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Выделение водорода из водного раствора гидразин-бисборана
https://doi.org/10.15518/isjaee.2019.28-33.023-035
Аннотация
В статье рассматривалась возможность использования водного раствора гидразин-бисборана (ГББ) H3B– N2H4–BH3 в качестве жидкого материала для химического хранения водорода (H) в условиях полного дегидрирования раствора в мягкой среде. Авторами впервые в научной литературе описан процесс дегидрирования водного раствора ГББ, проявляющего неустойчивость в воде. В щелочной среде степень устойчивости оказалась еще ниже, что обусловлено образованием неустойчивого промежуточного соединения [H3BOH] – . Установлено, что посредством металлических катализаторов гидролиз производных борана BH3 ускоряется, при этом наиболее активным оказался биметаллический катализатор на основе NiPt, способствующий, кроме того, разложению молекулы N2H4. Лучшие показатели кинетики отмечены в ходе реакции в щелочной среде при температуре 70 °C. При этом происходит неполное дегидрирование с максимальным значением конверсии 80 %, причина которого, к сожалению, пока не ясна. Несмотря на этот и ряд других вопросов, которые могут появиться в дальнейшем, авторы пришли к выводу, что раствор ГББ может быть использован в качестве жидкого материала для химического хранения водорода.
Об авторах
Э. Петит
Европейский институт мембран IEM, UMR 5635 (CNRS-ENSCM-UM2) Университет Монпелье
Франция
Франция
Эдди Петит инженер-химик, эксперт по аналитическим методам
E. Bataillon, F-34095, Монпелье, Франция
У. Б. Демирчи
Европейский институт мембран IEM, UMR 5635 (CNRS-ENSCM-UM2) Университет Монпелье
Франция
Франция
Умит Б. Демирчи д-р физ.-хим. наук., профессор в Университете Монпелье; помощник редактора International Journal of Hydrogen Energy (Elsevier)
E. Bataillon, F-34095, Монпелье, Франция
Список литературы
1. Schlesinger H.I., Brown H.C., Finholt A.E., Gilbreath J.R., Hoekstra H.R., Hyde E.K. Sodium borohydride, its hydrolysis and its use as a reducing agent and in the generation of hydrogen. J. Am. Chem.Soc., 1953;75:215–9.
2. Davis R.E., Gottbrath J.A. Boron hydrides. V. Methanolysis of sodium borohydride. J. Am. Chem.Soc., 1962;84:895–8.
3. Ren J., Musyoka N.M., Langmi H.W., Mathe M., Liao S. Current research trends and perspectives on materials-based hydrogen storage solutions: a critical review. Int. J. Hydrogen Energy, 2017;42:289–311.
4. Demirci U.B. The hydrogen cycle with the hydrolysis of sodium borohydride: a statistical approach for highlighting the scientific/technical issues to prioritize in the field. Int. J. Hydrogen Energy, 2015;40:267–91.
5. Stock A. Hydrides of boron and silicon. Ithaca: Cornell University; 1933. p. 58.
6. Schlesinger H.I., Burg A.B. Recent developments in the chemistry of the boron hydrides. Chem. Rev., 1942;31:1–41.
7. Shore S.G., Parry R.W. The crystalline compound ammoniaborane, H3NBH3. J. Am. Chem.Soc., 1955;77:6084–5.
8. Rusman N.A.A., Dahari M. A review on the current progress of metal hydrides material for solid-state hydrogen storage applications. Int. J. Hydrogen Energy, 2016;41:12108–26.
9. Emeléus H.J., Stone F.G.A. The reaction between diborane and anhydrous hydrazine. J Chem.Soc., 1951:840–1.
10. Karahan S., Zahmakıran., Özkar S. Catalytic hydrolysis of hydrazine borane for chemical hydrogen storage: highly efficient and fast hydrogen generation system at room temperature. Int. J. Hydrogen Energy, 2011;36:4958–66.
11. Goubeau V.J., Ricker E. Borinhydrazin und seine pyrolyseprodukte. Z. Anorg.Allg.Chem., 1961;310:123–42.
12. Hügle T., Kühnel M.F., Lentz D. Hydrazine borane: a promising hydrogen storage material. J. Am. Chem.Soc., 2009;131:7444–6.
