Соединение аммиак-борана с никелем в качестве универсального твердотельного материала для получения водорода путем гидролиза

В статье рассматривалась возможность использования аммиак-борана NH₃BH₃ (АБ) в соединении с никелем (Ni) в качестве универсального твердотельного материала для производства H₂ путем гидролиза при температуре 20–50 °C. Предложенный авторами метод (Ni/АБ) имеет дело с наночастицами АБ внутри матрицы Ni. При контакте с водой структура Ni/АБ легко гидролизирует и освобождает H₂ с частотой преобразования 13,8 моль(H₂)  моль^-1_Ni /мин^–1 при 43,3 °C. Установлено, что кажущаяся энергия активации в температурном диапазоне 23,5–50,4 °C невысока и составляет 19,5 ± 4,1 кДж/моль^–1 . Результаты проведенных экспериментов свидетельствуют о том, что матрица Ni, содержащая АБ, может выступать в роли эффективного катализатора. Помимо каталитических характеристик, в статье впервые описано успешное применение универсальных твердотельных структур при гидролизе АБ, что открывает уникальные возможности для развития одноразовых катализаторов.

аммиак-боран, химическое хранение водорода, производство водорода, гидролиз, наноразмерный, никель

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