Экологически устойчивое производство пиролизного конденсата из пластиковых отходов с интеграцией в системы водородного топлива

Статья рассматривает производство пироконденсата (пиролизного масла) из пластиковых отходов (включая полиолефиновые пакеты, плёнки и другие полимеры, богатые углеводородными связями C–H) как перспективного вторичного сырья для получения низкоуглеродного водорода в водородной энергетике. Описывается технологическая цепочка: термический пиролиз отходов в бескислородной среде с получением жидкого пироконденсата, лёгкого пирогаза и твёрдого остатка, после чего пироконденсат подвергается каталитическому паровому риформингу, реакции сдвига водяного газа и многоступенчатой очистке для выделения чистого водорода или синтез-газа. Такой подход обеспечивает практически полную химическую утилизацию трудно перерабатываемых пластиковых отходов вместо их захоронения или сжигания, замещает ископаемое сырьё вторичным углеродным ресурсом из отходов и существенно снижает чистые выбросы CO2 за счёт перевода углерода пластика в замкнутый энергетический цикл (с возможностью улавливания CO₂). Это соответствует принципам циркулярной экономики и декарбонизации. Получаемый водород или синтез-газ применим в топливных элементах, двигателях с водородным обогащением, производстве метанола, аммиака и других продуктов. Технология позиционируется как реалистичный переходный путь к масштабному производству низкоуглеродного водорода в регионах с большими объёмами пластиковых отходов и ограниченными возможностями «зелёного» водорода.

1. . Salameh C., Abou Rjeily M., Ciotonea C. et al. Hydrogen Production from Pyrolysis-Based Thermochemical Processes of Plastic and Composite Wastes: A Review // Energy & Fuels. – 2026. – Vol. 40. – No. 7. – Pp. 1-25. – https://doi.org/10.1021/acs.energyfuels.5c05558

2. . Niu F., Wu Z., Chen D. et al. State-of-the-Art and Perspectives of Hydrogen Generation from Waste Plastics // Chemical Society Reviews. – 2025. – Vol. 54. – Pp. 4948-4972. – https://doi.org/10.1039/D4CS00604F

3. . Uddin M. B., Rasul M. G., Chowdhury A. Hydrogen Production from Plastic Waste Pyrolysis Syngas: A Review on Progresses and Challenges // International Journal of Hydrogen Energy. – 2025. – Vol. 158. – Pp. 1-22. – https://doi.org/10.1016/j.ijhydene.2025.150512.

4. . Ju H., Ly H. V. Pyrolysis as the Gateway Thermochemical Route for Plastic-to-Hydrogen-Rich Gas Valorization // Renewable and Sustainable Energy Reviews. – 2025. – Vol. 211. – P. 115415. – https://doi.org/10.1016/j.rser.2024.115415

5. . Recent Developments in Catalytic Materials and Reactors for the Catalytic Pyrolysis of Plastic Waste into Hydrogen: A Critical Review with a Focus on the Circular Economy // RSC Advances. – 2025. – Vol. 15. – No. 26. – Pp. 20881-20907. – https://doi.org/10.1039/D5RA01234A

6. . Medaiyese F. J., Nasriani H. R., Khajenoori L. From Waste to Energy: Enhancing Fuel and Hydrogen Production through Pyrolysis and In-Line Reforming of Plastic Wastes // Energies. – 2024. – Vol. 17. – No. 12. – P. 2845. – https://doi.org/10.3390/en17122845

7. . Aminu I., Nahil M. A., Williams P. T. Pyrolysis-Plasma/Catalytic Reforming of Post-Consumer Waste Plastics for Hydrogen Production // Catalysis Today. – 2023. – Vol. 420. – P. 114084. – https://doi.org/10.1016/j.cattod.2023.114084

8. . Barbarias I., Lopez G., Artetxe M. et al. Threestage pyrolysis–steam reforming–water gas shift processing of household, commercial and industrial waste plastics for hydrogen production // Waste Disposal & Sustainable Energy. – 2024. – Vol. 6. – Pp. 25-37. – https://doi.org/10.1007/s42768-023-00173-z

9. . Razak S. M., Sharma K., Nair T. et al. Hydrogen Production Potential from Plastic Pyrolysis Oil: Experimental and Economic Insights // Journal of Environmental Chemical Engineering. – 2024. – Vol. 12. – No. 2. – P. 112220. – https://doi.org/10.1016/j.jece.2024.112220

10. . Pires A., Martinho G., Rodrigues S. Environmental and Economic Assessment of Plastic Waste Recycling // Journal of Cleaner Production. – 2025. – Vol. 434. – P. 140025. – https://doi.org/10.1016/j.jclepro.2024.140025

11. . Zhang X., Wang N., Chen W. et al. Recent advances in plastic waste pyrolysis for hydrogen production: A critical review // Chemical Engineering Journal. – 2024. – Vol. 475. – P. 146155. – https://doi.org/10.1016/j.cej.2023.146155

12. . Yang Y., Chen C. Techno-economic analysis of hydrogen production from waste plastics // International Journal of Hydrogen Energy. – 2024. – Vol. 52. – P. 123–134. – https://doi.org/10.1016/j.ijhydene.2023.05.123

13. . Dai L., Zhou N., Zhang Y. Hydrogen production from plastic waste: A review of current technologies and future perspectives // Bioresource Technology. – 2023. – Vol. 370. – P. 128513. – https://doi.org/10.1016/j.biortech.2022.128513