13. Moury R., Moussa G., Demirci U.B., Hannauer J., Bernard S., Petit E., et al. Hydrazine borane: synthesis, characterization, and application prospects in chemical hydrogen storage. Phys Chem.Chem. Phys., 2012;14:1768–77.
14. Shakespare W. The tempest. 1611, Act 2, Scene I.
15. Sun W., Gu Q., Guo Y., Guo Z., Liu H., Yu X. Hydrazine bisborane as a promising material for chemical hydrogen storage. Int. J. Hydrogen Energy, 2011;36:13640–4.
16. Nguyen V.S., Swinnen S., Leszczynski J., Nguyen M.T. Formation and hydrogen release of hydrazine bisborane: transfer vs. attachment of a borane. Phys. ChemChem. Phys., 2011;13:6649–56.
17. Gunderloy F.C., Spielvogel B., Parry R.W. Hydrazine-mono- and ebisborane. Inorg Synth., 1967;9:13–6.
18. Li L., Tan Y.Z., Tang Z., Xia G., Yuan F., Li Q, et al. Enhanced dehydrogenation of hydrazine bisborane for hydrogen storage. Mater. Chem. Phys., 2014;143:1055–60.
19. Pylypko S., Petit E., Yot P.G., Salles F., Cretin M., Miele P., et al. Key study on the potential of hydrazine bisborane for solid- and liquid-state chemical hydrogen storage. Inorg. Chem., 2015;54:4574–83.
20. Sayles D.C. Inventor; the United States of America as represented by the secretary of the army, assignee.Compacted hydrazine bisborane fuel and method of operating gas generators. United States Patent US 3,170,283.1965 Feb 23.
21. Coleman J.E. Inventor; Esso research and engineering company, assignee. Stabilized hydrazine bisborane. United States Patent US 3,382,050. 1968 May 7.
22. Olsen R.N. Inventor; Esso research and engineering company, assignee. Monopropellant in binder matrix. United StatesPatent US 3,499,289. 1970 Mar 10.
23. Longwell J.P. Inventor; Esso research and engineering company, assignee. Rocket nozzle cooling. United States Patent US 3,521,452. 1970 July 21.
24. Grant LR, Flanagan JE. Inventors; the United States of America as represented by the secretary of the army, assignee. Advanced solid reactants for H2/D2 generation. United States Patent US 4,381,206. 1983 Apr 26.
25. Hannauer J., Akdim O., Demirci U.B., Geantet C., Herrmann J.M., Miele P., et al. High-extent dehydrogenation of hydrazine borane N2H4BH3 by hydrolysis of BH3 and decomposition of N2H4. Energy Environ. Sci., 2011;4:3355–8.
26. Andrieux J., Demirci U.B., Hannauer J., Gervais C., Goutaudier C., Miele P. Spontaneous hydrolysis of sodium borohydride in harsh conditions. Int. J. Hydrogen Energy, 2011;36:224–33.
27. Karkamkar A., Aardahl C., Autrey T. Recent developments on hydrogen release from ammonia borane. Mater Matters., 2007;2:6–9.
28. Kreevoy M.M., Hutchins J.E.C. H2BH3 as an intermediate in tetrahydridoborate hydrolysis. J. Am. Chem. Soc., 1972;94:6371–6.
29. Mochalov K.N., Khain V.S., Gil’manshin G,G. Kinetic studies on intermediate steps of BH4 hydrolysis. Kinet.Katal., 1965;6:541–4.
30. Mochalov K.N., Khain V.S., Gil’manshin G.G. Generalized scheme for the hydrolysis of the borohydride ion and diborane. DoklAkadNauk, 1965;162:402–6.
31. Molina Concha M.B., Chatenet M., Lima F.H.B., Ticianelli E.A. In situ Fourier transform infrared spectroscopy and on-line differential electrochemical mass spectrometry study of the NH3BH3 oxidation reaction on gold electrodes. Electrochim. Acta, 2013;89:607–15.
32. Olu P.Y., Deschamps F., Caldarella G., Chatenet M., Job N. Investigation of platinum and palladium as potential anodic catalysts for direct borohydride and ammonia borane fuel cells. J. Power Sources, 2015;297:492–503.
33. Kalidindi S.B., Indirani M., Jagirdar B.R. First row transition metal ion-assisted ammonia-borane hydrolysis for hydrogen generation. Inorg. Chem., 2008;47:7424–9.
