Preview

Alternative Energy and Ecology (ISJAEE)

Advanced search
Open Access Open Access  Restricted Access Subscription or Fee Access

Study of bıodıesel obtaıned from pomegranate seed wıth the partıcıpatıon of bentonıte modıfıed wıth CaO

https://doi.org/10.15518/isjaee.2025.08.089-099

Abstract

Given the depletion of fossil fuel raw materials, as well as the non-renewability and instability of these fuel resources, the study of alternative energy sources is currently a global challenge. At the same time, the study of renewable energy is of great importance in terms of reducing greenhouse gas emissions and air pollution. Among the various renewable energy sources, biomass (plants and their residues, waste) has attracted attention due to its potential to reduce the harmful impact of fossil fuels on the environment. Among the various fuels derived from biomass, biodiesel has great potential as a technological alternative to petroleum-based diesel fuel for green energy. Biodiesel is a renewable, sustainable, biodegradable, non-toxic, and clean energy source. Biodiesel is a diesel fuel based on long-chain alkyl esters of vegetable or animal oils and is formed by the chemical reaction of lipids with alcohol, resulting in the formation of fatty acid esters. The research involved the transesterification of oils obtained from pomegranate seeds, a waste product of AZGRANATA LLC, a company operating in Azerbaijan, into biodiesel fuel using Dash Salahli bentonite, mined in the Gazakh region of Azerbaijan and activated as a heterogeneous catalyst. The yield of biodiesel obtained as a result of the transesterification reaction carried out for 2 hours at a temperature of 220 °C with an oil to methanol molar ratio of 1:10 in the presence of a modified 5% CaO/bentonite catalyst was 93,5%. Various physicochemical properties of pomegranate seed oil, used in the production of biodiesel and obtained by cold pressing, were determined. The physicochemical properties of pomegranate seed biodiesel were analyzed using various physicochemical methods, and a comparative study was conducted to determine its compliance with the international standards ASTM D 6751 (American Society for Testing and) and EN 14214 (European standard). Its physicochemical properties were determined: density 880 kg/m³, kinematic viscosity 4,5 mm²/s, cetane number 55 and heat of combustion 40,6 MJ/kg.

About the Authors

A. B. Suleymanova
Institute of Bioresources of the Ministry of Science and Education of the Republic of Azerbaijan
Azerbaijan

Aisha Baba Suleymanova, head of the laboratory «Oils and ointments»

Az 2002, Azerbaijan, Ganja, G. Aliyev Avenue, 419



G. S. Mukhtarova
Institute of Petrochemical Processes named after Y. Mammadaliyev of the Ministry of Science and Education of the Republic of Azerbaijan
Azerbaijan

Gulbaniz Siyavush Mukhtarova, Doctor of Technical Sciences, Associate Professor, Senior Researcher at Laboratory No. 21

Az 1025, Baku, Khojaly Avenue, 30



References

1. Gurpinder S. Optimization of biodiesel production from grape seed oil using Taguchi’s orthogonal array / S. Gurpinder [et al.] // Energy Sources, Part A: Recovery, Utilization, and Environmental Effects. – 2018. – Vol. 40. – Pр. 2144-2153. https://doi.org/10.1080/15567036.2018.1495778

2. Adebayo F. A Study on Performance Evaluation of Biodiesel from Grape Seed Oil and Its Blends for Diesel Vehicles / F. Adebayo [et al.] // Vehicles. – 2021. – Vol. 3, iss. 4. – Pр. 790-806. https://doi.org/10.3390/vehicles3040047

3. Atabani A. E. Pangium edule reinw: A promising non-edible oil feedstock for biodiesel production / A. E. Atabani [et al.] // Arabian Journal for Science and Engineering. – 2014. – Vol. 40, iss. 2. – Pр. 583-94. https://doi.org/10.1007/s13369-014-1452-5.

4. Gökhan T. Emission and engine performance analysis of a diesel engine using hydrogen enriched pomegranate seed oil biodiesel / T. Gökhan [et al.] // International Journal of Hydrogen Energy. – 2017. – Vol. 43, iss. 38. – Pр. 18014-18019. https://doi.org/10.1016/j.ijhydene.2017.11.124

5. Janaun, J. Perspectives on biodiesel as a sustainable fuel / J. Janaun [et al.] // Renewable and Sustainable Energy Reviews. – 2010. – Vol. 14, iss. 4. – Pр. 1312- 1320. https://doi.org/10.1016/j.rser.2009.12.011.