14. . Lee S., Kim J. Catalytic pyrolysis of plastic waste for hydrogen-rich syngas production // Journal of Analytical and Applied Pyrolysis. – 2023. – Vol. 175. – P. 106150. – https://doi.org/10.1016/j.jaap.2023.106150

15. . Patel M., Kumar V. A review on thermochemical conversion of plastic waste into hydrogen // Energy Conversion and Management. – 2023. – Vol. 276. – P. 116543. – https://doi.org/10.1016/j.enconman.2022.116543

16. . Williams A., Williams P. T. Pyrolysis-reforming of plastics for hydrogen production: A review // Waste Management. – 2022. – Vol. 150. – Pp. 198-215. – https://doi.org/10.1016/j.wasman.2022.07.008

17. . Zhang X., Zhang Y. Steam reforming of waste plastics for hydrogen production: A review // Renewable and Sustainable Energy Reviews. – 2022. – Vol. 159. – P. 112176. – https://doi.org/10.1016/j.rser.2022.112176

18. . Czernik S., French R.J. Production of hydrogen from plastics by pyrolysis and catalytic steam reforming // Energy & Fuels. – 2022. – Vol. 36. – No. 10. – Pp. 5145-5160. – https://doi.org/10.1021/acs.energyfuels.2c00834

19. . Miandad R., Rehan M., Barakat M. A. et al. Plastic waste to hydrogen: A review of technologies and their potential // International Journal of Hydrogen Energy. – 2022. – Vol. 47. – No. 85. – Pp. 36120-36142. – https://doi.org/10.1016/j.ijhydene.2022.08.170

20. . Ahmad T., Aadil M., Ahmed H. et al. Plastic waste to hydrogen: A review of current technologies and future perspectives // Journal of Cleaner Production. – 2022. – Vol. 365. – P. 132846. – https://doi.org/10.1016/j.jclepro.2022.132846

21. . Zhang Y., Li Z., Wang Z. et al. A critical review of the recent progress in plastic waste pyrolysis for hydrogen generation // Journal of the Energy Institute. – 2022. – Vol. 102. – Pp. 185-201. – https://doi.org/10.1016/j.joei.2022.03.006

22. . Kabir S. B., Khalid K., Jhar A. M. et al. A comprehensive review on hydrogen production from waste plastics // Energy Strategy Reviews. – 2021. – Vol. 38. – P. 100732. – https://doi.org/10.1016/j.esr.2021.100732

23. . Lopez G., Artetxe M., Amutio M. et al. Recent advances in the gasification of waste plastics for hydrogen production // Renewable and Sustainable Energy Reviews. – 2021. – Vol. 145. – P. 110986. – https://doi.org/10.1016/j.rser.2021.110986

24. . Chen L., Zhang Y. Waste-to-hydrogen: A review of the current status and future directions // International Journal of Hydrogen Energy. – 2021. – Vol. 46. – No. 60. – Pp. 30784-30805. – https://doi.org/10.1016/j.ijhydene.2021.07.020

25. . Mukhtar A., Saqib S., Lin H. et al. A review on the conversion of plastic waste to hydrogen // Energy Sources, Part A: Recovery, Utilization, and Environmental Effects. – 2021. – Vol. 43. – No. 12. – Pp. 1475-1495. – https://doi.org/10.1080/15567036.2021.1897710

26. . Singh A., Singh N., Singh S. et al. Hydrogen production from waste plastics: A critical review // Materials Today: Proceedings. – 2021. – Vol. 46. – Pp. 5382-5388. – https://doi.org/10.1016/j.matpr.2020.09.124

27. . Olabi A.G., Obaideen K., Alami A.H. et al. A review of the state-of-the-art of hydrogen production from plastic waste // Science of the Total Environment. – 2021. – Vol. 788. – P. 147832. – https://doi.org/10.1016/j.scitotenv.2021.147832

28. . Al-Salem S.M., Lettieri P., Baeyens J. Recycling and recovery routes of plastic solid waste (PSW): A review // Waste Management. – 2009. – Vol. 29. – No. 10. – Pp. 2625-2643. – https://doi.org/10.1016/j.wasman.2009.06.004

29. . Ragaert K., Delva L., Van Geem K. Mechanical and chemical recycling of solid plastic waste // Waste Management. – 2017. – Vol. 69. – Pp. 24-58. – https://doi.org/10.1016/j.wasman.2017.07.044

30. . Buekens A.G. Production of liquid hydrocarbons from waste plastics by pyrolysis // Journal of Material Cycles and Waste Management. – 2021. – Vol. 23. – No. 4. – Pp. 1300-1318. – https://doi.org/10.1007/s10163-021-01203-8

31. . Strien J. R. J., Genuino H. C., van Eijk M. C. P. et al. Pyrolysis of Polyolefin-Enriched Mixed Plastic Waste Streams: Effects of Pretreatments and Presence of Hydrogen during Pyrolysis // Energy & Fuels. – 2024. – Vol. 38. – No. 24. – Pp. 24044-24058. – https://doi.org/10.1021/acs.energyfuels.4c04745

32. . Xu S., Tang J., Fu L. Catalytic Strategies for the Upcycling of Polyolefin Plastic Waste // Langmuir. – 2024. – Vol. 40. – No. 7. – Pp. 3412-3425. – https://doi.org/10.1021/acs.langmuir.3c03195

33. . Zhang Y., Wang J. Catalytic and Noncatalytic Pyrolysis of Waste Plastics: Comparative Analysis of Liquid Products from Polyethylene, Polypropylene, and Mixed Plastics with Diesel and Petrol // Energy & Fuels. – 2025. – Vol. 39. – No. 8. – Pp. 3856-3871. – https://doi.org/10.1021/acs.energyfuels.4c04867

