.D. in Engineering, Associate Professor, the Chemistry and Materials Science Department at National Aviation Academy of Azerbaijan.
Education: Mendeleev University of Chemical Technology of Russia, specializing in the chemical technology of high-molecular compounds.
Research interests: marine ecology; remote aerospace monitoring; high-molecular compounds; composite materials; nanotechnologies.
Publications: more than 40, including 1 monograph, 5 manuals and guidelines.
Mardakyan Drive, Bina Khazarsky village, Baku, AZ1045.
Tel.: (+99412) 556 51 13.
Z. T. Mamedova
National Aviation Academy of Azerbaijan
Azerbaijan
Azerbaijan
Zubeyda T. Mammadova - lecturer at the Chemistry and Materials Science Department of National Aviation Academy of Azerbaijan.
Education: Baku State University, Chemical Faculty, Bachelor in Chemistry, Azerbaijan State Pedagogical University, master degree in “Organic chemistry and chemical technology”.
Research interests: fine organic synthesis; nanotechnology; polymeric materials.
Publications: more than 7.
Mardakyan Drive, Bina Khazarsky village, Baku, AZ1045.
Tel.: (+99412) 556 51 13.
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Review
For citations:
Zaginaichenko S.Yu., Schur D.V., Gabdullin M.T., Javadov N.F., Zolotarenko A.D., Zolotarenko A.D., Zolotarenko A.D., Mamedova S.Kh., Omarova G.D., Mamedova Z.T. THE PECULIARITIES OF SYNTHESIS AND CERTIFICATION OF CARBON NANOSTRUCTURED MATERIALS. Alternative Energy and Ecology (ISJAEE). 2018;(19-21):72-90. (In Russ.) https://doi.org/10.15518/isjaee.2018.19-21.072-090
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