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Calcium Manganese(III) Oxides (CaMn2O4·xH2O) as Biomimetic Oxygen-Evolving Catalysts
https://doi.org/10.15518/isjaee.2019.28-33.086-092
Abstract
Biomimetic and efficient: Mixed calcium manganese(III) oxides (see structure; Ca green, Mn red, O white) with elemental compositions and structures mimicking the active site of photosystem II were found to be highly active catalysts for the oxidation of water to molecular oxygen. As for PS II, the presence of Ca2+ greatly enhances the catalyst performance in comparison to the related manganese‐only system Mn2O3.
Supporting agencies: The authors would like to thank Ursula Cornelissen, Bastian Dietl, Kathrin Gerwien, Joachim Gripp, Jannes Ophey, Enrique Quiroga, Monika Schneeweis, Christian Stoltenberg, and Adam Wutkowski (all CAU Kiel) for experimental support. M.M.N. thanks the Ministry of Science and the National Elite Foundation of Iran for a travel grant. This work was financed by the Fonds der Chemischen Industrie (Liebig fellowship for P.K.).
About the Authors
M. M. Najafpour
Institute for Inorganic Chemistry, Christian-Albrechts-University Kiel;
Institute for Advanced Studies in Basic Sciences (IASBS)
Russian Federation
Russian Federation
2 Max-Eyth-Strasse, Kiel, 24118, Germany
Zanjan, Iran
T. Ehrenberg
Institute for Inorganic Chemistry, Christian-Albrechts-University Kiel
Russian Federation
2 Max-Eyth-Strasse, Kiel, 24118,Germany
Russian Federation
2 Max-Eyth-Strasse, Kiel, 24118,Germany
M. Wiechen
Institute for Inorganic Chemistry, Christian-Albrechts-University Kiel
Russian Federation
2 Max-Eyth-Strasse, Kiel, 24118,Germany
Russian Federation
2 Max-Eyth-Strasse, Kiel, 24118,Germany
Ph. Kurz
http://www.ac.uni-kiel.de/phkurz
Institute for Inorganic Chemistry, Christian-Albrechts-University Kiel
Russian Federation
2 Max-Eyth-Strasse, Kiel, 24118,Germany
Institute for Inorganic Chemistry, Christian-Albrechts-University Kiel
Russian Federation
2 Max-Eyth-Strasse, Kiel, 24118,Germany
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Review
For citations:
Najafpour M.M., Ehrenberg T., Wiechen M., Kurz P. Calcium Manganese(III) Oxides (CaMn2O4·xH2O) as Biomimetic Oxygen-Evolving Catalysts. Alternative Energy and Ecology (ISJAEE). 2019;(28-33):86-92. (In Russ.) https://doi.org/10.15518/isjaee.2019.28-33.086-092
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