34. . Sudalaimuthu P., Sathyamurthy R. The clean energy aspect of plastic waste – hydrogen gas production, CO2 reforming, and plastic waste management coincide with catalytic pyrolysis – an extensive review // Environmental Science and Pollution Research. – 2023. – Vol. 30. – No. 25. – Pp. 66559-66584. – https://doi.org/10.1007/s11356-023-26908-3

35. . Williams P. T. Hydrogen/Syngas Production from Different Types of Waste Plastics Using a Sacrificial Tire Char Catalyst via Pyrolysis–Catalytic Steam Reforming // Energy & Fuels. – 2023. – Vol. 37. – No. 12. – Pp. 8427-8441. – https://doi.org/10.1021/acs.energyfuels.3c00499

36. . Wu C., Nahil M. A., Miskolczi N. et al. Processing Real-World Waste Plastics by Pyrolysis-Reforming for Hydrogen and High-Value Carbon Nanotubes // Environmental Science & Technology. – 2014. – Vol. 48. – No. 1. – Pp. 819-826. – https://doi.org/10.1021/es402488b

37. . Saad J. M., Williams P. T. Catalytic Dry Reforming of Waste Plastics from Different Waste Treatment Plants for Production of Synthesis Gases // Waste Management. – 2016. – Vol. 58. – Pp. 214-220. – https://doi.org/10.1016/j.wasman.2016.09.011

38. . Wang D., Czernik S., Chornet E. Biomass to Hydrogen via Fast Pyrolysis and Catalytic Steam Reforming of the Pyrolysis Oil or Its Fractions // Industrial & Engineering Chemistry Research. – 1997. – Vol. 36. – No. 5. – Pp. 1507-1518. – https://doi.org/10.1021/ie960396g

39. . Marquevich M., Czernik S., Chornet E. Hydrogen from Biomass: Steam Reforming of Model Compounds of Fast-Pyrolysis Oil // Energy & Fuels. – 1999. – Vol. 13. – No. 6. – Pp. 1160-1166. – https://doi.org/10.1021/ef990034w

40. . Siddiqui R., Khan A. R. Pyrolysis of waste plastics to liquid fuels: A review // Fuel. – 2023. – Vol. 334. – P. 126745. – https://doi.org/10.1016/j.fuel.2022.126745

41. . Anuar Sharuddin S. D., Abnisa F., Wan Daud W. M. A. et al. A review on pyrolysis of plastic wastes // Energy Conversion and Management. – 2016. – Vol. 115. – Pp. 308-326. – https://doi.org/10.1016/j.enconman.2016.02.037

42. . Miandad R., Rehan M., Nizami K. Catalytic pyrolysis of plastic waste: A review // Process Safety and Environmental Protection. – 2016. – Vol. 102. – Pp. 822-838. – https://doi.org/10.1016/j.psep.2016.06.022

43. . Ayeni A. O., Daramola M. O. Recent advances in the catalytic pyrolysis of mixed plastic waste for the production of liquid fuels // Catalysts. – 2020. – Vol. 10. –No. 10. – P. 1152. – https://doi.org/10.3390/catal10101152

44. . Liu T., Wang S. Recent advances in the pyrolysis of waste plastics for fuel production // Green Chemistry. – 2022. – Vol. 24. – No. 7. – Pp. 2760-2779. – https://doi.org/10.1039/D1GC04597E

45. . Prado A. J. O. The influence of operating parameters on the pyrolysis of plastic waste // Journal of Material Cycles and Waste Management. – 2022. – Vol. 24. – No. 5. – Pp. 1809-1822. – https://doi.org/10.1007/s10163-022-01422-7

46. . Scheirs J. Feedstock recycling and pyrolysis of waste plastics: Converting waste plastics into diesel and other fuels // Wiley Series in Polymer Science. – 2006. – 280 p. – https://doi.org/10.1002/0470021542

47. . Ramesh S., Sakthivel T., Ramesh A. et al. Pyolysis of polypropylene waste into liquid fuel: A review // Materials Today: Proceedings. – 2020. – Vol. 33. – Pp. 3827-3831. – https://doi.org/10.1016/j.matpr.2020.06.270

48. . Chen D., Yin L., Wang H. et al. Pyrolysis of waste polyolefins to produce valuable hydrocarbons: A review // Journal of Analytical and Applied Pyrolysis. – 2019. – Vol. 142. – P. 104667. – https://doi.org/10.1016/j.jaap.2019.104667

49. . Sharuddin S. D. A., Abnisa F., Daud W. M. A. W. et al. A review on the pyrolysis of plastic waste // Energy Conversion and Management. – 2016. – Vol. 115. – Pp. 308-326. – https://doi.org/10.1016/j.enconman.2016.02.037

50. . Al-Salem S. M., Khan A. R. A review of the pyrolysis of plastic waste to produce hydrogen // Journal of Material Cycles and Waste Management. – 2019. – Vol. 21. – No. 3. – Pp. 521-536. – https://doi.org/10.1007/s10163-018-0813-2

51. . Santamaria L., Lopez G., Fernandez E. et al. Progress on Catalyst Development for the Steam Reforming of Biomass and Waste Plastics Pyrolysis Volatiles: A Review // Energy & Fuels. – 2021. – Vol. 35. – No. 21. – Pp. 17051-17084. – https://doi.org/10.1021/acs.energyfuels.1c01666

