Buy (120 RUB)
|Generate QR code
Open Access
Subscription or Fee Access
HYDROGEN CONTAINING COMPOSITES OF MAGNESIUM HYDRIDE WITH LANTHANIDE OXIDES
https://doi.org/10.15518/isjaee.2017.01-03.034-045
Abstract
The paper studies the effect of additions of binary lanthanide oxides (lantana, ceria, and terbia) on the thermal decomposition of magnesium hydride phase. It is shown that ball-milling of powder mixtures of MgH2 with 2mol% of the oxides in 10 bar hydrogen atmosphere makes possible the formation of composites where the particles of lanthanide oxides distribute uniformly in the volume of larger particles of magnesium hydride. The additions of the oxides of lanthanum, cerium, and terbium have been found to shift towards lower values the temperatures of the endothermic thermal decomposition of the magnesium hydride phases in the composites, and the addition of ceria having strongest effect.
About the Authors
P. V. Fursikov
Institute of Problems of Chemical Physics of RAS
Russian Federation
Russian Federation
Pavel Fursikov - Ph.D. (chemistry), Senior Researcher of Institute of Problems of Chemical Physics of RAS.
1 Aсad. Semenov ave., Chernogolovka, 142432, tel./fax: +7(49652)2-54-01; e-mail: fpv@icp.ac.ru; 1 Leninskie Gory, Moscow, 119991, e-mail: adilya_f@mail.ru
A. M. Fattakhova
Institute of Problems of Chemical Physics of RAS; Lomonosov Moscow State University
Russian Federation
Russian Federation
Adilya Fattakhova - Student of Faculty of Fundamental Physical and Chemical Engineering of Moscow State University, engineer of Institute of Problems of Chemical Physics of RAS.
1 Aсad. Semenov ave., Chernogolovka, 142432, tel./fax: +7(49652)2-54-01; e-mail: fpv@icp.ac.ru; 1 Leninskie Gory, Moscow, 119991, e-mail: adilya_f@mail.ru
S. A. Mozhzhukhin
Institute of Problems of Chemical Physics of RAS; Ivanovo State University
Russian Federation
Russian Federation
Sergey A. Mozhzhukhin - Postgraduate Student of Ivanovo State University, engineer of Institute of Problems of Chemical Physics of RAS.
1 Aсad. Semenov ave., Chernogolovka, 142432, tel./fax: +7(49652)2-54-01; e-mail: fpv@icp.ac.ru; 39 Ermak str., Ivanovo, 153025, tel.: +7(49552)2-16-48, e-mail: mozhuhin@icp.ac.ru
L. N. Blinova
Institute of Problems of Chemical Physics of RAS
Russian Federation
Russian Federation
Larisa Blinova - Senior Engineer of IPCP RAS.
1 Aсad. Semenov ave., Chernogolovka, 142432, tel./fax: +7(49652)2-54-01; e-mail: fpv@icp.ac.ru
B. P. Taraso
Institute of Problems of Chemical Physics of RAS
Russian Federation
Russian Federation
Boris Tarasov - Ph.D. (chemistry), Head of Laboratory of Institute of Problems of Chemical Physics of RAS.
1 Aсad. Semenov ave., Chernogolovka, 142432, tel./fax: +7(49652)2-54-01; e-mail: fpv@icp.ac.ru
References
1. Tarasov B.P., Lotockiy M.V., Yartysh V.A. Problema hraneniâ vodoroda i perspektivy ispol’zovaniâ gidridov dlâ akkumulirovaniâ vodoroda. Rossijskij himičeskij žurnal. 2006;(50/6):34–48 (in Russ.).
2. Jain I.P., Lal C., Jain A. Hydrogen storage in Mg: A most promising material. International Journal of Hydrogen Energy. 2010;(35/10):5133–5144 (in Eng.).
3. Fursikov P.V., Borisov D.N., Tarasov B.P. Gidrirovanie nanostrukturirovannyh splavov i kompozitov na osnove magniâ. Izvestiâ Akademii Nauk. Seriâ himičeskaâ. 2011;(9):1816–1824 (in Russ.).
4. Poletaev A.A., Denys R.V., Solberg J.-K., Tarasov B.P., Yartys V.A. Microstructural optimization of LaMg12 alloy for hydrogen storage. Journal of Alloys and Compounds. 2011;(509/2):S633–S639 (in Eng.).
5. Poletaev A.A., Denys R.V., Maehlen J.-P., Solberg J.-K., Tarasov B.P., Yartys V.A. Nanostructured rapidly solid-ified LaMg11Ni alloy: Microstructure, crystal structure and hydrogenation properties. International Journal of Hydrogen Energy. 2012;(37/4):3548–3557 (in Eng.).
6. Denys R.V., Poletaev A.A, Maehlen J.-P., Solberg J.-K., Tarasov B.P., Yartys V.A. Nanostructured rapidly solidi-fied LaMg11Ni alloy. II. In situ synchrotron X-ray diffraction studies of hydrogen absorption–desorption behaviours. International Journal of Hydrogen Energy. 2012;(37/7):5710–5722 (in Eng.).
7. Tarasov B.P., Fursikov P.V., Borisov D.N., Lototsky M.V., Yartys V.A., Pedersen A.S. Metallography and hy-drogenation behaviour of the alloy Mg-72 mass%-Ni-20 mass%-La-8 mass%. Journal of Alloys and Compounds. 2007;(446–447):183–187 (in Eng.).
