

LITHIUM-IRON-PHOSPHATE-BASED BATTERIES: MATERIALS, PROCESSES, CHARACTERISTICS AND PRODUCTION EXPERIENCE IN RUSSIA
https://doi.org/10.15518/isjaee.2016.01-02.007
Abstract
The paper analyses the establishment of mass production of lithium-iron-phosphate-based batteries in Liotech Co., Ltd. (Novosibirsk) and studies the electrochemical characteristics of LT-LFP 300 model of batteries. Irreversible capacity for the batteries in the first (formation) cycle was the permissible value of 16.8%. The increase in normalized discharge current within 0.2 to 1.5 С interval had only little effect on the discharge capacity of LT-LFP 300. The discharge capacity of the batteries was virtually unchanged within the temperature range 0 оC to +50 оC while it reasonable declined with temperature decrease below 0 oC. Nevertheless, the LT-LFP 300 batteries demonstrated discharge capacity about ~67% even at –40 оC. When the temperature was increased again to positive values, full recovery of the former values of discharge capacity was observed. After 500 cycles at the normalized discharge current of 0.2 С with discharge depth of ≤80%, the discharge capacity of LT-LFP 300 gradually stabilized at the level of 85-90% in respect to initial value. Operational characteristics of the LT-LFP 300 batteries comply with similar products of other world companies. The lithium-iron-phosphate-based batteries produced by “Liotech” Co., Ltd. were successfully tried as an autonomous power supply in electric vehicles and stationary energy storage systems.
About the Authors
Yu. A. DobrovolskyRussian Federation
D.Sci. (Chemistry), Professor, Head of Department of IPCP RAS
O. V. Bushkova
Russian Federation
D.Sci. (Chemistry), Chief Researcher of IHTE UB RAS
K. K. Denshchikov
Russian Federation
D.Sci. (Engineering), Chief Researcher of Joint Institute for High Temperatures, RAS
E. A. Chudinov
Russian Federation
D. Sci. (Engineering), Professor, Chief Designer of Liotech-Innovation Ltd
References
1. Daniel C., Mohanty D., Li J., Wood D.L. Cathode materials review. AIP Conf. Proc., 2014, vol. 1597, pp. 26–43 (in Eng.).
2. Cherkouk C., Nestler T. Cathodes – Technological review. AIP Conf. Proc., 2014, vol. 1597, pp. 134– 145 (in Eng.).
3. Zaghib K., Guerfi A., Hovington P. et al. Review and analysis of nanostructured olivine-based lithium re-cheargeable batteries: Status and trends. J. Power Sources, 2013, vol. 232, pp. 357–369 (in Eng.).
4. Liu D., Zhu W., TrottierJ. et al. Spinel materials for high-voltage cathodes inLi-ion batteries. RSC Adv., 2014, vol. 4, pp. 154–167 (inEng.).
5. Chen J. Recent progress in advanced materials for lithium ion batteries. Materials, 2013, vol. 6, pp. 156–183 (in Eng.).
6. Myung S.-T., Amine K., Sun Y.-K. Nanostructured cathode materials for rechargeable lithium batteries. J. Power Sources, 2015, vol. 283, pp. 219–236 (in Eng.).
7. Hu M., Pahg X., Zhou Z. Recent progress in high-voltage lithium ion batteries. J. Power Sources, 2013, vol. 237, pp. 229–242 (in Eng.).
8. Nitta N., Wu F., Lee J.T. et al. Li-ion battery materials: present and Future. Materials Today, 2015, vol. 18, no. 5, pp. 252–264 (in Eng.).
9. Deng S., Wang H., Liu H. et al. Research progress in improving the rate performance of LiFePO4 cathode materials. Nano-Micro Letters, 2014, vol. 6, no. 3, pp. 209–226 (in Eng.).
10. 10 Amine K., Kanno R., Tzeng Y. Rechargeable lithium batteries and beyond: Progress, challenges, and future directions. MRS Bull., 2014, vol. 39, pp. 395–401 (in Eng.).
11. Sauvage F., Baudrin E., Laffont L. et al. Origin of electrochemical reactivity enhancement of post-annealed LiFePO4 thin films: Preparation of heterosite-type FePO4. Solid State Ionics, 2007, vol. 178, pp. 145– 152 (in Eng.).
12. Fergus J.W. Recent developments in cathode materials for lithium ion batteries. J. Power Sources, 2010, vol. 195, pp. 939–954 (in Eng.).
13. Balakrishnan P.G., Ramesh R., Prem Kumar T. Safety mechanisms in lithium-ion batteries. J. Power Sources, 2006, vol. 155, pp. 401–414 (in Eng.).
14. Padhi A. K., Nanjundaswamy K. S., Masquelier C. et al. Effect of structure on the Fe3 +/ Fe2 + redox couple in iron phosphates. J. Electrochem. Soc., 1997, vol. 144, no. 5, pp. 1609–1613 (in Eng.).
15. Winter M., Moeller K.-C., Besenhard J.O. Carbonaceous and graphitic anodes / In: Lithium Batteries. Science and Technology. Ed. By G.-A. Nazri. Kluwver Academic Publishers, Boston-Dordrecht-New York-London, 2004, pp. 144–194 (in Eng.).
16.
Review
For citations:
Dobrovolsky Yu.A., Bushkova O.V., Denshchikov K.K., Chudinov E.A. LITHIUM-IRON-PHOSPHATE-BASED BATTERIES: MATERIALS, PROCESSES, CHARACTERISTICS AND PRODUCTION EXPERIENCE IN RUSSIA. Alternative Energy and Ecology (ISJAEE). 2016;(1-2):64-75. (In Russ.) https://doi.org/10.15518/isjaee.2016.01-02.007