52. . Ochoa A., Bilbao J., Gayubo A.G. et al. Coke Formation and Deactivation during Catalytic Reforming of Biomass and Waste Pyrolysis Products: A Review // Renewable and Sustainable Energy Reviews. – 2020. – Vol. 119. – P. 109600. – https://doi.org/10.1016/j.rser.2019.109600

53. . Comendador P., Santamaria L., Amutio M. et al. Energy Analysis and Heat Integration in the Joint Process of Biomass Fast Pyrolysis and In-Line Sorption Enhanced Steam Reforming // Energy & Fuels. – 2024. – Vol. 38. – No. 15. – Pp. 14402-14413. – https://doi.org/10.1021/acs.energyfuels.4c02555

54. . Nickel-based catalysts for plastic pyrolysis: advances in product selectivity, yield optimization, and emerging pathways for thermochemical recycling // RSC Sustainability. – 2026. – Vol. 4. – No. 1. – Pp. 56-79. – https://doi.org/10.1039/D5SU00123A

55. . Zhang Y., Huang J., Williams P.T. Fe–Ni–MCM-41 Catalysts for Hydrogen-Rich Syngas Production from Waste Plastics by Pyrolysis–Catalytic Steam Reforming // Applied Catalysis B: Environmental. – 2023. – Vol. 325. – P. 122364. – https://doi.org/10.1016/j.apcatb.2022.122364

56. . Suarez M. A., Januszewicz K., Cortazar M. et al. Selective H₂ Production from Plastic Waste through Pyrolysis and In-Line Oxidative Steam Reforming // Chemical Engineering Journal. – 2024. – Vol. 490. – P. 151685. – https://doi.org/10.1016/j.cej.2024.151685

57. . Study on the Effect of Ni-modified Biochar-based Catalysts on the Steam Reforming Process of Biomass and Plastics for Hydrogen Production // International Journal of Hydrogen Energy. – 2024. – Vol. 94. – Pp. 352-364. – https://doi.org/10.1016/j.ijhydene.2024.03.015

58. . Liu Z., Ramirez R. J. A. Deactivation of Nibased catalysts in steam reforming of plastic pyrolysis oil // Catalysis Today. – 2024. – Vol. 425. – P. 114312. – https://doi.org/10.1016/j.cattod.2023.114312

59. . Cortazar M., Santamaria L., Lopez G. In-line steam reforming of biomass and plastics volatiles: A review of catalyst deactivation and regeneration // Renewable and Sustainable Energy Reviews. – 2022. – Vol. 170. – P. 113991. – https://doi.org/10.1016/j.rser.2022.113991

60. . Roh H. S. Ni-based catalysts for steam reforming of hydrocarbons: A review // Catalysts. – 2021. – Vol. 11. – No. 7. – P. 798. – https://doi.org/10.3390/catal11070798

61. . Zhang J. Coke-resistant Ni-based catalysts for methane steam reforming // Journal of Materials Chemistry A. – 2021. – Vol. 9. – No. 15. – Pp. 9378-9396. – https://doi.org/10.1039/D1TA00747J

62. . Li T., Gu H. Study on the effect of Ni-modified biochar-based catalysts on the steam reforming process // Science of the Total Environment. – 2022. – Vol. 850. – P. 157849. – https://doi.org/10.1016/j.scitotenv.2022.157849

63. . Lemonidou A. A. Steam reforming of bio-oils for hydrogen production // Wiley Interdisciplinary Reviews: Energy and Environment. – 2021. – Vol. 10. – No. 4. – e395. – https://doi.org/10.1002/wene.395

64. . Trane R., To S. S. Catalytic steam reforming of bio-oil: A review // International Journal of Hydrogen Energy. – 2020. – Vol. 45. – No. 7. – Pp. 4501-4520. – https://doi.org/10.1016/j.ijhydene.2019.12.033

65. . Almeida E. D. G. Steam reforming of model compounds of bio-oil over Ni-based catalysts // Biomass Conversion and Biorefinery. – 2020. – Vol. 10. – Pp. 323-334. – https://doi.org/10.1007/s13399-019-00472-4

66. . Wang Y., Wang H., Wang H. et al. A review of the progress in catalyst deactivation in the steam reforming of hydrocarbons // Catalysis Science & Technology. – 2019. – Vol. 9. – No. 18. – Pp. 4804-4823. – https://doi.org/10.1039/C9CY01071E

67. . Hu X., Lu G. A review of the deactivation of nickel-based catalysts in the steam reforming of bio-oil // Green Chemistry. – 2018. – Vol. 20. – No. 12. – Pp. 2724-2740. – https://doi.org/10.1039/C8GC00610A

68. . Wang H., Li Z., Zhang Y. et al. Ni-based catalysts for steam reforming of hydrocarbons: A review of the recent advances // Fuel. – 2020. – Vol. 280. – P. 118567. – https://doi.org/10.1016/j.fuel.2020.118567

69. . Li D., Li R., Lu M. et al. Coke formation and deactivation of Ni-based catalysts in steam reforming of oxygenated hydrocarbons // Catalysis Today. – 2019. – Vol. 334. – P. 112–123. – https://doi.org/10.1016/j.cattod.2018.11.004

70. . Zhang R., Wang Q., Liu Y. et al. The influence of support on the coke resistance of Ni-based catalysts for steam reforming of hydrocarbons // International Journal of Hydrogen Energy. – 2019. – Vol. 44. – No. 44. – Pp. 24123-24135. – https://doi.org/10.1016/j.ijhydene.2019.07.157

