

MICRO LEVEL TWO DIMENSIONAL STRESS AND THERMAL ANALYSIS ANODE/ELECTROLYTE INTERFACE OF A SOLID OXIDE FUEL CELL
https://doi.org/10.15518/isjaee.2017.22-24.110-120
Abstract
The delamination and degradation of solid oxide fuel cells (SOFCs) electrode/electrolyte interface is estimated by calculating the stresses generated within the different layers of the cell. The stresses developed in a SOFC are usually assumed to be homogenous through a cross section in the mathematical models at macroscopic scales. However, during the operating of these composite materials the real stresses on the multiphase porous layers might be very different than those at macro-scale. Therefore micro-level modeling is needed for an accurate estimation of the real stresses and the performance of SOFC. This study combines the microstructural characterization of a porous solid oxide fuel cell anode/electrolyte with two dimensional mechanical and electrochemical ana yses to investigate the stress and the overpotential. The microstructure is determined by using focused ion beam (FIB) tomography and the resulting microstructures are used to generate a solid mesh of two dimensional triangular elements. COMSOL Multiphysics package is employed to calculate the principal stress and Maxwell Stefan Diffusion. The stress field is calculated from room temperature to operating temperature while the overpotential is calculated at operating temperature.
About the Authors
S. CelikTurkey
Mechanical Engineering Department
B. Ibrahimoglu
Turkey
Mechanical Engineering Department
M. D. Mat
Turkey
Mechanical Engineering Department
Yu. Kaplan
Turkey
Mechanical Engineering Department
T. N. Veziroglu
United States
Ph.D. in Heat Transfer, Professor, President of International Association for Hydrogen Energy
References
1. Singhal S.C., Kendall K. High temperature solid oxide fuel cells. 1st ed. 2003. Genova.
2. Staffell I., Green R. The cost of domestic fuel cell micro-CHP systems. Int. J. Hydrogen Energy, 2013;38:1088–102.
3. Celik S., Timurkutluk B., Mat M.D. Measurement of the temperature distribution in a large solid oxide fuel cell short stack. Int. J. Hydrogen Energy, 2013;38:10534–41.
4. Gostovic D., Smith J.R., Kundinger D.P., Jones K.S., Wachsman E.D. Three-dimensional reconstruction of porous LSCF cathodes. Electrochem. Solid State Lett., 2007;10:B214–7.
5. Holzer L., Muench B., Wegmann M., Gasser P., Flatt R.J. FIBnanotomography of particulate systems – part I: particle shape and topology of interfaces. J. Am. Ceram. Soc., 2006;89:2577–85.
6. Holzer L., Munch B., Iwanschitz B., Cantoni M., Hocker T., Graule T. Quantitative relationships between composition, particle size, triple phase boundary length and surface area in nickelecermet anodes for solid oxide fuel cells. J. Power Sources, 2011;196:7076–89.
7. Kanno D., Shikazono N., Takagi N., Matsuzaki K., Kasagi N. Evaluation of SOFC anode polarization simulation using three-dimensional microstructures reconstructed by FIB tomography. Electrochimica Acta, 2011;56:4015–21.
8. Shearing P.R., Cai Q., Golbert J.I., Yufit V., Adjiman C.S., Brandon N.P. Microstructural analysis of a solid oxide fuel cell anode using focused ion beam techniques coupled with electrochemical simulation. J. Power Sources, 2010;195:4804–10.
9. Vivet N., Chupin S., Estrade E., Piquero T., Pommier P.L., Rochais D., et al. 3D microstructural characterization of a solid oxide fuel cell anode reconstructed by focused ion beam tomography. J. Power Sources, 2011;196:7541–9.
10. Vivet N., Chupin S., Estrade E., Richard A., Bonnamy S., Rochais D., et al. Effect of Ni content in SOFC Ni-YSZ cermets: a three-dimensional study by FIB–SEM tomography. J. Power Sources, 2011;196:9989–97.
11. Wilson J.R., Kobsiriphat W., Mendoza R., Chen H.Y., Hiller J.M., Miller D.J., et al. Three-dimensional reconstruction of a solidoxide fuel-cell anode. Nat. Mater, 2006;5:541–4.
12. Grew K.N., Peracchio A.A., Chiu W.K.S. Char-acterization and analysis methods for the examination of the heterogeneous solid oxide fuel cell electrode micro-structure: part 2. Quantitative measurement of the micro-structure and contributions to transport losses. J. Power Sources, 2010;195:7943–58.
13. Shearing P.R., Gelb J., Brandon N.P. X-ray nano computerized tomography of SOFC electrodes using a focused ion beam sample-preparation technique. J. Eur. Ceram. Soc., 2010;30:1809–14.
14. Cronin J.S., Wilson J.R., Barnett S.A. Impact of pore microstructure evolution on polarization resistance of Niyttria-stabilized zirconia fuel cell anodes. J. Power Sources, 2011;196:2640–3.
15. Jasak H., Weller H.G. Application of the finite volume method and unstructured meshes to linear elasticity. Int. J. Numer. Meth. Eng., 2000;48:267–87.
16. Fryer Y.D., Bailey C., Cross M., Lai C.H. A control volume procedure for solving the elastic stress– strain equations on an unstructured mesh. Appl. Math. Model, 1991;15:639–45.
17. Atkinson A., Ramos T.M.G.M. Chemically-induced stresses in ceramic oxygen ion-conducting membranes. Solid State Ionics, 2000;129:259–69.
18. Radovic M., Lara-Curzio E. Mechanical properties of tape cast nickel-based anode materials for solid oxide fuel cells before and after reduction in hydrogen. Acta Mater, 2004;52:5747–56.
19. Radovic M., Lara-Curzio E. Elastic properties of nickel-based anodes for solid oxide fuel cells as a function of the fraction of reduced NiO. J. Am. Ceram. Soc., 2004;87:2242–6.
20. Wang L., Wang Y., Zhang W.Q., Sun X.G., He J.Q., Pan Z.Y., et al. Finite element simulation of stress distribution and development in 8YSZ and double-ceramic-layer La2Zr2O7/8YSZ thermal barrier coatings during thermal shock. Appl. Surf. Sci., 2012;258:3540–51.
Review
For citations:
Celik S., Ibrahimoglu B., Mat M.D., Kaplan Yu., Veziroglu T.N. MICRO LEVEL TWO DIMENSIONAL STRESS AND THERMAL ANALYSIS ANODE/ELECTROLYTE INTERFACE OF A SOLID OXIDE FUEL CELL. Alternative Energy and Ecology (ISJAEE). 2017;(22-24):110-120. (In Russ.) https://doi.org/10.15518/isjaee.2017.22-24.110-120