Preview

Alternative Energy and Ecology (ISJAEE)

Advanced search
Open Access Open Access  Restricted Access Subscription or Fee Access

INFLUENCE OF THE NATURE OF SUBSTITUENT ION (F- , Cl- ) ON ELECTROCONDUCTIVITY OF BROWNMILLERITES BASED ON BARIUM INDATE

https://doi.org/10.15518/isjaee.2016.07-08.038-042

Abstract

In this article, the temperature dependencies of conductivity for fluorine- and chlorine-substituted complex oxides based on barium indate were obtained. The influence of the nature of the halogen and concentration of dopant on the conductivity was determined. 

About the Authors

N. A. Tarasova
Ural Federal University named after the first President of Russia B.N. Yeltsin
Russian Federation

19, Mir str., Yekaterinburg, 620002, Russia

tel.: +7(343)261-74-70

Information about the author: Ph.D. (chemistry), associate professor, Ural Federal University named after the first President of Russia B.N. Yeltsin.

Education: Ural Federal University named after the first President of Russia B.N. Yeltsin, chemist.

Research area: high-temperature proton conductivity in complex oxides.

Publications: 74.



I. E. Animitsa
Ural Federal University named after the first President of Russia B.N. Yeltsin
Russian Federation

19, Mir str., Yekaterinburg, 620002, Russia

tel.: +7(343)261-74-70

Information about the author: D.Sc. (chemistry), professor, Ural Federal University named after the first President of Russia B.N.Yeltsin.

Education: Ural State University, chemist.

Research area: high-temperature proton conductivity in complex oxides.

Publications: 216.



E. D. Pilshchikova
Ural Federal University named after the first President of Russia B.N. Yeltsin
Russian Federation

19, Mir str., Yekaterinburg, 620002, Russia

tel.: +7(343)261-74-70

Information about the author: postgraduate, Ural Federal University named after the first President of Russia B.N. Yeltsin.

Education: Ural Federal University named after the first President of Russia B.N. Yeltsin, chemist.

Research area: high-temperature proton conductivity in complex oxides.

Publications: 8.



A. V. Obrubova
Ural Federal University named after the first President of Russia B.N. Yeltsin
Russian Federation

19, Mir str., Yekaterinburg, 620002, Russia

tel.: +7(343)261-74-70

Information about the author: postgraduate, Ural Federal University named after the first President of Russia B.N. Yeltsin.

Education: Ural Federal University named after the first President of Russia B.N. Yeltsin, chemist.

Research area: high-temperature proton conductivity in complex oxides.

Publications: 6.



References

1. Kharton V.V., Marques F.M.B., Atkinson A. Transport properties of solid oxide electrolyte ceramics: a brief review // Solid State Ionics. 2004. Vol. 174. P. 135–149.

2. Thangadurai V., W. Weppner Recent progress in solid oxide electrolytes research // Ionics. 2006. Vol. 12. P. 81–92.

3. Jayaraman V., Magrez A., Caldes M., Joubert O., Ganne M., Piffard Y., Brohan L. Characterization of perovskite systems derived from Ba2In2O5. Part I: the oxygen-deficient Ba2In2(1-x)Ti2xO5+x (0 ≤ x ≤ 1) compounds // Solid State Ionics. 2004. Vol. 170. P. 17–24.

4. Jayaraman V., Magrez A., Caldes M., Joubert O., Taulelle F., Rodriguez-Carvajal J., Piffard Y., Brohan L. Characterization of perovskite systems derived from Ba2In2O5. Part II: The proton compounds Ba2In2(1-x)Ti2xO4+2x(OH)y [0 ≤x≤1; y≤2(1-x)] // Solid State Ionics. 2004. Vol. 170. P. 25–35.

5. Rolle A., Vannier R.N., Giridharan N.V., Abraham F.Structural and electrochemical characterization of new oxide ion conductors for oxygen generating systems and fuel cells // Solid State Ionics. 2005. Vol. 176. P. 2095– 2103.

6. Animitsa I., Tarasova N., Filinkova Ya. Electrical properties of the fluorine-doped Ba2In2O5 // Solid State Ionics. 2012. Vol. 207. P. 29.

7. Yamamura H., Yamada Y., Toshiyuki M., Tooru A. Order-disorder transition of oxygen vacancy in brawnmillerite system // Solid State Ionics. 1998. Vol. 108. P. 377–381.

8. Prasanna T.R., A. Novrotsky Energetics of the oxygen vacancy order-disorder transition in Ba2In2O5 // J. Mater. Res. 1993. Vol. 8, № 7. P. 1484–1486.


Review

For citations:


Tarasova N.A., Animitsa I.E., Pilshchikova E.D., Obrubova A.V. INFLUENCE OF THE NATURE OF SUBSTITUENT ION (F- , Cl- ) ON ELECTROCONDUCTIVITY OF BROWNMILLERITES BASED ON BARIUM INDATE. Alternative Energy and Ecology (ISJAEE). 2016;(7-8):38-42. (In Russ.) https://doi.org/10.15518/isjaee.2016.07-08.038-042

Views: 668


ISSN 1608-8298 (Print)