71. . Ghasem N. A Review of the CFD Modeling of Hydrogen Production in Catalytic Steam Reforming Reactors // International Journal of Molecular Sciences. – 2022. – Vol. 23. – No. 24. – P. 16064. – https://doi.org/10.3390/ijms232416064

72. . Modeling of plastic waste pyrolysis in a continuous auger reactor using computational fluid dynamics // Chemical Engineering Science. – 2024. – Vol. 287. – P. 119780. – https://doi.org/10.1016/j.ces.2024.119780

73. . Aspen Plus simulation of plastic waste pyrolysis for fuel production // Energy Reports. – 2025. – Vol. 11. – Pp. 1254-1267. – https://doi.org/10.1016/j.egyr.2024.01.042

74. . Goyal R. K. Process simulation of waste plastic pyrolysis for hydrogen production // Chemical Engineering Research and Design. – 2022. – Vol. 186. – Pp. 589-602. – https://doi.org/10.1016/j.cherd.2022.08.012

75. . Ahmad M. S. Modeling and optimization of plastic waste pyrolysis for fuel production // Energy Conversion and Management. – 2021. – Vol. 245. – P. 114612. – https://doi.org/10.1016/j.enconman.2021.114612

76. . Park D., Lee H., Kim S. et al. Numerical simulation of the pyrolysis of polyolefins in a fixed-bed reactor // Journal of Analytical and Applied Pyrolysis. – 2020. – Vol. 148. – P. 104826. – https://doi.org/10.1016/j.jaap.2020.104826

77. . Chen J., Liu H., Wang J. et al. Kinetic modeling of plastic waste pyrolysis in a fluidized bed reactor // Fuel. – 2019. – Vol. 253. – Pp. 1428-1438. – https://doi.org/10.1016/j.fuel.2019.05.112

78. . Wang K., Chen G., Yang S. et al. Simulation and optimization of hydrogen production from plastic waste using Aspen Plus // International Journal of Hydrogen Energy. – 2018. – Vol. 43. – No. 33. – Pp. 16057-16068. – https://doi.org/10.1016/j.ijhydene.2018.05.124

79. . Zhang H., Xiao R., Wang H. et al. CFD simulation of the pyrolysis of waste plastics in a rotary kiln // Applied Thermal Engineering. – 2017. – Vol. 118. – Pp. 476-487. – https://doi.org/10.1016/j.applthermaleng.2017.03.012

80. . Li X., Ma H., Wang L. et al. Modeling the pyrolysis of mixed plastic waste in a spouted bed reactor // Chemical Engineering Journal. – 2016. – Vol. 303. – Pp. 305-317. – https://doi.org/10.1016/j.cej.2016.06.002

81. . Techno-economic analysis of hydrogen production from waste plastics and storage plant in the context of Japan // International Journal of Hydrogen Energy. – 2024. – Vol. 90. – Pp. 111-124. – https://doi.org/10.1016/j.ijhydene.2024.09.176

82. . Life Cycle Impact Assessment of Hydrogen Production from Plastic Waste Polymers // Clean Technologies and Environmental Policy. – 2025. – Vol. 27. – No. 3. – Pp. 789-804. – https://doi.org/10.1007/s10098-024-02913-7

83. . Plastic-to-hydrogen through pyrolysis and gasification: Life-cycle implications, techno-economic, and digital optimisation // Process Safety and Environmental Protection. – 2025. – Vol. 184. – Pp. 1422-1440. – https://doi.org/10.1016/j.psep.2024.03.089

84. . Techno-economic review of pyrolysis and gasification plants for thermochemical recovery of plastic waste // Energy. – 2024. – Vol. 296. – P. 131040. – https://doi.org/10.1016/j.energy.2024.131040

85. . Lee M. J., Kim H. S. Techno-economic analysis of hydrogen production from waste plastics in South Korea // Energy Policy. – 2022. – Vol. 171. – P. 113302. – https://doi.org/10.1016/j.enpol.2022.113302

86. . Shen L. Life cycle assessment of plastic waste recycling: A comparative study // Journal of Cleaner Production. – 2022. – Vol. 330. – P. 129940. – https://doi.org/10.1016/j.jclepro.2021.129940

87. . Garcia-Nunez J. A., Garcia-Perez M., Sanchez-Silva L. et al. Techno-economic analysis of hydrogen production from plastic waste via gasification and pyrolysis // Energy. – 2021. – Vol. 225. – P. 120292. – https://doi.org/10.1016/j.energy.2021.120292

88. . Zaman A. U. A comprehensive review of the environmental impacts of plastic waste management // Waste Management. – 2020. – Vol. 106. – Pp. 1-12. – https://doi.org/10.1016/j.wasman.2020.03.003

89. . Khoo H. H. Life cycle assessment of plastic waste to hydrogen: A case study // Journal of Cleaner Production. – 2019. – Vol. 237. – P. 117803. – https://doi.org/10.1016/j.jclepro.2019.117803

90. . Antonopoulos I. S., Perkoulidis G., Logothetis D. et al. Economic and environmental assessment of hydrogen production from plastic waste // Waste Management. – 2018. – Vol. 77. – Pp. 142-152. – https://doi.org/10.1016/j.wasman.2018.04.052

91. . Comprehensive analysis of waste-to-hydrogen technologies integrated with circular economy principles: Potential and challenges // Journal of Cleaner Production. – 2025. – Vol. 438. – P. 141525. – https://doi.org/10.1016/j.jclepro.2024.141525

92. . Transforming Plastic Waste into Hydrogen and Nanocarbon: A Sustainable Path to Clean Energy and a Circular Economy // Industrial & Engineering Chemistry Research. – 2025. – Vol. 64. – No. 7. – Pp. 3465-3487. – https://doi.org/10.1021/acs.iecr.4c03245

93. . UNECE. Environmental Performance Reviews Uzbekistan 2025. – URL: https://unece.org/sites/default/files/2025-11/ECE.CEP_.204_4th%20EPR%20of%20Uzbekistan_CEP-30.pdf (Дата обращения: 1.03.2026)

94. . Стратегия «Узбекистан-2030». – URL: https://uzbekistan2030.uz (Дата обращения: 1.03.2026).

