Buy (120 RUB)
|Generate QR code
Open Access
Subscription or Fee Access
Research of bıodıesel obtaıned from agro-ındustrıal waste usıng physıcochemıcal methods
https://doi.org/10.15518/isjaee.2025.01.105-114
Abstract
In modern petrochemistry, in the conditions of increasing energy shortage and significant increase in demand for all types of fuel raw materials, saving energy resources and raw materials is an extremely urgent problem. Biodiesel is an alternative fuel used in diesel engines, made from renewable raw materials such as vegetable oils. The article discusses the process of obtaining biodiesel from grape seed oil, a waste remaining after the production of various wines and fruit juices, at Ganja Sharab-2 OJSC, an agro-industrial enterprise operating in the Western region of Azerbaijan. Oil obtained by extraction from grape seed waste was used as raw material. Biodiesel was produced from grape seed oil by transesterification using KOH as a catalyst, the reaction temperature range is 20˚C, 40˚C, 60˚C and the ratio of oil to methanol is 1:3, 1:6, 1:12 mol. When the transesterification reaction was carried out optimally at a molar ratio of oil to methanol of 1:12 and a temperature of 60˚C, the biodiesel yield increased from 60% to 100%. The composition of the resulting biodiesel was analyzed by IR spectroscopy and confirmed by peaks indicating that it was formed as a result of transesterification of vegetable oils. Various physicochemical properties of biodiesel fuel were studied in comparison with the properties of petroleum-based diesel fuel. The resulting biofuel surpasses traditional diesel fuel in both its physicochemical properties and environmental and performance characteristics. To improve the operational and environmental properties of diesel fuel, it is proposed to use biodiesel as a biological additive.
About the Authors
A. B. Suleymanova
Institute of Bioresources of the Ministry of Science and Education of the Republic of Azerbaijan
Azerbaijan
Azerbaijan
Suleymanova Aisha Baba - head of the laboratory “Oils and ointments”
Az 2002, Azerbaijan, Ganja, G. Aliyev Avenue, 419
+99450-488-37-92, 022556769
G. S. Mukhtarova
Institute of Petrochemical Processes named after Y. Mamedaliyev Ministry of Science and Education of the Republic of Azerbaijan
Azerbaijan
Azerbaijan
Mukhtarova Gulbaniz Siyavush - Doctor of Technical Sciences, Associate Professor, Senior Researcher at Laboratory No. 21
Az 1025, Azerbaijan, Baku, Khojaly Avenue, 30
+99455-827-80-36, 0224932367
References
1. Hajjaria M. A review on the prospects of sustainable biodiesel production: A global scenario with an
2. emphasis on waste-oil biodiesel utilization / M. Hajjaria [et al.] // Renewable and Sustainable Energy Reviews, – 2017. – Vol. 72. – P. 445-464. https://ideas.repec.org/a/eee/rensus/v72y2017icp445-464.html
3. Murugesan A. Bio-Diesel as an Alternative Fuel for Diesel Engines-A Review / A. Murugesan A. [et al.] // Renewable and Sustainable Energy Reviews. – 2009. – Vol.13. – P. 653-662.
4. Mukhtarova G.S., Suleymanova A.B. Study of biodiesel obtained from agro-industrial waste / G.S. Mukhtarova, A.B. Suleymanova // Processes of Petrochemistry and Oil Refining. – 2024. – Vol. 25, iss. 3. – P. 666-674.
5. Mukhtarova G.S. Study of regime parameters effect on hydrocracking process of fuel oil in the presence of nano-sized halloysite modified by Mo, Ni / G.S. Mukhtarova // Processes of Petrochemistry and Oil Refining. – 2021. – Vol.22, iss. 4. – P.441-449.
6. Hasanova A.B., Production of diesel fraction frome the hydrocracking process of fuel oil / G.S. Mukhtarova, A.B. Hasanova // Processes of Petrochemistry and Oil Refining. – 2023. –Vol. 24, iss. 2. – P. 278-285.
7. Takase M. An Expatiate Review of Neem, Jatropha, Rubber and Karanja as Multipurpose Non-Edible Biodiesel Resources and Comparison of Their Fuel / M. Takase [et al.] // Engine and Emission Properties. Renewable and Sustainable Energy Reviews. – 2015. – Vol.43. –P. 495-520.
8. Demirbas A. Relationships Derived from Physical Properties of Vegetable Oil and Biodiesel Fuels / A. Demirbas // Fuel. – 2008. – Vol.87. – P. 1743-1748.