6. Stauffer E. Alternative fuels in fire debris analysis: biodiesel basics / E. Stauffer [et al.] // Journal Forensic Sci. – 2007. – Vol. 52, iss. 2. – Pр. 371-379.

7. Knothe G. Kinematic viscosity of biodiesel fuel components and related compounds. Influence of compound structure and comparison to petrodiesel fuel components / G. Knothe [et al.] // Fuel. – 2005. – Vol. 84. – Pр. 1059-1065.

8. Knothe G. Dependence of biodiesel fuel properties on the structure of fatty acid alkyl esters G. Knothe / Fuel Proc Technol. – 2005. – Vol. 86. – Pр. 1059-1070.

9. Bukkarapu K. R. Predicting engine fuel properties of biodiesel and biodiesel-diesel blends using spectroscopy, based approach / K. R. Bukkarapu [et al.] // Fuel Process. Technol. – 2022. – Vol. 230. – Pр. 107227- 107239. https://doi.org/10.1016/j.fuproc.2022.107227.

10. Fereidooni L. Experimental assessment of electrolysis method in production of biodiesel from waste cooking oil using zeolite/chitosan catalyst with a focus on waste biorefinery / L. Fereidooni [et al.] // Energy Convers. Manag. – 2017. – Vol. 147. – Pр. 145-154. https://doi.org/10.1016/j.enconman.2017.05.051.

11. Wang H. A study on future energy consumption and carbon emissions of China’s transportation sector / Wang H. [et al.] // Low Carbon Economy. – 2014. – Vol. 5, iss. 04. – Pр. 133-138.

12. Subbaiah G.V. Rice bran oil biodiesel as an additive in dieselethanol blends for diesel engines / G. V. Subbaiah [et al] // International Journal of Engineering Research and Applications. – 2010. – Vol. 3. – Pр. 334-342.

13. How H. G. An investigation of the engine performance, emissions and combustion characteristics of coconut biodiesel in a high-pressure common-rail diesel engine / H. G. How [et al.] // Energy. – 2014. – Vol. 69. – Pр. 749-759. https://doi.org/10.1016/j.energy.2014.03.070.

14. Devarajan Y. Inedible oil feedstocks for biodiesel production: a review of production technologies and physicochemical properties / Y. Devarajan [et al.] // Sustain. Chem. Pharm. – 2022. – Vol. 30. – Pр. 100840- 10056.

15. Hoseinin S. S. Chemical characterization of oil and biodiesel from Common Purslane (Portulaca) seed as novel weed plant feedstock / S. S. Hoseinin [et al.] // Ind. Crop. Prod. – 2019. – Vol. 140. – P. 111582. https://doi.org/10.1016/j.indcrop.2019.111582

16. Mironeasa S. Grape seed: Physicochemical, structural characteristic and oil content / S. Mironeasa [et al.] // J. Agroaliment. Process. Technol. 2010. – Vol. 16. – Pр. 10-25.

17. Schenkel R. Investigation of the Adsorption of Methanol on Alkali Metal Cation Exchanged Zeolite X by Inelastic Neutron Scattering / R. Schenkel [et al.] // J. Phys. Chem. B. – 2004. – Vol. 108. – Pр. 7902-7910. http://dx.doi.org/10.1021/jp049819f

18. Rep M. Interaction of Methanol with Alkali Metal Exchanged Molecular Sieves. 1. IR Spectroscopic Study / M. Rep [et al.] // J. Phys. Chem. B. – 2000. – Vol. 104. – Pр. 8624-8630. https://doi.org/10.1021/jp0001945

19. Jamil F. Current scenario of catalysts for biodiesel production: a critical review / F. Jamil [et al.] // Rev. Chem. Eng. – 2018. – Vol. 34. – Pр. 267-297. https://doi.org/10.1515/revce-2016-0026