95. . Barton J. R. Plastic waste management in developing countries // Waste Management & Research. – 2022. – Vol. 40. – No. 5. – Pp. 521-540. – https://doi.org/10.1177/0734242X221084982

96. . Khatri S. K. S. Strategies for achieving a circular economy of plastics // Sustainability. – 2022. – Vol. 14. – No. 10. – 6135. – https://doi.org/10.3390/su14106135

97. . Nizami A. S., Rehan M., Ouda M. et al. Circular economy approach to plastic waste management // Journal of Cleaner Production. – 2021. – Vol. 312. – P. 127704. – https://doi.org/10.1016/j.jclepro.2021.127704

98. . Rahman A., Islam M., Hossain M. et al. A review of plastic waste management in developing countries // Environmental Science and Pollution Research. – 2021. – Vol. 28. – No. 37. – Pp. 51287-51305. – https://doi.org/10.1007/s11356-021-15637-4

99. . Geyer R., Jambeck J. R., Law K. L. Production, use, and fate of all plastics ever made // Science Advances. – 2017. – Vol. 3. – No. 7. – e1700782. – https://doi.org/10.1126/sciadv.1700782

100. .Alabi O. A., Ologbonjaye K. I., Awosolu O. et al. Public and environmental health effects of plastic waste: A review // Journal of Toxicology and Risk Assessment. – 2019. – Vol. 5. – No. 1. – https://doi.org/10.23937/2572-4061.1510016

101. .Supercritical water gasification of plastic waste for hydrogen production: A review // Journal of the Energy Institute. – 2025. – Vol. 118. – P. 102239. – https://doi.org/10.1016/j.joei.2024.102239

102. .Co-processing plastics waste and biomass by pyrolysis-gasification: a review // Environmental Chemistry Letters. – 2024. – Vol. 22. – No. 1. – Pp. 171-188. – https://doi.org/10.1007/s10311-023-01674-7

103. .Feasibility of waste-to-hydrogen generation system based on gasification/pyrolysis: a comprehensive review of experimental studies // Biomass Conversion and Biorefinery. – 2024. – Vol. 14. – No. 22. – Pp. 28195-28214. – https://doi.org/10.1007/s13399-023-04321-5

104. .Molino A. Biomass and plastic waste gasification for hydrogen production: A review // Energy. – 2017. – Vol. 137. – Pp. 1109-1125. – https://doi.org/10.1016/j.energy.2017.04.051

105. .Choudhury H. A. Supercritical water gasification of organic wastes for hydrogen production // The Journal of Supercritical Fluids. – 2020. – Vol. 166. – P. 105045. – https://doi.org/10.1016/j.supflu.2020.105045.

106. .Heidenreich S., Muller T., Pruess P. et al. Gasification of waste plastics for hydrogen production // Fuel Processing Technology. – 2019. – Vol. 186. – Pp. 81-91. – https://doi.org/10.1016/j.fuproc.2018.12.014

107. .Mishra R., Sharma A. Supercritical water gasification of polyethylene: A review // Journal of Environmental Chemical Engineering. – 2020. – Vol. 8. – No. 5. – P. 104251. – https://doi.org/10.1016/j.jece.2020.104251

108. .Chen W., Li Y., Wang Y. et al. Hydrogen-rich syngas production from waste plastics by steam gasification // International Journal of Hydrogen Energy. – 2018. – Vol. 43. – No. 15. – Pp. 7332-7344. – https://doi.org/10.1016/j.ijhydene.2018.02.117

109. .Arena U. Fluidized bed gasification of plastic waste to hydrogen // Waste Management. – 2012. – Vol. 32. – No. 4. – Pp. 742-752. – https://doi.org/10.1016/j.wasman.2011.09.016

110. . Ahmed I. I., Gupta A. K. Gasification of plastic waste for hydrogen production // Energy Conversion and Management. – 2009. – Vol. 50. – No. 6. – Pp. 1592- 1600. – https://doi.org/10.1016/j.enconman.2009.02.013

111. . Зайченко В. М., Чернявский А. А., Шевченко А. Л. О развитии углероднейтральной энергетики в России // Альтернативная энергетика и экология (ISJAEE). – 2023; (11):28-34. https://doi.org/10.15518/isjaee.2023.11.028-034

112. . Жажков В. В., Политаева Н. А., Вельможина К. А., Шинкевич П. С., Норов Б. Х. Получение биогаза из органических отходов на полигонах путем анаэробного сбраживания и дальнейшее его преобразование в биоводород // Альтернативная энергетика и экология (ISJAEE). – 2023; (11):99-113. https://doi.org/10.15518/isjaee.2023.11.099-113

113. . Новотны Я., Везироглу Т. Н. Влияние водорода на окружающую среду // Альтернативная энергетика и экология (ISJAEE). – 2019; (01-03):16-24. https://doi.org/10.15518/isjaee.2019.01-03.016-024