9. Knothe G. “Designer” Biodiesel: Optimizing Fatty Ester Composition to Improve Fuel Properties / G. Knothe // Energy and Fuels. – 2008, – Vol.22. – P.1358-1364.
10. Cardone M., Mazzoncini M., Menini S., Rocco V., Senatore A., Seggiani M., Vitolo S. Brassica carinata as an alternative oil crop for the production of biodiesel in Italy: agronomic evaluation, fuel production by transesterification and characterization / M. Cardone [et al.] // Biomass Bioenergy. –2003. – Vol.25. – P. 623-636.
11. Antolin G. Optimisation of biodiesel production by sunflower oil transesterification / G. Antolin [et al.] // Bioresource Technology. – 2004. – Vol. 83. – P. 111-114.
12. Bajpai D. Biodiesel: source, production, composition, properties and its benefits / D. Bajpai, V.K. Tyagi // Journal of Oleo Science. – 2006. – Vol.55. – P. 487-502.
13. Kyriakidis N.B., Katsiloulis T. Calculation of iodine value from measurements of fatty acid methyl esters of some oils: comparison with the relevant American oil chemists society method / N.B. Kyriakidis, T. Katsiloulis // Journal of the American Oil Chemists Society. – 2000. –Vol.77. – P. 1235-1238.
14. Lang X. Preparation and characterization of bio-diesels from various bio-oils / X. Lang [et al.] // Bioresource Technology. –2001, – Vol. 80. – P. 53-62.
15. Rutz D., Rainer J. Technology Handbook, / D. Rutz // Rutz D. WIP Renewable Energies / D. Rutz, J. Rainer. – G., 2007. 98-110p.
16. Lois E. Impact of Using Biodiesels of Different Origin and Additives on the Performance of a Stationary Diesel Engine / Lois E. [et al.] // Journal of Engineering for Gas Turbines and Power. – 2000. – Vol. 122, iss. 4. – P. 624-631.
17. Lotko W. The Effect of Rape Oil – Diesel Oil Mixture Composition on Particulate Matter Emission Level in Diesel Engine / W. Lotko, R. Longwic, M. Swat // SAE Technical Paper Series. – 2001. – Vol. 3388, iss. 01. – P. 1-4.
18. Kinast J.A. Production of Biodiesels from Multiple Feedstocks and Properties of Biodiesels and Biodiesel-Diesel Blends / J.A. Kinast // National Renewable Energy Lab., Golden, CO / J.A. Kinast. –B., –2003. – P. 7-31.
19. Yoshimoto Y. Performance and Emission Characteristics of Diesel Engines Fueled by Vegetable Oils / Y. Yoshimoto, M. Onodera, H. Tamaki // SAE Technical Paper Series. – 2001. – Vol. 1807/4227, iss.01. – P. 1-4
20. Meher L.C. Technical Aspects of Biodiesel Production by Transesterification-A Review / L.C. Meher, D. Vidya Sagar, S.N. Naik // Renewable and Sustainable Energy Reviews. – 2004. – Vol. 10. – P. 248-268.
21. Lapuerta M. Ballesteros R. Diesel Particulate Emissions from Biofuels Derived from Spanish Vegetable Oils / M. Lapuerta, O. Armas // SAE Technical Paper Series, – 2002, iss.01, –Vol.1657, –P. 1-7.
22. Cao Y. Qiu-Shi R. Re-characterization of three conjugated linolenic acid isomers by GC-MS and NMR / Y. Cao // Chemistry and physics of lipids. – 2007, – Vol.145. – P. 128-133.
23. Куришбаев А. Возможности эффективного использования водных ресурсов и водородного рынка в Казахстане / А. Куришбаев // Альтернативная энергетика и экология (ISJAEE). – 2024. №1. – С. 1
24. Щуров Н. И. Моделирование и симуляция гибридного электромобиля с топливными ячейками / Н. И. Щуров, С. И. Дедов, А. А. Штанг // Альтернативная энергетика и экология (ISJAEE). – 2024. №2. – С. 166-181. https://doi.org/10.15518/isjaee.2024.02.166-181
Review
For citations:
Suleymanova A.B., Mukhtarova G.S. Research of bıodıesel obtaıned from agro-ındustrıal waste usıng physıcochemıcal methods. Alternative Energy and Ecology (ISJAEE). 2025;(1):105-114. (In Russ.) https://doi.org/10.15518/isjaee.2025.01.105-114
Views:
168
Email this article 