34. Hannauer J., Demirci U.B., Geantet C., Herrmann J.M., Miele P. Transition metal-catalyzed dehydrogenation of hydrazine borane N2H4BH3 via the hydrolysis of BH3 and the decomposition of N2H4. Int. J. Hydrogen Energy, 2012;37:10758–67.
35. Moussa G., Moury R., Demirci U.B., Miele P. Borates in hydrolysis of NH3BH3. Int. J. Hydrogen Energy, 2013;38:7888–95.
36. Chandra M., Xu Q. A high-performance hydrogen generation system: transition metal-catalyzed dissociation and hydrolysis of ammonia-borane. J. Power Sources, 2006;159:190–4.
37. Hannauer J., Demirci U.B., Geantet C., Herrmann J.M., Miele P. Enhanced hydrogen release by catalyzed hydrolysis of sodium borohydride-ammonia borane mixtures: a solution- state 11B NMR study. Phys. Chem. Chem. Phys., 2011;13:3809–18.
38. Janda R., Heller G. IR- and Ramanspektren isotope markieter tetra- und pentaborate. Spectrochim Acta, 1982;36A:997–1001.
39. Jun L., Shuping X., Shiyang G. FT-IR and Raman spectroscopic study of hydrated borates. Spectrochim Acta, 1995;51:519–32.
40. Demirci U.B., Bernard S., Chiriac R., Toche F., Miele P. Hydrogen release by thermolysis of ammonia borane NH3BH3 and then hydrolysis of its by-product [BNHx]. J. Power Sources, 2011;196:279–86.
41. Singh S.K., Xu Q. Bimetallic Ni-Pt nanocatalysts for selective decomposition of hydrazine in aqueous solution to hydrogen at room temperature for chemical hydrogen storage. Inorg. Chem., 2010;49:6148–52.
42. Zhu Q.L., Zhong D.C., Demirci U.B., Xu Q. Controlled synthesis of ultrafine surfactant-free NiPt nanocatalysts toward efficient and complete hydrogen generation from hydrazine borane at room temperature. ACS Catal., 2014;4:4261–9.
43. Zahmakıran M., Özkar S. Transition metal nanoparticles in catalysis for the hydrogen generation from the hydrolysis of ammonia-borane. Top Catal., 2013;56:1171–83.
44. Patel N., Miotello A. Progress in Co-B related catalyst for hydrogen production by hydrolysis of boronhydrides: a review and the perspectives to substitute noble metals. Int. J. Hydrogen Energy, 2015;40:1429–64.
45. Gao W., Li C., Wu M., He S., Wei M., Evans D.G., et al. Supported nickel-iron nanocomposites as a bifunctional catalyst towards hydrogen generation from N2H4·H2O. Green Chem., 2014;16:1560–8.
46. Singh S.K., Xu Q. Complete conversion of hydrous hydrazine to hydrogen at room temperature for chemical hydrogen storage. J. Am. Chem. Soc., 2009;131:18032–3.
47. Singh S.K., Xu Q. Bimetallic nickel-iridium nanocatalysts for hydrogen generation by decomposition of hydrous hydrazine. Chem. Commun., 2010;46:6545–7.
48. Singh S.K., Iizuka Y., Xu Q. Nickel-palladium nanoparticle catalyzed hydrogen generation from hydrous hydrazine for chemical hydrogen storage. Int. J. Hydrogen Energy, 2011;36:11794–801.
49. Schlesinger H.I., Burg A.B. Hydrides of boron. I. An efficient new method of preparing diborane; new reactions for preparing bromo-diborane and the stabler pentaborane, B5H9. J. Am. Chem. Soc., 1931;53:4321–32.
Рецензия
Для цитирования:
Петит Э., Демирчи У.Б. Выделение водорода из водного раствора гидразин-бисборана. Альтернативная энергетика и экология (ISJAEE). 2019;(28-33):23-35. https://doi.org/10.15518/isjaee.2019.28-33.023-035
For citation:
Petit E., Demirci U.B. Hydrogen Release from Aqueous Hydrazine Bisborane. Alternative Energy and Ecology (ISJAEE). 2019;(28-33):23-35. (In Russ.) https://doi.org/10.15518/isjaee.2019.28-33.023-035
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