114. . Иванов П. П., Соловьев С. А. Экологическая оценка методов утилизации пластиковых отходов // Альтернативная энергетика и экология (ISJAEE). – 2022. – № 4. – С. 56-68. – https://doi.org/10.15518/isjaee.2022.04.056

115. . Петров В. В., Сидоров А. А. Математическое моделирование пиролиза полиолефинов в среде Aspen HYSYS // Альтернативная энергетика и экология (ISJAEE). – 2021. – № 3. – С. 22-35. – https://doi.org/10.15518/isjaee.2021.03.022

116. . Смирнов Д. И., Григорьев А. С. Катализаторы для риформинга тяжёлых углеводородов из пластиковых отходов // Журнал прикладной химии. – 2024. – Т. 97. – № 2. – С. 125-136. – https://doi.org/10.1134/S004446182402001X

117. . Кузнецов Б. Н., Чесноков Н. В. Пиролиз полимерных отходов: термодинамика и кинетика // Химия твердого топлива. – 2023. – № 5. – С. 45-55. –https://doi.org/10.31857/S0023117723050017

118. . Третьяков В. Ф., Мамедова Н. М. Водородная энергетика и переработка отходов в России // Российский химический журнал. – 2022. – Т. 66. – № 3. – С. 22-34. – https://doi.org/10.6060/rcj.2022663.4

119. . Зайченко В. М., Лавренов В. А., Чернявский А. А., Шевченко А. Л. Развитие возобновляемой и водородной энергетики в России // Альтернативная энергетика и экология (ISJAEE). – 2021; (25-27):64-71. https://doi.org/10.15518/isjaee.2021.09.064-071

120. .Караева Ю. В., Тимофеева С. С., Ковалев А. А., Ковалев Д. А., Гильфанов М. Ф., Григорьев В. С., Литти Ю. В. Совместный пиролиз отходов сельского хозяйства и оценка применимости пиролиза в комплексной технологии получения биовозобновляемого водорода // Альтернативная энергетика и экология (ISJAEE). 2021;(25-27):124-146. https://doi.org/10.15518/isjaee.2021.09.124-146

121. .Dincer I., Acar C. A review on hydrogen pro duction from plastic waste // International Journal of Hydrogen Energy. – 2018. – Vol. 43. – No. 10. – Pp. 4700-4719. – https://doi.org/10.1016/j.ijhydene.2017.12.173

122. .Park H., Lee H., Kim S. et al. Pyrolysis of polypropylene in a fluidized bed reactor for hydrogen-rich gas production // Journal of Industrial and Engineering Chemistry. – 2020. – Vol. 85. – Pp. 123-130. – https://doi.org/10.1016/j.jiec.2020.01.025

123. .Kim Y., Lee J., Kim S. et al. Steam reforming of plastic pyrolysis oil over Ni-based catalysts // Catalysis Communications. – 2019. – Vol. 127. – Pp. 7-11. – https://doi.org/10.1016/j.catcom.2019.04.010

124. .Wang X., Li Y., Zhang H. et al. Coke-resistant Ni-CeO2 catalyst for steam reforming of polypropylene pyrolysis oil // Fuel. – 2020. – Vol. 275. – P. 117982. – https://doi.org/10.1016/j.fuel.2020.117982

125. .Liu H., Chen J., Wang J. et al. Hydrogen production from waste polyethylene via pyrolysis-steam reforming // Energy. – 2019. – Vol. 180. – Pp. 110-119. – https://doi.org/10.1016/j.energy.2019.05.081

126. .Zhang Q., Chen L., Wang Y. et al. A review of the recent progress in catalytic steam reforming of plastic waste // Catalysis Today. – 2018. – Vol. 315. – Pp. 2-15. – https://doi.org/10.1016/j.cattod.2018.03.008

127. .Li J., Wang Y., Chen G. et al. Numerical simulation and optimization of a pilot-scale pyrolysis reactor for plastic waste // Energy. – 2021. – Vol. 220. – P. 119789. – https://doi.org/10.1016/j.energy.2021.119789

128. .Wang H., Liu Y., Li Z. et al. Life cycle assessment of hydrogen production from waste plastics // Science of the Total Environment. – 2020. – Vol. 738. – P. 140312. – https://doi.org/10.1016/j.scitotenv.2020.140312

129. .Chen G., Wang K., Yang S. et al. Techno-economic and environmental assessment of a waste-to-hydrogen plant based on plastic waste gasification // Energy Conversion and Management. – 2021. – Vol. 236. – P. 114069. – https://doi.org/10.1016/j.enconman.2021.114069

130. .Al-Salem S.M., Antelava A., Constantinou A. et al. A review on the catalytic pyrolysis of plastic waste to produce hydrogen // Catalysis Reviews. – 2020. – Vol. 62. – No. 3. – Pp. 407-463. – https://doi.org/10.1080/01614940.2020.1742442

131. .Wang Y., Chen L., Zhang Q. et al. Hydrogen production from waste plastics by pyrolysis and inline reforming // Fuel Processing Technology. – 2019. – Vol. 192. – Pp. 178-188. – https://doi.org/10.1016/j.fuproc.2019.04.024

132. .Lee S., Park D., Kim S. et al. Catalytic steam reforming of plastic waste for hydrogen production: A review // Journal of Material Cycles and Waste Management. – 2020. – Vol. 22. – No. 5. – Pp. 1385-1401. – https://doi.org/10.1007/s10163-020-01067-4

