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HYDRATION PROCESS AND STATES OF PROTON-CONTAINING SPECIES IN DOUBLE PEROVSKITE Ba4Ca2Nb2-хРхO11
https://doi.org/10.15518/isjaee.2016.01-02.003
Abstract
The hydrated solid solutions Ba4Ca2Nb2-хРхO11 studied by thermogravimetry, and IR spectroscopy. It was found that the samples are able to reversible dissolution of water vapour, this process is accompanied by appearing in structure nonequivalent ОН-groups with different hydrogen-bonds. The protonic defects concentration reduces with increasing of phosphorus content and the concentration of different ОН-groups is redistributed. Concentration of hydroxyl groups involved in the strong hydrogen bonds (less thermally stable) decreases first.
About the Authors
K. G. Belova
Ural Federal University named after the first President of Russia B.N.Yeltsin
51 Lenin ave., Ekaterinburg, Russia, 620000
Russian Federation
Russian Federation
Ph.D. student, Ural Federal University named after the first President of Russia B.N. Yeltsin
A. V. Obrubova
Ural Federal University named after the first President of Russia B.N.Yeltsin
51 Lenin ave., Ekaterinburg, Russia, 620000
Russian Federation
Russian Federation
undergraduate
S. S. Nokhrin
Ural Federal University named after the first President of Russia B.N.Yeltsin
51 Lenin ave., Ekaterinburg, Russia, 620000
Russian Federation
Russian Federation
Ph.D. (chemistry), assistant professor of Ural Federal University named after the first President of Russia
I. E. Animitsa
Ural Federal University named after the first President of Russia B.N.Yeltsin
51 Lenin ave., Ekaterinburg, Russia, 620000
Russian Federation
Russian Federation
D.Sc. (chemistry), professor, the head of the Department of Inorganic Chemistry of Ural Federal University named after the first President of Russia B.N. Yeltsin
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Review
For citations:
Belova K.G., Obrubova A.V., Nokhrin S.S., Animitsa I.E. HYDRATION PROCESS AND STATES OF PROTON-CONTAINING SPECIES IN DOUBLE PEROVSKITE Ba4Ca2Nb2-хРхO11. Alternative Energy and Ecology (ISJAEE). 2016;(1-2):37-42. (In Russ.) https://doi.org/10.15518/isjaee.2016.01-02.003
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