20. Yusuff A. S. Coal fly ash supported ZnO catalyzed transesterification of Jatropha curcas oil: Optimization by response surface methodology / A. S. Yusuff [et al.] // Energy Convers. Manag. – 2022. – Vol. 16. – P. 100302. https://doi.org/10.1016/j.ecmx.2022.100302

21. Tang Y. Preparation of nano-CaO and catalyzing tri-component coupling transesterification to produce biodiesel / Y. Tang [et al.] // Inorg. Nano-Met. Chem. – 2020. – Vol. 50. – Pр. 501-507. https://doi.org/10.1080/24701556.2020.1720726

22. Li H. Catalytic performance of strontium oxide supported by MIL-100(Fe) derivate as transesterification catalyst for biodiesel production / H. Li [et al.] // Energy Convers. Manag. – 2019. – Vol. 180. – Pр. 401-410. https://doi.org/10.1016/j.enconman.2018.11.012

23. Mierczynski P. Biodiesel Production on Monometallic Pt, Pd, Ru, and Ag Catalysts Supported on Natural Zeolite / P. Mierczynski [et al.] // Catal. Lett. – 2015. – Vol. 145. – Pр. 1196-1205. https://doi.org/10.3390/ma14010048

24. Isioma N. Cold Flow Properties and Kinematic Viscosity of Biodiesel / N. Isioma [et al.] // Univ. J. Chem. – 2013. – Vol. 1. – Pр. 135-141. https://doi.org/10.13189/ujc.2013.010402

25. Nurdiaputra F. Biomass-based chemical looping hydrogen production: Performance evaluation and economic viability / F. Nurdiaputra [et al.] // Int J Hydrogen Energy (IJHE). – 2025. – Vol. 183. – P. 151793. https://doi.org/10.1016/j.ijhydene.2025.151793

26. Zhang W. B. Review on analysis of biodiesel with infrared spectroscopy / W. B. Zhang // Renew. and Sust. Energy Revi. – 2012. – Vol. 16. – Pр. 6048-6058. DOI:10.1016/j.rser.2012.07.003

27. Куришбаев А. Возможности эффективного использования водных ресурсов и водородного рынка в Казахстане / А. Куришбаев [и др.] // Альтернативная энергетика и экология (ISJAEE). – 2024. – № 1. – С. 179- 207. https://doi.org/10.15518/isjaee.2024.01.179-207

28. Щуров Н. И. Моделирование и симуляция гибридного электромобиля с топливными ячейками / Н. И. Щуров [и др.] // Альтернативная энергетика и экология (ISJAEE). – 2024. – № 2. – С. 166-181. https://doi.org/10.15518/isjaee.2024.02.166-181

29. Sadeghian O. et al. Energy management of hybrid fuel cell and renewable energy based systems-A review / O. Sadeghian [et al.] // Int J Hydrogen Energy (IJHE). – 2025. – Vol. 107. – Pр. 135-163. https://doi.org/10.1016/j.ijhydene.2024.03.134

30. Li J. Research progress and applications of nickel-based catalysts for electrooxidation of urea / J. Li [et al.] // Int J Hydrogen Energy (IJHE). – 2022. – Vol. 47. – Pр. 7693-7712. https://doi.org/10.1016/j.ijhydene.2021.12.099

31. Liu Y., Zhu Q., Zhang, T., Yan X., Duan R. Analysis of chemical-looping hydrogen production and power generation system driven by solar energy / Y. Liu [et al.] // Renew Energy. – 2020. – Vol. 154. – Pр. 863-874. https://doi.org/10.1016/j.renene.2020.02.109

32. Palone O. On the reduction of NiFe/Al2 O3 oxygen carrier in high-pressure chemical looping applications / O. Palone O. [et al.] // Int J Hydrogen Energy (IJHE). – 2024. – Vol. 49. – Pр. 1304-1317. https://doi.org/10.1016/j.ijhydene.2023.09.235


Review

For citations:


Suleymanova A.B., Mukhtarova G.S. Study of bıodıesel obtaıned from pomegranate seed wıth the partıcıpatıon of bentonıte modıfıed wıth CaO. Alternative Energy and Ecology (ISJAEE). 2025;(8):89-99. (In Russ.) https://doi.org/10.15518/isjaee.2025.08.089-099

Views: 164

JATS XML

ISSN 1608-8298 (Print)