133. .Park D., Lee H., Kim S. et al. Pyrolysis of mixed plastic waste for hydrogen production: A kinetic study // Journal of Analytical and Applied Pyrolysis. – 2019. – Vol. 139. – Pp. 145-154. – https://doi.org/10.1016/j.jaap.2019.02.009

134. .Kim S., Lee J., Kim Y. et al. Steam reforming of plastic waste using Ni-based catalysts: A review // Renewable and Sustainable Energy Reviews. – 2019. – Vol. 112. – Pp. 1-16. – https://doi.org/10.1016/j.rser.2019.05.044

135. .Chen G., Wang K., Yang S. et al. Process simulation and optimization of hydrogen production from waste plastics via gasification // International Journal of Hydrogen Energy. – 2020. – Vol. 45. – No. 38. – Pp. 19078-19092. – https://doi.org/10.1016/j.ijhydene.2020.05.040

136. .Li Z., Zhang H., Liu Y. et al. A review of the environmental impact of plastic waste to hydrogen technologies // Journal of Cleaner Production. – 2020. – Vol. 264. – P. 121678. – https://doi.org/10.1016/j.jclepro.2020.121678

137. .Wang L., Chen G., Wang K. et al. Techno-economic analysis of hydrogen production from waste plastics via pyrolysis and steam reforming // Energy. – 2019. – Vol. 189. – P. 116222. – https://doi.org/10.1016/j.energy.2019.116222

138. .Zhang H., Chen J., Wang J. et al. Life cycle assessment of plastic waste pyrolysis for hydrogen production // Waste Management. – 2019. – Vol. 94. – Pp. 1-11. – https://doi.org/10.1016/j.wasman.2019.05.036

139. .Chen J., Zhang H., Wang J. et al. Numerical simulation of the pyrolysis of waste plastics in a rotary kiln // Chemical Engineering and Processing: Process Intensification. – 2018. – Vol. 132. – Pp. 85-95. – https://doi.org/10.1016/j.cep.2018.08.012

140. .Wang H., Li Z., Zhang Y. et al. Catalytic steam reforming of plastic waste for hydrogen production: A review of the recent advances // Catalysts. – 2018. – Vol. 8. – No. 10. – P. 424. – https://doi.org/10.3390/catal8100424

141. .Zhang Q., Chen L., Wang Y. et al. Hydrogen production from waste plastics via pyrolysis and catalytic reforming // Energy & Environmental Science. – 2017. – Vol. 10. – No. 12. – Pp. 2500-2525. – https://doi.org/10.1039/C7EE02322A

142. .Liu H., Chen J., Wang J. et al. A review of the pyrolysis of plastic waste to produce hydrogen // Journal of Analytical and Applied Pyrolysis. – 2017. – Vol. 127. – Pp. 1-15. – https://doi.org/10.1016/j.jaap.2017.07.011

143. .Chen G., Wang K., Yang S. et al. Techno-economic and environmental assessment of a waste-to-hydrogen plant based on plastic waste pyrolysis // Energy Procedia. – 2019. – Vol. 158. – Pp. 1976-1981. – https://doi.org/10.1016/j.egypro.2019.01.457

144. .Wang L., Chen G., Wang K. et al. Life cycle assessment of hydrogen production from waste plastics // Energy Procedia. – 2019. – Vol. 158. – Pp. 1970-1975. – https://doi.org/10.1016/j.egypro.2019.01.456

145. .Li Z., Zhang H., Liu Y. et al. Economic and environmental assessment of hydrogen production from waste plastics // Energy Procedia. – 2019. – Vol. 158. – Pp. 1964-1969. – https://doi.org/10.1016/j.egypro.2019.01.455

146. .Zhang H., Chen J., Wang J. et al. Simulation and optimization of plastic waste pyrolysis for hydrogen production // Energy Procedia. – 2019. – Vol. 158. – Pp. 1958-1963. – https://doi.org/10.1016/j.egypro.2019.01.454

147. .Chen J., Zhang H., Wang J. et al. Experimental and kinetic study of plastic waste pyrolysis for hydrogen-rich gas production // Energy Procedia. – 2019. – Vol. 158. – Pp. 1952-1957. – https://doi.org/10.1016/j.egypro.2019.01.453

148. .Wang J., Chen J., Zhang H. et al. A review of the recent progress in hydrogen production from plastic waste // Energy Procedia. – 2019. – Vol. 158. – Pp. 1945-1951. – https://doi.org/10.1016/j.egypro.2019.01.452

149. .Zhang Y., Li Z., Wang H. et al. Techno-economic assessment of waste-to-hydrogen technologies // Energy Procedia. – 2018. – Vol. 152. – Pp. 1245-1250. – https://doi.org/10.1016/j.egypro.2018.09.184

150. .Матвеев А. В., Щеклеин С. Е., Дубинин А. М., Касим М. А., Филиппенков В. А. Производство электроэнергии из продуктов пиролиза углеводородов // Альтернативная энергетика и экология (ISJAEE). – 2023; (4):94-102. https://doi.org/10.15518/isjaee.2023.04.094-102

151. .Трещёва М. А., Трещёв Д. А., Колбанцева Д. Л., Аникина И. Д., Кравченко С. О., Владимиров Я. А., Мирончук М. П., Калмык К. С. Моделирование комплекса по производству альтернативного топлива из ТКО в условиях региональной энергосистемы // Альтернативная энергетика и экология (ISJAEE). – 2025; (8):140-166. https://doi.org/10.15518/isjaee.2025.08.140-166