8. Webb C.J. A review of catalyst-enhanced magnesium hydride as a hydrogen storage material. Journal of Physics and Chemistry of Solids. 2015;(84):96–106 (in Eng.).
9. Friedrichs O., Klassen T., Sánchez-López J.C., Bormann R., Fernández A. Hydrogen sorption improvement of nanocrystalline MgH2 by Nb2O5 nanoparticles. Scripta Materialia. 2006;(54.7):1293–1297 (in Eng.).
10. Aguey-Zinsou K.-F., Ares Fernandez J.R., Klassen T., Bormann R. Effect of Nb2O5 on MgH2 properties during mechanical milling. International Journal of Hydrogen Energy. 2007;(32/13):2400–2407 (in Eng.).
11. Tonus F., Fuster V., Urretavizcaya G., Castro F.J., Bobet J.-L. Catalytic effect of monoclinic WO3, hexagonal WO3 and H0.23WO3 on the hydrogen sorption properties of Mg. International Journal of Hydrogen Energy. 2009;(34/8):3404–3409 (in Eng.).
12. Oelerich W., Klassen T., Bormann R. Comparison of the catalytic effects of V, V2O5, VN, and VC on the hy-drogen sorption of nanocrystalline Mg. Journal of Alloys and Compounds. 2001;(322/1–2):L5–L9 (in Eng.).
13. Borisov D.N., Fursikov P.V., Tarasov B.P. Influence of carbonaceous additives on hydrogen sorption proper-ties of Mg-RE-Ni “pseudoalloys”. International Journal of Hydrogen Energy. 2011;(36/1):1326–1329 (in Eng.).
14. Hadano M., Urushihara N., Inoue T., Uchida H. The effect of O2 preadsorption on the rate of H2 absorption on the surface of rare earths (La, Ce, Tb, Dy) at 298 K. Journal of Alloys and Compounds. 1999;(293–295):403–406 (in Eng.).
15. Oelerich W., Klassen T., Bormann R. Metal oxides as catalysts for improved hydrogen sorption in nanocrys-talline Mg-based materials. Journal of Alloys and Compounds. 2001;(315/1–2):237–242 (in Eng.).
16. Barkhordarian G., Klassen T., Bormann R. Catalytic Mechanism of Transition-Metal Compounds on Mg Hydrogen Sorption Reaction. Journal of Physical Chemistry. B. 2006;(110/22):11020–11024 (in Eng.).
17. Volodin A.A., Belmesov A.A., Murzin V.B., Fursikov P.V., Zolotarenko A.D., Tarasov B.P. Èlektroprovodâŝie kompozity na osnove oksida titana i uglerodnyh nanotrubok. Neorganičeskie materialy. 2013;(49/7):702–708 (in Russ.).
18. Volodin A.A., Fursikov P.V., Belmesov A.A., Shulga Yu.M., Hodos I.I., Abdusalyamova M.N., Tarasov B.P. Èlektroprovodnost’ kompozitov na osnove oksida lantana s dobavkami uglerodnyh nanovolokon. Neorganičeskie materialy. 2014;(50/7):726–734 (in Russ.).
19. Balboul B.A.A.A. Physicochemical characterization of the decomposition course of hydrated holmium nitrate. Thermoanalytical studies. Powder Technology. 2000;(107/1–2):168–174 (in Eng.).
20. Thompson A.C. (Eds). X-ray Data Booklet. 3rd ed. Berkeley, CA: Lawrence Berkeley National Laboratory, University of California, 2009 (in Eng.).
21. Adachi G., Imanaka N., Kang Z.C. (Eds) Binary Rare Earth Oxides. Dordrecht: Kluwer Academic Publishers, 2004 (in Eng.).
22. Abdusalyamova M.N, Kovalev I.D., Fursikov P.V., Khodos I.I., Shulga Y.M. Structural features of nanocrys-talline holmium oxide prepared by the thermal decomposition of organic precursors. Journal of Alloys and Compounds. 2014;(601):31–37 (in Eng.).
23. Lavalley J.C. Infrared spectrometric studies of the surface basicity of metal oxides and zeolites using ad-sorbed probe molecules. Catalysis Today. 1996;(27/3–4):377–401 (in Eng.).
24. Fursikov P.V., Kovalev I.D., Kovalev D.Yu., Morgunov R.B., Koplak O.V., Volodin A.A., Khodos I.I., Shulga Y.M. Structural features and magnetic behavior of nanocrystalline powders of terbium oxide prepared by the ther-mal decomposition of terbium acetate in air. Journal of Alloys and Compounds. 2016;(657):163–173 (in Eng.).
25. Toby B.H. CMPR – a powder diffraction toolkit. Journal of Applied Crystallography. 2005;(38/6):1040–1041 (in Eng.).
Review
For citations:
Fursikov P.V., Fattakhova A.M., Mozhzhukhin S.A., Blinova L.N., Taraso B.P. HYDROGEN CONTAINING COMPOSITES OF MAGNESIUM HYDRIDE WITH LANTHANIDE OXIDES. Alternative Energy and Ecology (ISJAEE). 2017;(1-3):34-45. (In Russ.) https://doi.org/10.15518/isjaee.2017.01-03.034-045
Views:
716
Email this article 